Subject Subject [7940/TFU-CHEIGLE:II QuesiontookltNe, 534568 “adler Spares HT ATT ada gr aiei—angve TS FT TE wa ae wr wa Seal of Superintendent of Examination Centre| To be filled in by Candidate by Ball-Point pen only SI. No. of Answer-Sheet — 20 7 cn SET 8] aegis eee eA Roll No | go and We S' ateorr : 83 ra faa wa Freer area are get aa fee eI am Declaration : [have read and understood the instructions given below. Fash ett (Gignature of Invigilator).... (Gignature of Candidate)... dee a ape TT (Name of Invigilator) .. «| (Name of Candidate) wn ns vo Paper: II subject : CHEMICAL ‘SCIENCEStime: 1 Hour 15 Minutes wee 100 Fewer 8 yet at eT } 32 Faw afecreer a et at ear }50 Number of Pages in this Question Booklet Number of Questions in this Question Booklet. INSTRUCTION TO CANDIDATES reat & fee Pret 1. Immediately after getting the Booklet read instructions carefully, mentioned on the front and back page of the (Question Booklet and do not open the seal given on the right hand side, unless asked by the invigilator. Do not accept a booklet without sticker-seal and do not accept an open booklet. As soon as you are instructed to open the booklet in the first 5 minutes you should compulsorily tally the number of pages and number of questions in the booklet with the information printed on the cover page. Faulty booklets due to pages/questions missing or duplicate or not in serial order or any other discrepancy should be got replaced immediately within 5 minutes, Afterwards, neither the Question Booklet will be replaced nor any extra time will be given. 2. Write your Roll No,, Answer-Sheet No,, in the specified places given above and put your signature. 3. Make all entries in the OMR Answer-Sheet as per the given instructions, otherwise AnswerSheet will not be evaluated 4, For each question in the Question Booklet choose only one correct/most appropriate answer, out of four options given and darken the circle provided against that option in the OMR Answer-Sheet, bearing the same serial number of the question, Darken the circle with Black or Blue ball-point pen only. 5. Darken the circle of chosen option fully, otherwise answers ‘will not be evaluated. Example: A) @ O© D tt @) is correct answer. 6. There are 50 objective type questions in this Booklet. All questions are compulsory and carry 2 marks each. 7. Do not write anything anywhere in the Question Booklet or on the Answer-Sheet except making entries in the specified places. Rough work is to be done in the space provided in this booklet. 8, When the examination is over, original OMR Answer Sheet is to be handed over to the invigilator before leaving the examination hall, while the Question Booklet and carbon copy of the Answer-Sheet can be retained by the candidate. 9. There is no negative marks for incorrect answer. 10. Use of any calculator/log table/mobile phone is prohibited 11. In case of any ambiguity in Hindi & English versions, the English version shall be considered authentic. For Technical words terminology in English shall be considered as standard. 7210/TFU-CHE/GLE-I1 1, we-yferar frord a ye ye a alfa ge # fee me free aT erat me ve Safe sik eri diet i dass et aT “aha ore dhe athe wer gece aT ga A eT yeaa BT waar at) wer Berar a ie & fee San er TT we 5 fae H siftenda: er ys oe alera yet a een wa wei at een at gfevar # yet at don we vel ah em 8 fre tad) Felaet a gen Ge Bee Gore wT aT ‘ee ay area fet Parte & are Se ewel we Bio aT wal 5 fate & six sec Ga) eR Ward 3 A wer Gia Bee SH aar & atte a Ol aE safer wre fen ATT 2. ome fen ay Fretfta eat & aren argon, sayfa wri ford wen Hat BETA HE 3. shunan, sacwte Famer wate fel wa Peer st ara sae ate ar ype AE Frat SET 4. Were we & ae tq wegen Tower Ae feu me ae fered 4a wetjaad sept ae UH et feaed a1 a eT air saeeie # set freed aa tte Hi, Sh se we ae ani 8 ea a, ere aT he atereangor a | EI 5. FG aR aa the Bh are ae 8 i, sere sat wr aT wet rT zen: @ @ © Oxo arat 6. wereaferet & 50 aeghae wes feu me #1 wate wer % fire ats Foes tas we ard &1 7. ea an ete Pe ear eae at wd a go 9 fee oF ad, ce Geran F see eT RT 8. aden ane & sara oa we oat Fl AT RT, satate them at at ser yer ytcar aae aie cards adh itll art ara @ 1 wea o, ane era wel Frat 10, Feat sf ace % Breegeeran ae stares we aa z 11, weet a tcc a fed a tire ROTH ay err at feafe &, at afish qaor at orators art sree) arttert ‘vredl & fora aiitsht yreraeht @ arte ArT TETSPACE FOR ROUGH WORK / 1 ard & faa STs 2 7210/1 FU-CHE/GLE-ICHEMICAL SCIENCES - I Tare faa - I The correct quantum numbers for the unpaired electron of chlorine atom is : (A) n=2;1=1; m=0 (8) n=2;1=1; mj=1 (©) n=3;1=1; m=1 (D) n=3;1=0; my=0 The correct bond order for N,O, Nz 2 molecules is : (A) Ny > Nz >0,> 07 (B) N,>O,> Nz > O07 (C) 0,>N,> 03 > NZ (D) Nz >N,> 07 >0, Among the following : (a) 1*7 (b) Ln +3 (©) Kt (d) P +2 Which ions are treated as hard acids ? (A) (a) and (b) only (B) (@), (b) and (d) only (©) © and (d) only (PD) @), (b) and (©) only 1. 