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PREMIUM ALUMINA

FOR REFRACTORY APPLICATIONS


Sales Office
ALUMINA FOR REFRACTORIES
Application Lab

Plant

Refinery Almatis – The Premium Alumina Company


With more than 100 years of alumina expertise, Almatis offers the most comprehensive alumina QUICK FACTS:
Rotterdam
Frankfurt Almatis is the world’s leader in the develop- product portfolio in the industry. Our broad
Ludwigshafen ment, manufacture and supply of premium product line includes: Global specialty alumina producer with
alumina and alumina-based products. • Tabular aluminas over 100 years of expertise
Bauxite Leetsdale + Neville
Dalton Tokyo • Calcined and reactive aluminas Most comprehensive alumina portfolio
Qingdao Iwakuni Almatis is both a global and fully integrated
Burnside • Polishing aluminas Closer to our customers with
Kolkata
producer, serving our customers from sixteen
Falta
strategically located sales, research and manu- • Calcium aluminate cements highest quality products
facturing sites. Our employees strive to exceed • Alphabond 300 Reliable and secure supply from our refinery
customers’ expectations through industry lead- • Dispersing aluminas and 9 world-class production facilities
ing customer service, technical support and • Brown sintered alumina, BSA 96 Excellent global and local service
manufacturing excellence. We implement lead- • Alumina and magnesia-rich spinels with leading-edge technical support
ing technologies and continuous improvement • Calcium hexa-aluminates, Bonite and SLA-92 Continuous development of innovative
programs, which have established Almatis solutions and applications know-how
products as the benchmark for quality and con- Across our core markets—refractories, ceramics
Almatis Burnside, Inc. sistency. Our commitment to strong partnerships and polishing—we deliver one-stop shop-
Burnside,
Louisiana, USA Campinas with our customers creates innovative solutions ping, always expanding our portfolio to meet
that support and enhance their growth in all customer and market requirements.
regions of the world.

Almatis, Inc., Almatis, Inc., Almatis, Inc., Almatis, Inc., Almatis B.V., Almatis GmbH, Almatis Alumina Qingdao Almatis Almatis Limited,
Bauxite, Dalton, Leetsdale, Neville, Rotterdam, Ludwigshafen, Private Ltd., Co. Ltd., Iwakuni, Japan
Arkansas, USA Georgia, USA Pennsylvania, USA Pennsylvania, USA The Netherlands Germany Falta, India Qingdao, China

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ALUMINA FOR REFRACTORIES ALUMINA FOR REFRACTORIES

Refractories: Heat and Wear Resistance


ALMATIS ALUMINAS Broadest alumina portfolio worldwide
FOR REFRACTORIES: Refractories are formulated for the harsh All Almatis alumina-based aggregates are
conditions they will face in service. These manufactured from high purity raw materials.
• High-alumina dense aggregates include applications in the production of iron The well-controlled production processes result
• Lightweight aggregates and steel, cement, petrochemicals, non-ferrous in very homogeneous, pure products for produc-
metal, glass and others. ing high quality refractories.
• Calcined and reactive aluminas
The Almatis range of premium aluminas is
• Calcium aluminate cements and binders
designed for use in advanced refractories such as: High performance matrix products
• Dispersing aluminas • monolithics The aggregate fines and matrix products, such as
• prefabricated pieces calcined and reactive alumina, optimize the
• bricks particle size distribution and increase the
• isostatic pressed products refractoriness of the product.
Almatis products ensure the design of higher The use of ultrafine aluminas with high sinter
performance refractories where heat tolerance, reactivity provides mechanical strength and
creep resistance and corrosion resistance are of abrasion resistance to bricks and functional
crucial importance. products. In monolithic formulations, engineered
reactive aluminas define the rheology and allow,
High-alumina aggregates in combination with dispersing aluminas, the
Almatis offers multiple aggregates in a wide formulation of castables with extremely low
range of crushed and milled sizes to optimize water demand.
refractory formulations.
High temperature calcium aluminate cements
Aggregates are the backbone of a refractory and binders bring stability to monolithic products
formulation and provide dimensional stability and complete the Almatis product range for our
to the refractory products. The coarser fractions refractory customers.
add thermal shock and corrosion resistance.

