Subject Code: 0128/TFU-CHEMIELG-II eter Saree I HTL Seal of Superintendent of Examination Centre To be filled in ‘Wena grr atet—argee 4B aT TE 53527 saat a Sl, No. of AnswerSheet Question Booklet No. by Candidate by Ball-Point pen only core SHT-ZE Pa Pexo-jT or Roll No. | Declaration : Chemical Sci Creed Stee: AAS fea a der ore ae aga ag Fee Thave read and understood the instructions given below. aaah pert are 3 GET (Gignature of invigilator). cnn Cignature of Candidate)... heres 3 Tr ait ara (Name of Invigilator) nnn (Name of Candidate) sess _ vaper:1_sunjee: CHEMICAL SCIENCE ime: 2 Hour Mane!” 200 a garigdatten | Fryeariuiaiven | Number of Page inthis Quetonooktee | OO Sen rs easy era Sine aics ich Gra miocr’Dorsec ahi! Wem shaac ate oer ea Scaets nate Souenuseant mem ea lea ere ae dea See ines Aen eke Se, “aie rcieebtorny ce one ae See Wate your RlNo, Awe Neopia si Wek pa ear aehaae fatal cus ni OM Neh prt ge Sion et rt oe Si ere en ae a a te = Bata i ce of hen pon fy, here ve want Soma ample: @) @ © D1) icons snawer There are 100 objective type questions in this Booklet. All «questions are compulsory and carry 2 marks each, Do not write anything anywhere in the Question Booklet or on the Answer-Shoet except making entries in the specified pplaces. Rough work is to be dane in the space provided in this booklet. ‘When the examination is over, original OMR Answer Sheet is to be handed over to the invigilator before leaving the ‘examination hall, while the Question Booklet and carbon copy of the Answer-Sheet can be retained by the candidate, There is no negative marks for incorrect answer. Use of any calculator/log table/ mobile phone is prohibited {In case of any ambiguity in Hindi & English versions, the English version shall be considered authentic. For Technical words terminology in English shall be considered as standard, 01287TFU-CHEM/ELG-1T 10. un. 1 1 Number of Questions inhi Question toate,” LOO swat & ere Per 1, weregficem Fert ger ge wel in ge fee ore bet we ara eg ie ate rit ats wh cha aA A ET a hee ate ate wer Ger aT gS I oF yee elon 1 wer yer a a fore Sen get aT rem» fife fra: yay sifen yet at er wl we ai don 8 ghee fot at den wa weit st der 8 fro Bead Pact wa Ge Ges A a wT A aT ‘ae a or fe Retarere 3 eT Ure afeqeT wea eae aT ‘ras fate alee were S41 gee wears 7 ee YT aren ou weet shea eh we safes we fe aT “ae faq ay fran eat A ae orgs, seer nie feel ae seed eee BE stoemom, save Hare afafeai Ra a8 fEegeR ay rae Saas Yeates el Fe are see wer sae tg afer A were AA fee me a Fame #8 weld sega Bam UHH Pewee stare, seve Haat Pewee ara a aA, oh ge 7 ‘are wai A aang wah are ar cage ea EL wet see me HS aH staat awe a NE, or a a EHS ad emi zt: @ @ © Oxw arnt: wearer #100 argh wer fee me Caer a fey 2 Prete 1 a we afrard £1 rere ae sow 8 Pe er eal we te we Sh goa fed ww ar, ye year a ea ear aE tie wae & sea we we Tee TE a she sacra aters at ats ore Wega TH sae sands ih viet oro are 3 oT at sarees eens el fret ae fed oh ate & Seagal Paes a a we aT ti wet a ater af ft etoile geo ay era at eater, at fiat geen at areas rt ardor Tarte ret fea atti meget ares AeA TT 10. 