2. Beis Wea & ara eelags ar wat aI den are? (A) n=2;1=1; m,=0 NO, Nz Op FY Sr Bet are HE: (A) N,> Nz >0,> O35 (B) N,>O,> Nz > 02 (C) O,>N,> Oz > NE (D) Nz >N,> 0}; >0, frafafaa 4, fara arr at were ore FT ae a GT Te? (a) It7 (b) Lnt3 (©) kt (d) prt2 (A) Raat (a) at (o) (8) Fae (a), (&) HR (a) HI (CQ *aa (0) ak (a) (D) aa (a), (b) HR (CH ‘SPACE FOR ROUGH WORK / th ward & fora we 7210/TFU-CHE/GLE-IIMatch List - I with List - II : List - I List - I (a) Icly @) Linear (b) BrF3 (i) Tetrahedral () CIF, (iii) Angular (d) AlcIz (iv) _ Distorted trigonal bipyramidal Codes : f@) () (©) (dd) ) @ @ Gi w&) ® ® Gi) @) @ © @ & HH @ () @) @ Gi) @ Among the following (@) [V(H,0)6* (&) [Fe(H,0),)?* (©) [Co(H,0),}** (2) [Ni(H,0),P* The compounds which possess orbital angular moment are : (A) (@), (b) and (c) only (B) (b) and (c) only (© (®), (©) and (d) only (D)_ (c) and (d) only get -1 sik get. 0 ar fires ae : (A) ®) © () wat -1 wet - Icy @ ages BrF} Gi) Faererata CIF, Gi) era Alc; Gv) frefia fraiiia fafa @ &) © @ o @ @& w& ® @ @ @ @) Gi) @ @) @ Gi) @ frafefiad 4 @, fara attire a, weit area sarget aren aren & ? (a) () ©) (a) (A) (B) 2 (D) [V(H,0).** [Fe(H,0),}°* [Co(H,0),]** (Ni(H,O),P* aa (a), (b) a (C) F Hae (b) site (0) F Ha (b), (0) HR (a) F Fae (0) ste (d) F SPACE FOR ROUGH WORK / Te word & feat we 7210/TFU-CHE/GLE-II‘Assertion (A) : [Co(NH)3Cly] gives white ppt with AgNO, solution. Reason (R) : Chlorine is not present in ionisable part of the given complex. Codes : (A) Both (A) and (R) are correct (R) is correct explanation of (A). (B) Both (A) and (R) are correct but (R) is not correct explanation of (A). (©) (A) is correct, but (R) is wrong. (D) (A) is wrong, but (R) is correct. Assertion (A) : Cf is used as an oxidizing agent in volumetric analysis. Reason (R) : Ci4 has tendency to attain +3 oxidation state. Codes : (A) Both (A) and (R) are correct (R) is correct explanation of (A). (B) Both (A) and (R) are correct but (R) is not correct explanation of (A). (©) (jis correct but (R) is wrong. (D) (A) is wrong but (R) is correct. wRert (A): [Co(NH,),Cly], AgNO, Hr % ary wa aa (ppt) YEA FEAT e1 a& (R): faq 7a afta (complex) # areata art F weir arqafeent Tea B1 qe: (A) (A) SiR (R) Shit we F az (R), (A) wa aT a (B) (A) site (R) Brat ae EEC), (A) wa aren At © (A Fas Ra (RTE! (D) (A) Tea @, Hq (R) HAE! ‘mort (A): arnt fara #, cit #1 va TF aiactore 1 ae 8 fear orate) wa (R): cy! at vafa +3 ater feta er ore Fe a St Ti qe: (A) (A) sik (R) aH Be E BIR (Ry, (A) ad arene (B) (A) site (Ry Brat ae Tq (B, (A) F wat caren Ae eI © (Awe FIR He (D) (Ay Tea %, TAR) FEE SPACE FOR ROUGH WORK / te word & fort se 7210/TFU-CHE/GLE-II8. Match List - I with List - 11: 8. qet-raitcget- na fram ae : List - I List - II Get -1 wat - 1 (a) [(PPh,);RhCl] i) Hydroformylation (@) [(PPh3)RCl] i) WRT of alkenes (b) [Rh(CO),15] (i) Hydrogenation (6) [Rh(CO),15] i) TegRFRE soe catalyst (Q [Pach] (ii) Monsanto catalyst (© [Pact] (ai) Wifee ora & fore for acetic acid Tee sae (@ [HCO(CO),] (iv) The Wacker (d) [HCO(CO),] (iv) Sax WiraT process Codes : qe: @ & © @ f@) ) © (@ (4) Gi) Gi) ww) @ (A) Gi) @ (wv) @ ®) @ Gy) Gi) Gi ® @® @& @ Gi) © @ @ @ Ww) © @ @ Gi w&) (D) (i) Gi) Gv) @ 0) @ @ wy @ 9. The molecular orbital electron 9. [Re,Clg]?~ 47&% & Re—Re S194 FT configuration of the Re-Re bond in afters ares seats fara eat & + [Re,Clg]?~ cluster is : (A) o® nts! 8 (A) o®atat am (B) oats ar (8) on2as” (C) ont a? (CE) oats? (D) ona x (D) o2nsta” 10. Which of the following metal ion is 10. frrafefaa ¥ 8, ett a atias art present in nitrogenase ? sige H safer teat 8? (A) Zn (A) Zn (B) Cu (B) Cu (©) Mg (C) Mg (D) Mo (D) Mo SPACE FOR ROUGH WORK / t& @td & fet we 7210/TFU-CHE/GLE-II