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REFRACTORY AGGREGATES REFRACTORY AGGREGATES

Tabular Alumina T60/T64


High-purity aggregate
Almatis Tabular Alumina T60/T64 is widely used Tabular alumina exhibits excellent chemical
for various high temperature applications. resistance against basic and acidic corrosive
The purity and unique microstructure of tabular media and exhibits a high abrasion resistance
alumina offer considerable advantages over with a Mohs hardness of 9 for corundum.
other high alumina aggregates used for the for- Refractories made of tabular alumina are used
mulation of unshaped and shaped refractories. in many applications in various industries:
The high purity of Almatis Tabular Alumina • Iron and Steel
T60/T64 ensures excellent thermomechanical • Cement
properties of the refractory products. In combi- • Petrochemical Almatis Tabular Alumina
nation with carefully selected, high performance • Foundry T60/T64 converter discharge
binding systems, refractory products based on • Non-ferrous metallurgy
Almatis Tabular Alumina T60/T64 can be • Glass
applied at temperatures up to 1800° C. • Incineration

Tabular Alumina T60/T64


Chemical Composition [%] All Sizes1 -45 micron LI -45 micron STD -20 micron
Al203 by difference (typical) 99.5 99.5 99.1 99.3
Na20 ≤ 0.40 ≤ 0.40 ≤ 0.60 ≤ 0.40
Si02 ≤ 0.09 ≤ 0.09 ≤ 0.12 ≤ 0.15
Fe Magnetic ≤ 0.02 ≤ 0.02 ≤ 0.30 ≤ 0.02

Physical Properties Almatis Tabular Alumina


Bulk Specific Gravity [g/cm ] 3
≥ 3.50 T60/T64 sized
Apparent Porosity [%] ≤ 5
Water Absorption [%] ≤ 1.5

1) All sizes excluding -45 micron LI, -45 micron STD and -20 micron

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REFRACTORY AGGREGATES REFRACTORY AGGREGATES

Tabular Alumina T60/T64


Comparison of thermal shock test resistance: Volume stability Stable PSD and chemistry BENEFITS OF ALMATIS
60% of tabular alumina grains survive a thermal The consistent quality of Almatis Tabular Alu- length with closed spherical pores. Because Almatis offers various tabular alumina sizings As a result of the sinter process, tabular alumina TABULAR ALUMINA T60/T64:
shock whereas all fused grains get damaged. mina T60/T64 is the result of a well-controlled of this unique microstructure, tabular alumina from very coarse fractions to fine-ground sizes exhibits the same mineralogical and chemical
sinter process with firing temperatures above exhibits an excellent thermal shock resistance of <45 µm and <20 µm. composition for all fractions. Contrary to fused • Excellent thermomechanical
100% 1800° C. The use of high temperature furnaces when compared to fused aggregates. products where impurities accumulate in the properties
The controlled particle size distribution (PSD)
with state-of-the-art technology permits densifi- fines, the use of tabular alumina in refractory • High volume stability
80% Parts under severe thermal shock conditions, and low batch-to-batch variation make Almatis
cation of selected raw materials without sinter- formulation guarantees stable and reliable
60% such as burner blocks or steelmaking’s sliding Tabular Alumina T60/T64 the material of • High thermal shock resistance
ing aids that would negatively impact the high behavior.
40% gate plates and sub-entry nozzles, achieve a choice for critical applications such as isostatic • High chemical resistance
temperature properties of the refractories.
stable and long service life when formulated pressing or recipes for dry vibrating mixes.
20% Refractories made of Almatis Tabular Alumina Global product specifications • High purity
with Almatis Tabular Alumina T60/T64. Crushing and milling are followed by intensive
0% T60/T64 show, therefore, high volume stability. Almatis Tabular Alumina T60/T64 is available • High mechanical stability
Tabular alumina-based monolithic ladle linings de-ironing steps that result in very low free iron in various sizes and the majority are global
10 CYCLES lower the specific refractory consumption and within the various tabular alumina fractions, • High wear resistance
Unique microstructure products. Identical product specifications, re-
20 CYCLES offer chemical inertness for the production of thus providing a high resistance in reducing
30 CYCLES The particular production process is controlled gardless of where they are produced, facilitate
to achieve the special microstructure of tabular clean steel. atmospheres. the transfer of formulations and production from
CYCLE: 20° CALUMINA
TABULAR ➞ 1300° C ➞ 20° C alumina. one geographic region to another.
WHITE FUSED ALUMINA
TABULAR ALUMINA
Almatis Tabular Alumina T60/T64 is charac-
WHITE FUSED ALUMINA
terized by its large, well-developed hexagonal
tablet-shaped alumina crystals of up to 200 µm