4,SPACE FOR ROUGH WORK / 7% ard & fort 31 (0128/TFU-CHEM/ELG-IICHEMICAL SCIENCE®: - II Tarr fear - I The shape of S,F, is similar to : 1. SF, HT STR free aE eat 3? (A) GF (A) GF, 8) H,0, (8) HAO, © WR © HF (D) CH, (D) C,H, Assertion (A): Caro’sacidhas‘S’ atom 2. afm (A): ea +6 aii in +6 oxidation state, sae Fs) way sar Reason (R): — Caro’s acid contains RTT (R) : a ara Fou wis one peroxo 03” group. (A) Both (A) and (R) are correct (R) is correct explanation of (A). (B) Both (A) and (R) are correct but (R) is not correct explanation of (A). (C)_ (A) is correct but (R) is wrong. (D) (A) is wrong but (R) is correct. The number of bridged Sulphur atoms in P,S;is: (A) 4 (B) 3 © 5 (D) 2 OF Baw aa e1 (A) (A) a2 (R) eri wat % itz (R), (A) a wd creme! (B) (A) 34 (R) Bai waz, Ty (R), (A) at ad aren ae 81 (QO A) aS WAR) TAT! (D) (A) TIT 8, FEY (R) TET P,S, 4 fars eae TASH St HeM zs : (A) 4 (8) 3 © 5 (D) 2 SPACE FOR ROUGH WORK / @ @rd & fora we 0128 /TFU-CHEM/ELG-IITo prepare cis[Pt(NH3),Cly] which of the following pair is needed ? (A) [Pt(NH,),P* and KCL (B) [Pt(NH,),/?* and NH,CI (©) [PtCl,?> and NH,CI (D) [PCP and NH, The correct sequence of stepwise stability constants of logKy, logKy, logKy, logk is: (A) logy > logK, > logk, > logk, (B) _logK, > logK, > logK, > logKy (C)_logK, > logk, > log; > logK, (D) _logk, >logKs > logk,> logy ‘The correct sequence of ionic radii in increasing order of given cations Ce*, La*3, Pm*3 and Yb*3is: (A) Cet3 ak NH, logK,,logK, logky logK, FOTAR feat feorciait a wet aH e (A) logk,> log > logk, > logk, (B) _logK, > logk, >logK, > logK, (©) logk, > logK, > logks > logky (D) logK, >logK, > logK, > logKy fea wa warer Cet3, Lat3, Pm*3 WaT Yb+3 & aga an A seer a et aA e: (A) Cet3< Yb*3 < Pm*3< Lat (8) Yb*9< Pm*3< Ce*3< Lat? (C Yo*3< Pm*3 Oo &) @ @ Gi ~™ © &) @ ™ @ Gi 8. Reaction. 1 and 2 are termed as respectively : ct 7 1, SnCl,+CoxCO}g_ (OQ4Co~Sn=ColCO}, a Me 2. MexSnCl,+2NaRe(CO)s (Oc)sRe~$n—Re(CO)s Me +2Nacl (A) Insertion, Metathesis (B) Metathesis, Insertion (©) Oxidative addition, Metathesis (D) Oxidative addition, Insertion 7. Wat 14 yen ars at gett - 0 A vee qarsi & aa gaara site wat -1 wet - 0 (a) TiClAlet, @ Safa areata (b) [Pt(NH,),CL] Gi) aegtsrtarcr (©) [Cofen),5* (iti) Fegferirret ary (iv) Wetter verter areetater (@) [RhCIPPh,),] (©) Fe(CP),(CO). (v) Es 7 @ © © @ €) A @ @ Gi) (~) @y) 8 @) @ @ w&) © @) @ @ Gi) ~™ ) @) @ (&) i) i) 8, aftfea 1 der 2 ser: Ge aT es: a 1 SiCeCafCOy, (OCHE-S CaCO} a Me 2. MesSnCly+2NaRe(CO}s(OC);Re~fn—Re(CO}s Me +2Nacl (A) ah, Fatfafra (3) Fafafes, ea (C) afetstea ufser, tafifra (D) aiadisfea ufeer, sat SPACE FOR ROUGH WORK / th ard & fort 31 0128 /TFU-CHEM/ELG-IL10. @) () © (d) The changes which occur when O, binds to hemerythrin are : (a) One iron atom is oxidized Both the iron atoms are oxidized O, binds to one iron atom and also hydrogen bonded Oy binds both the iron atoms and is also hydrogen bonded Code : (A) (B) © (D) (a) and (b) are correct (b) and (c) are correct (a) and (d) are correct (@) and (c) are correct Match List - I with List - 11: List - 1 List - IL Metallo enzyme ‘Metal present Carboxy peptidase (i) Fe Cytochrome i) cu Nitrogenase (ii), Zn Ascarbate oxidase (iv) Mo Code : @ ® © @ (A) Gi) @ wv) @ ®) @ @ Gi) te) © Gd @ @ & (D) jv) @) @ @ % Fa O, Bide 8 aerate at: (a) (b) © (a) qe: (A) (8) © (D) re ar 1 Tey ataetpa Sat TI apr & St weary siterip BaF 0, era 1 AY a wets eT T wen BETAS Ee F1 0, aa & Sri seargsit 8 Se HUTS TET STTHAAE Sear BI (a) 3 () FE EI (6) aik (9) FEI (a) ait @) HEL (a) ait () AE 10. Get - 1a geht - 11% aa wafers shee : (@) () o} (a) wet -1 Revit TET arias tesa @ acer areaifartst oearde aes qe: (A) @) © ©) at - waftea feat Fe (i) Cu cc) @) Zn @) &) Gi) @® @ Gi) w&) Gi) @ @ &) @v) @) Gi) @ (©) (iy) @) (i) SPACE FOR ROUGH WORK / 3% ard & fort TE 0128 / TFU-CHEM/ELG-II11. The correct sequence of L>M charge 44, transfer transition energy of : (a) CrOF (6) MoO} () WOF- (A) @), 0), © (8) ), ©), &) © ©, @ ©) ©), 0, @ 12, The correct sequence of CO stretching 4 vibrational frequency of following is : (@) (THCO),2 ©) IV(CO- ( co @) [cx(CO),] A) 0.0, 0.@) ®) 0-@). © @,0,0,@) ©) @), @), (a) cro} (b) Moo? (c) Wo? &, LoM aM gine da Sal ar eet STA e: (A) @), ), ©) (B) a), ©), &) (©) ©), ®), @) (PD) (), ©), @ . frafafad a1 Co efda weer fiscal aT wet aA e: (@) [T(CO)P- ©) [V(CO)]- () co (a) [Cx(CO),] A) © @), 0) @ ®) ©,@, 0, @ © @,0,0,@ (DP) @), @), b), © SPACE FOR ROUGH WORK / tH @rd & feat wae 0128/TFU-CHEM/ELG-II 713. 14, ‘Among the following, the compound which has the lowest energy barrier for the cis-trans isomerism is : The reaction given below is an example of: MeO, NO? NO, coed A (A) Ezelimination (8) E,-elimination (C) Symelimination (D) E,cb-elimination 13. 14, Prada fra aifre a fae-era orenies & fore frac Sat seat @ (a) pO aretferan safitiven ferent saree 8? MeO, NO2 NO, Ma! COomco facie (A) E~ ®) E, ~ faci (©) Syn - faire (D) E,cb - facia SPACE FOR ROUGH WORK / te wre & fet we 0128/TFU-CHEM/ELG-II15. 16. Consider the following two statements I and II below : I: In the electrophilic aromatic substitution reactions, nitro group is meta directing. Il: Nitro group increases electron density at the meta position of aromatic ring. The correct statement from the following is: (A) Land II are correct (B) Land I are incorrect (©) Lis correct and II is incorrect (D) Tis incorrect and II is correct The order of stability for the following cyclic olefins is: aA xd oO a) (my @) (@) O<@z>¥ ®) Y>x>z (© Y>z>x () xX>yY>z 19. An organic compound X exhibited the following spectral data : IR: 1760 cm~1 THNMR : 8 (ppm) : 7.2 (1H, d, J=16.0 Hz), 5.1 (1H, m), 2.1 (3 H, $) 18 GH, d, J=7.0 Hz) BC NMR : 6 (ppm) : 170 (Carbonyl Carbon) Compound X is : OM @ J 8 Mi ry" ® Uo 2 © fo Mo 9 Nom 19, Set seat affine H Fie ere, x, y ae Za aaftieariteran a aa & : ows (A) X>Z>y¥ ®) Y>x>z ( Y>z>x (D) X>Y>z ie aie ait Fina wa aga srr WI vee Hee IR: 1760 cm=1 1HINMR : 8 (ppm) : 7.2 (1H, d, J=16.0 Hz), 5.1 (1H, m), 21 3 HS) 18 (3H, d, J=7.0 Hz) SC NMR : 8 (ppm) : 170 (araifret re) airs x @: ©) So os (D) i] wa? io SPACE FOR ROUGH WORK / ta ad & faa we 0128/TFU-CHEM/ELG-II20. An organic compound having the molecular formula CigHy, exhibited two singlets in the "HNMR spectrum and three signals in the C-NMR spectrum. The compound is : B® NN © © < cr 21. Which among the following is not the correct chemical name of the medicine Aspirin ? (A) Salicylic acid acetate (B)_2-(acetyloxy)-benzoic acid (©) 0-Acetylsalicylic acid (PD) Acetylsalicylate 20. 21. aig atiffra afte frre onftaa qa Cyotha & HNMR Baga 4S fereal te BC.NMR agen @ aia farrell ar weela ween 81 ae aire e : (a) (8) A * \ o KI GPmi M . KU fra 3 8 cade Usie ar aa Waal A wae? (A) Sfefaferr sma ufaee (B) 2-(afafectraet) -aisitear aire (C o-efafertfafaters ar (D) Ufafeerdferfacre SPACE FOR ROUGH WORK / T% 3a & fer SE 0128 / TFU-CHEM/ELG-II22. The compound OH OH HO met CCH CH3CH,00€ ‘COOC;H; is: (A) (+) @R)- diethyl tartarate (B) (RS) - diethyl malonate (OG R)- tihydroxy butanoate (D) (-) © $)- diethy! tartarate 23. The following conversion : TI— () ars CTTI]— (A) can be made slow by using butyl lithium (8) can be made fast in presence of AgBF, (©) is very slow thermally (D) takes place by a disrotatory pathway 24, The nomenclature of : —Ss8\ -— Cox] is: (A) 10-0x0-6-Sulphobicyclo [4,5] heptane (B) 6-ox0-10-thiaspiro [4, 5) decane (©) 10-0x0-6-thiaspiro [4, 5] decane ©) 6-0x0-10 thiabicyclo [5,4] decane 22, 23, 24, 535271 wifi: OH OH HOM C— CoH CHACH,00 00H t: (A) (+) (8 R) - sei erate (8) (RS) ~ eeefire aeitie (© GR) - Feeegrt ae ©) (-) GS) - sRefre enete Prafetiaa oftads ; (A) reife chee & vin fis rae a () 31 AgBE, & via fear oT wan 1 (CQ wit era ae sie) (D) fewteed aria dua tere) 5 a Cox] wT eS (A) 10-31 6-aettargEaCH (4, 5] ea (8) 6-39t-10-erarTE 14, 5) 34 (©) 10-39i-6-erereagy 4,5] 334 (D) 6-STRH - 10 eTaTETgETERRA (5, 4] Ba SPACE FOR ROUGH WORK / t& @d fora oe 0128/TFU-CHEM/ELG-IL25. 26. 27. The wave function and energy of the 25. particle in 1D box (0 < x = a) are: o> Fsin( 22) and Ba mu (0=1, 2) ‘The number of nodes in the second excited state of such system are : (A) 3 ® 1 ©) 2 (D) Zero The hydrogenic orbital(s) exhibiting two 26. radial nodes are : (A) 4p, 5d (8) 4p, 34 (© 2p,4d (D) 6f, 3s Match Column-I and Column-II. 27. Column-1 Column-II (a) XeF, — (i)_‘Tetrahedral (b) SeF, (i) Square planar () XeO; Gil). Pyramidal (4) XeO, (iv) Triangular planar (v) Distorted tetrahedral Code : @ &® © @ «@ @ @ @& ® @ ™ wd @ © @ ™ &) 0 © @ © @ ™ 1 ata (0. < x Co(NHs)5 NO3++Br” —- Co(NHg)sBr°*+NO3 > Co(NHs)5 NO3*+Br™ What is the effect on the rate of the ionic ead aretha wae a Vet CK FA AT strength ? we? (A) _ Rate increases (A) ae (B) Rate decreases (8) ae (©) Rate is independent *of" ionic (© Rarhtre vaca eR Fok ae eT strength (D) First rate increases and’ then (D) Wee ease atte fae FET decreases 35. Match the following : 35. fra at aaa Fifa List-I List-II 1 wet - (Crystal system) (Minimum (farce fara ) (=a watt symmetry wa) elements) (a) Hexagonal () one C, axis (a) @aarire @ we, wie (6) Triclinic (i) one C, axis () aefrarae @ wo wit (} Orthorhombic (iii) one C, axis (ater (ii) UC, wR (a) Monoclinic (iv) one Ce axis (a) Artfact @&) WC wR (v) three mutually (vy) dares orrat perpendicular C,- Cy Ure axis The correct match is : wat fra é : @ © © @ @ © © @ () @) © @ “a &% @ @ ® @) @ ™ Gi @®) @) @ ©) i © @” @ ™ & Ow @ ™ & © ww % © & © * % ®@ & SPACE FOR ROUGH WORK / TH ward & fer we 18 0128/TFU-CHEM/ELG-II36. 