240 µm 70 µm

Almatis Tabular Alumina T60/T64 Almatis Tabular Alumina T60/T64 APPLICATION : Sliding gate plate
microstructure (SEM) <45µm (SEM)

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REFRACTORY AGGREGATES REFRACTORY AGGREGATES

Magnesium Aluminate Spinels


Magnesium aluminate spinel has excellent The Almatis magnesium aluminate spinel product
refractory properties with a melting point of stoi- line includes both alumina-rich and magnesia-
chiometric spinel of 2135° C. All spinels have rich spinels, which are increasingly used in
the ability to substitute large percentages of one refractories for demanding applications in these
or both of the cationic site components (Al3+ or industries:
Mg2+) with other elements with the same charge
• Steel
and similar atom size. These specific interac-
• Cement
tions with corrosive media, especially steel slag,
• Foundry
explain the use of magnesium aluminate
spinels in refractory products designed for high
corrosion resistance.
Furthermore, the thermal-shock resistance of
refractories can be improved by the addition Sintered Spinel
of high purity, sintered spineI. Chemical Composition [%] MR 66 AR 78 AR 90
High purity Al203 > 63.0 > 74.0 > 87.0
The purity and homogeneous microstructure of Mg0 33.0 22.5 9.5
Almatis sintered spinels offer considerable ad- Ca0 0.39 0.24 0.15
vantages over other high purity fused spinels Si02 0.09 0.10 0.06
used for the formulation of unshaped and Na20 0.03 0.09 0.15
Fe203 0.20 0.15 0.06
shaped refractories. Low grade spinel materials
made of bauxite or diaspore cannot be com- Phase Composition (X-ray diffraction peaks)
pared with the premium sintered spinels and do
Spinel main phase main phase main phase
not match the excellent thermomechanical prop-
Corundum (AI203 ) none trace minor phase
erties, especially creep resistance, of high purity
Periclase (Mg0) minor phase none none
sintered spinel.

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REFRACTORY AGGREGATES REFRACTORY AGGREGATES

Alumina-Rich Spinels AR 78 and AR 90


MgAI2O4 – Spinel Structure* Alumina-rich spinels AR 78 and AR 90 are lattice sites with the capability to absorb low- Volume stability Without silica fume BENEFITS OF ALMATIS
distinguished by their chemistries (78% and 90% melting, low-viscosity components of the attack- Established practice sets a total spinel content Although spinel-forming solutions require the ALUMINA-RICH SPINELS
alumina respectively). ing slag, such as Fe (FeO) and Mn (MnO). As the of 15-30% for alumina refractories in contact addition of some microsilica for expansion control, AR 78 / AR 90:
slag composition becomes deficient in FeO and with steel slag. the optimum performance of pre-reacted
AR 78 and AR 90 are mainly used in high-
MnO, the slag viscosity increases and has much sintered spinels can only be achieved when • High refractoriness
alumina refractory bricks, monolithics and pre- High quality pre-reacted spinels ensure volume
lower tendency for penetration and erosion. formulated with high purity aggregates and a • High corrosion resistance against
fired shapes in the iron and steel industry. Latest stability during firing and are therefore less
silica-free matrix. steel slag
research shows the superiority of these spinel- Superstoichiometric spinel AR 90 precipitates prone to the spalling of refractory linings, which
containing materials when in contact with mag- alpha alumina at working temperatures, which is sometimes experienced with in situ spinel • Excellent thermomechanical properties
nesium-containing aluminum alloys. reacts with calcium oxide in the slag forming forming solutions. Pre-reacted spinel is inert and • High volume stability
the refractory CA 6 phase at the edge of the spi- does not react with water. The use of Almatis
• High thermal shock resistance
Mechanism of spinel nel grains that protect the spinel grains against AR 78 and AR 90 is therefore recommended
When compated to stoichiometric spinel, the further corrosion. for the production of prefabricated shapes like
alumina-rich spinels have additional vacant impact pads, purging plugs, well blocks and
EAF-roofs. With spinel-containing formulations,
AI – atoms on octahedral sites crack-free pieces can easily be achieved.
Can be replaced by Fe(III), Cr, Mn(III), ... Impact of Silica content on HMoR of ladle castables
Mg – atoms on tetrahedral sites Spinel containing +
Can be replaced by Fe(II), Ni, Mn(II), Zn, ... Spinel forming
0.5% silica fume
Mix A
Oxygen With Spinel