37. Assertion (A) : A polymer solution, containing 50% of molecules of molecular weight 5x 10° and 50% of molecules of molecular weight 10°, was injected into GPC column polymer of molecular weight 5 x 10° was eluted first. Reason (R) : ‘The polymer of molecular weight 5 x 105, due to its large size does not enter into all pores of GPC column and hence eluted first. The correct answer is : (A) Both (A) and (R) are correct and (R) is the correct explanation of (A) (B) Both (A) and (R) are correct and (R) is not the correct explanation of (A) (C) (A) is correct but (R) is not correct (D) (A) is not correct but (R) is correct Identify correct statements from the following : (a). The molecular weight of a polymer can be obtained from GPC measurements. is known as Mu (®) The ratio FR polydispersity index. (©) The molecular weight obtained from Osmometry measurements is My Code : (A) (@) and (b) only (8) @), (b) and (~) (© @)and (©) only .(D)_() and (0) only 36. 37. aafirenert (A) : Fert cietine ferctar 4, snfoers om 5105 I 50% TeN stars ae 103 I 50% ssi wi, snftas aR 5x105 & GPC stem Wtettr F ia: afta serena Fare B safer AR 5x10 a tei waa wet ae a Ta ERT (R) ama AT 5 x 105 ser VASA aT ST STE WH & SR GPC Hien & Be H yaa ae RTT Sra: Te Free TAT wae: (A) (A) #21 (R) i wet, 3H (R), (A) at at Sree (B) (A) en (R) Sri wet, sik (R), (A) wi wel aren Fe eI (C) (A) Fes wey (RTE e (D) (A) Tee, FEY (R) BEE! fre 8 8 ad ser at wean Fife (a) GPC art @ vice an snftar a an feat HT aaa eI © FE saan a weteete qa we aT eI (0) stretfret ard a ara snftasr aR Nyy ame Re: (A) ae (a) atte (b) ®) ©), () aK) (©) ¥ (a) sit) (D)_¥ae (b) si (0) SPACE FOR ROUGH WORK / ta ard & feat we 0128 / TFU-CHEM/ELG-IIAmong the mismatched ? following which is (A) Instrumental Error - Used under inappropriate conditions. (B) Method Error - Non-ideal chemical or physical behaviour of analytical system (©) Random Error - Datas are more symmetrical around mean value (D) Personal Error - Personal limitations of experimenter, Assertion (A) : The standard free energy changes of all spontaneously occurring reactions are positive. Reason (R) : The standard free energy of elements at 298 K and 760 mm of Hg are taken as zero. Code : (A) Both (A) and (R) are correct but (R) is correct explanation of (A) (B) Both (A) and (R) are correct but (R) is not a correct explanation of (A) (©) (A)is correct but (R) is wrong (D) (A) is wrong and (R ) is correct 38. 39. fre a waa Gera ETS 7 (A) Sr Ble ~ aafad cenei F seit (8) fate afe - Sects Frac ar arent marae sera vier rere (© ages gfe - wer & area Stet a afire faftigact ern (D) Safeear gfe - warrarct ar Safar cafedtar afienert (A) ail waa: SFR afte a are yaa Sat was Sat ZI BIT (R) = Hg = 760 fash. dem 298 Ke sree aT ane Yad Sat SY wa F fern rae Re: (A) (A) 321 (R) Sr eS, FT (B), (A) a wel Saree (8) (A) FH (R) ST BES, Wy (B), (A) at ae aren a EI (©) (A) Fa 8, HIB) TATE! (D) (A) Teme, aie (R) AAI SPACE FOR ROUGH WORK / 1% ard & fet we 0128 /TFU-CHEM/ELG-II40. 41, Assertion (A) : 40. The micelle formed by sodium stearate in water has ~COO~ groups at the surface. Reason (R) Surface tension of water is reduced by the addition of sodium stearate. (A) Both (A) and (R) are correct and (R) is correct explanation of (A) (B) Both (A) and (R) are correct but (R) is not a correct explanation of (A) (©) (A) is correct but (R) is wrong (D) (A) is wrong and (R ) is correct The correct sequence of decreasing dipole 41. moment of the following molecules. @) HF (b) NF; () HO @ NH, The correct answer is : (4) @, ©, @) and &) ® @),©,@ and &) © @,(, (and (@) ©) (©, @,@) and (b) aafitenert (A) : ‘Se 4 ifear Rite 8 faftia fae a ata ™® -COO- Fa wa waz) BRUT (R) : Wo 1 athe oa tiisan wits frend ar ore) (A) 3 (R) Si wat F Biz (R), (A) at wet orem a (B) (A) 7 (R) SHH we Z org (R), (A) at ad omen wee) (©) (A) v8 %, WIR Tae) (D) (A) Tet @, a(R) HEEL (A) Frafetaa ampsit ar sate feya erect a wet oye: (a) HE () NF; () #0 (a) NHy wa oe: (A) @), 0, @ aK @) ©) @), ©, (a) aR © ©), ®), © sR (a) ©) ©, @), @ aR @) SPACE FOR ROUGH WORK / t% Grd & fea Te 0128 / TFU-CHEM/ELG-IL 2142, @ © ©) (d) 43, Match the following List-I with List-II : 42. List-I List-II (Cluster) (Structure) Rh(CO)js —@)_—-Closo bicapped @) FeyC(COyy ~— ii), Nido (b) HgRuy(CO)p — (iii) Closo © Osg(CO)2 iv), Arachno (a) The correct answer is : @ ©) © @ (A) Gi) @&) @ @ ®) @ @ Gb) © @ ~ @ @& (©) Gi) @ w&) @ The $-S bond is absent in which of the 43, following : (A) S,07° (8) $,03° (© s,03- (PD) $,07- ae - aan gett - 11 a ees Fife yet -1 wat - 0 (ArET) Caveat) Rhg(CO) 6 @ ware Fec(coys =i) HRuy(CO), iit) eA Osg(CO%m — iv) AAT wat SRE: @ ©) © @ (A) Gi) @) @ @ ® @ @ @& ©. di @ @ @ (0) @) @ &) @ fra Ba fail ss ate aqafiont &? (A) $,07° (8) 8,05" () 8,057 (D) 8,077 SPACE FOR ROUGH WORK / 7 ad & fort Te 22 0128 / TFU-CHEM/ELG-IL44. Match the following List-I with List-II : List-I List-IIT (Raw material) (Product) (a) Limestone (Porcelain (b) Gypsum (i) Glass (0) Silica sand (iii) Plaster of Paris (a) Clay (iv) Cement The correct answer is : @ % © @ A) @ @) @® @ ©) Gy) Gi) @ Wi (C) Wy) i) @ @ ©) @ @ Gi) és) 45. Match the List-I with List-II : List-I List-IL (Reagents) (Reaction type) (@) Grcl]*+[rCiy- _()_Transeffect (©) [COWH);CO,]* +H,0 (il) Acid hydrolysis (©) [PCL +NH, (ii) Electron transfer reaction (@ [CO(NH,),CIP* +H,0 (tv) Substitution reaction without cleavage of ‘metal ligand bond The correct answer is : @ ©) © i) &) @ (ii) Gv) i) (vy) Gi) @) ® @ Gi) (a) (i) @ @ (iv) (a) (B) © (D) 44. yet - Laem yet - 0 a wafer Ff! wet -1 at - (rem Are) (sae) (a) Saree Wider () fran ata (Q) fate ta wares atte tite (a) Frat feet fare we THE: (a) (iii) (iv) (iv) @ (b) (iv) (ai) (i) @ (d) @ @ @ (iv) (A) B) © () 45. aelt - 1 ce gett - a aaa aif) wit wen ( affranis ) ( afar rae) (@) [rch + Orci @ Fare (b) [COWH,),CO)* +H,0 (i) Ute werenefee (©) [Ptcy?> +NH3] Gi) yea gies afatra (4) [CO(NH,) CIP" +H,O () Fee ferns ae ‘Freenr efea are fata wa TRE: (@) (ii) (iii) ») ) ) Co) @ ©) @ @ @) (ii) (a) @ @ @ (iv) (A) () © (D) (iv) @ SPACE FOR ROUGH WORK / ta wre & fered STE 0128/TFU-CHEM/ELG-II 2346. 47. Identify the correct sequence of increasing 46. vr acidity of the following ligands : (a) CF, (pb) NEty () co (@) GH, The correct answer is : (A) @), (&), © and (d) (B) (b), @), @) and (©), (© ©, €@), @) and (b) (D) (b), ©), @) and (a) Consider the following non-carbonyl 47. clusters. (a) [Zrg(PRs)4Clo] (b) _ [Nbj(PR;CHPR,),Clo] (©) Moc- (ad) MoO,clg- ‘The increasing order of metal-metal bonds is: (A) ©, (b), (@) and (a) (8) (@), (b), @) and ©) © @,), © and (d) (D) (@), ©), (&) and (a) fae ferret at aed oe rere Be THA et veaM Fs @ OF (0) NEty () co (@) GH, Wa TRE: (A) @, ©, © aR @) &) ©), @),@ AO © 0@,@ a ©) &), (0, @) aK @) fas ait-arreifare sere AIK fT (a) [Zx,(PR,),Cle] (©) _[Nbp(PR,CHPRy),Cle (© Mods @ Moc eag—eng ae ar Bat ar we: (A) ©) @ aR @) ©) @),0),@ a © © @,0),© a a) ©) @,©,@) 4 @ SPACE FOR ROUGH WORK / ta ard & fra se 0128 / TFU-CHEM/ELG-I48. Match List-I with List-II : 48, Get - 1. oan gett - a aafe sitar) List-I List-II yet -1 wet - 0 (Protein/ (Function) (até faerfe ) (ard) Vitamin) (a) Ferritin (@) Electron @) Skea @ wag ciate transport (b) Haemoglobin (ii) _ Iron storage (>) ehirchfar Gi) are ei (©) Cytochromes (iii) Oxygen (© aR (iii) safaris etette transport (d) Vitamin Bj (iv) Organometallic (a) faetr B,, (iv) Steer enzyme Tee The correct answer is : wane: @ & © @ @ © © @ @) @ @ Gi) Gy (A) @ Gi) ii) Gv) ®) (i) @) @ 8) @ @ @ © @ @ w&) @ © @ Gi) @& @ (D) (ii) @ (iv) Gi) ©) Gi) @ (vy) 49. Among the following, the nuclei which 49,_-ATwait 4 fisareiter =yfaciené aaah 8B? are active in Mossbauer are : @ ™% @ ™% 6) %co ) "co (c) Fe () Fe (@ Msp (@ sp Code : qe: (A) @), 0), (© and (€) (A) @), ©), © 3k (@ (B) (a), (0) and (d) only (8) ¥4e (a), (0) sik (a) (©) ©), (© and (A) only (C) Fae (b), (0) SR (a) (©) @), &) and (0) only (D) Ae (a), b) 3k ©) SPACE FOR ROUGH WORK / T% ard & fed aE 0128 / TEU-CHEM/ELG-II 2550. 51. 52. 53. In a nuclear reactor oxides of which of 50. the following metals are used as a fuel ? @ U (&) Np () Ac (@) Pu Code : (A) (b), © and (4) only (8) (@), (and (A) only (©) © and (a) only (PD) @) and (A) only The state of hybridization of chlorine in 51. CIF; is : (A) sp (B) sp? (©) sp'd (D) dsp? Based on simple MOT, which of the 52. following should have largest bond dissociation energy ? (A) CN* (B) CN (Q cot (D) NO The elements Si, P, S and Cl follows the order : (A) si@> a () @)>@>q@ © O>a@>@ (De) @>ap>@ 59. 60. 61. 62. anit aa sh aichineres or ara recast fers ara sie wa a flee Sea et: (a) fata (8) faire © a (D) Teer eet fa ta inom ae tH STA 05 cmig™? aren vere fare Sta Samet ST? (A) 50 m?g-? (B) 100 mg"? (C) 500 mg~! (D) 1000 m@g~? aren fare aes Sar See Starz, F: (A) ari crest 6) ae © west (D) AEs Sy? wferearse & far went favaretierat & HH A fre atta #1 rafeers wise 2a 2Adtetret @ Latter 2 a) (a) () O>@> aD () a> @> a) © O©>a@>@ ©) @>a>@ SPACE FOR ROUGH WORK / Ue ra & feral ITE 0128 / TFU-CHEM/ELG-II63. 64, Whatis the expected major product of the following reaction sequence ? te 1. BH. THF 2, HO, NaOH OH om > ~ OH (a) (B) Arr ool a © (D) The following isomers are : IL Br Et. = )=N H a Me ‘OH I u (A) Tis E and His Z (B) Lis Zand Mis Z (C) lis Zand is E (D) Lis Eand Mis E 63. 64. fre ofatirar am aa er eae een 8? 1. BH. THF YY “2.0; NaOH” fe) (B) OH. ao | () Fre organ & : 1 Br Et a Jen H Cl Me oH I m (A) LEtW ze (B) Lzeean,ze (©) Lzevniee (D) LEtWHL Ee SPACE FOR ROUGH WORK / ta ard & feat Te 0128/TFU-CHEM/ELG-II65. The major product in reaction sequence is: mee 12, NaHCO3 [ NaOMe ~ g NaOMe wD I so ®) oe OMe © yk ‘OMe OMe ©) Saye OH ° 65. afitren wa A yer see es OH 12,NaHCO3 jaOMe AY —\ “) LY Koo OH oxy OMe o OMe (D) Me 1 HL ° SPACE FOR ROUGH WORK / TH ard & feral TE 0128 /'TFU-CHEM/ ELG-II66. The major product formed in the 66. frmfafad afifear son a1 yer seme @ following reaction sequence : ® 7 ® ~ yon KCN, MeOH-H,O a A ii KCN, MeOH, HO 25°C BC ° ° An @) ‘yh (a) NN CN Ar. ®) SA ®) MeO~t CN ® ® Ar Ar © iC NMe3 © SAL NMe3 A Ar 5 ©) Soo ©) oN SPACE FOR ROUGH WORK / th @a & feat we 0128/TFU-CHEM/ELG-II 3167. The major product formed in the 67. fra affnen # fafa er sere @ : following reaction is : O O o+7 ° a | as, Ph Nout Ph “put (a) ik at (a) YY But But ) ®) rm Ph But But Oo << © 7— Ph COOH Ph COOH COOK COOH OM 7 © 7 Ph Ph SPACE FOR ROUGH WORK / Ta ard & fea we 32 0128 / TFU-CHEM/ELG-IL68. What is the following major product in 68. fH siffeean A yer sere SI Te? reaction ? HCl | HCL one Si ann a) xy a) hy a cl (B) sha (B) she ~ Dt shy © OY © : () SPACE FOR ROUGH WORK / Te @rd & fea we 0128 / TFU-CHEM/ELG-II 3369. The major product formed in the 69. fre african 8 er See BH TT? following reaction is : MeO 1.Me,SiCLEGN 5 2. PRCOCHO, Tick,” HO 1.Me,SiCLEGN 2. PRCOCHO, TiCly HO. HO. Ph (ay Meo ( (ay MeO f ° Me,SiO Me;sio~ ~~ MO “yr (B) J ®) Messio A ° Me;SiO o 8° ° HO. Dy 10, Son © “IX © “ry HO ° HO: ° SPACE FOR ROUGH WORK / T ard & ‘fora we 34 0128 / TFU-CHEM/ELG-II70. Which of the following reactant given the 70. f= # 8 wt afufwaH NaNO, HCl & product by using NaNO, HCl? Srin a a a sere ST? a) PK a) pou NE NH OH OH w ~Z wo YZ NH NH) © pron o Sout NH) NH OH OH © >A © AZ, SPACE FOR ROUGH WORK / tH wera & feet se 0128/TFU-CHEM/ELG-II 3571 Whatis the expected major productinthe 71. FF aafataren Hata a TSA See B? following reaction ? BD3/THF cy BD3/THF CO HyOy, "H,0, NaOH LA Hx NaOH (A) Ce T Cy D cr o o »OH oO © D —s Sp ©) Sk ©) OH OH SPACE FOR ROUGH WORK / Ta word & fort Te 36 0128 / TFU-CHEM/ELG-II72. Match the following compounds with their spectral characterization : cH, och @ () UV absorption at Fc “SCH 269 nm (b) H-C=C-CH, (ii) _ IR absorption band at 1690 cm~1 © cr (ii) Four signals in 1H NMR spectrum ° (a) mc\ Arc, (iv) IR absorption band at 3300 cm~1 Code : @ ©) © (A) @&) Gi) @ @ ®) (ii) @) @ O gi) @ (D) () 72. Pre aitnet a sre Sage afreeit & aet ‘gates afar CH oct, ® f @ mC cy (b) H-C=C-CH, (ii) o cr (ii ° @) ctor, @ &) © (a) @) Gi) @ ®) Gi) (vy) @ © @ @ w& ©) @) @ @ SPACE FOR ROUGH WORK / %& ad & fea we 0128/TFU-CHEM/ELG-II 37 269 nm % UV arate 1690 cm~1% IR seer FS 1H NMR Sa Fan frre 3300 cm=1 ¥ IR seer FS @ @ @ (w) qi)73. Arrange the following nucleophiles in 73. fre afer ah ayfacretrtettael ae decreasing order of nucleophilicity : wa 8 crater sf : uc \-8 H,COC 4 8 HC 4 \8 wycoc-{”)-8 I I I aig onc )-8 Mm (A) W>1> m1 (A) W>T> i (B) W>I>0 (8) W>I>1 (CQ) I>m>1 (© I>mel (D) >>I (D) W>m>1 74, The amino acids containing sulphur are: 74. arith ore free aeRR eB: (A) Aspartate and Cysteine (A) seanee wen fae (B) Alanine and Methionine (8) varie wen fafesia (©) Methionine and Cysteine (© fafasirta cen frets (D) Tyrosine and Glutamate (D) aatia wat Teerte, SPACE FOR ROUGH WORK / Te Td & fea we 38 0128/TFU-CHEM/ELG-II