Spinel forming
Mix A
*The Structure of Materials, by Marc De Graef & 0.5% silica fume Without Spinel
Michael McHenry, published by Cambridge University Press

Mix B
Spinel containing With Spinel
No silica fume

Mix B
Without Spinel
0 5 10 15 20 25
HMoR [MPa] Improved corrosion resistance APPLICATION: Steel ladles APPLICATION: Steel well blocks
due to spinel addition
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REFRACTORY AGGREGATES REFRACTORY AGGREGATES

Magnesia-Rich Spinel MR 66
Stress relief through microcracks
Almatis magnesia-rich spinel MR 66 is used in Magnesia-rich spinel MR 66 contains free
basic refractory bricks for cement rotary kilns. magnesium oxide. The free magnesia easily
It imparts the improved thermal shock re- hydrates with water, which is accompanied
sistance normally associated with chrome by volume expansion and potential crack
additions, but without the potential problem formation. The MR 66 spinel is, therefore, not
of hazardous waste disposal. recommended for use in castables, especially
for large structural parts.
Because MR 66 spinel has a lower thermal
expansion coefficient than periclase, micro-
pores and microcracks form around the spinel
grains during heating and firing. This inhibits
crack propagation from thermally or mechani-
cally induced stress.

Acc.V Spot Magn Det WD Exp 1mm


20.0 kV 4.0 15x BSE 10.1 20963 XL30 LIRR

APPLICATION: Cement rotary kiln Microcracks around MR 66 grains

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REFRACTORY AGGREGATES REFRACTORY AGGREGATES

BSA 96
High-alumina sinter aggregate Carbide and metallic free
BSA 96 is a highly refractory, dense aggregate BSA 96 is a homogeneous sintered product
with an Al2O3 content greater than 96%. The with identical chemical composition across all
major phase of the BSA 96 aggregate is size fractions. It is free of the carbide or metallic
corundum with traces of tialite (Al2TiO5). contaminants which disturb the performance
of fused high-alumina aggregates in mono-
The sintered aggregate BSA 96 is produced
lithic and brick applications.
in Germany and provides a technical and stra-
tegic alternative to brown fused alumina and Refractory bricks based on BSA 96 are conse-
refractory bauxite used in refractory products quently free from any blisters or brown spots.
for various industries: Refractory castables formulated with BSA 96
Almatis BSA 96 show a stable flow and setting behavior and
• Iron and Steel
do not release any gases.
• Aluminum
• Foundry BSA 96 is de-ironed and is inert with liquid phos-
• Petrochemical phate binder for mortars and ramming mixes,
• Incineration providing a longer shelf life for these special
type of refractory materials.

BSA 96
Chemical Composition [%] Typical Physical Properties Typical
BSA 96 microstructure
Al2O3 96.5 Bulk Specific Gravity [g/cm3] 3.5
TiO2 1.5 Apparent Porosity [%] 4.5
SiO2 1.0 Water Absorption [%] 1.3
MgO 0.4
Na2O 0.3
Fe2O3 0.15

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REFRACTORY AGGREGATES REFRACTORY AGGREGATES

BSA 96
Economic advantage
BSA 96 has intergranular closed pores mechanical strength and abrasion resistance
similar to tabular alumina. Therefore, the bulk of the refractory products. Low-cement castables
density of refractory products based on BSA 96 with BSA 96 showed, according to ASTM,
is 5 to 8% lower when compared to brown fused abrasion values below 3 cm³ at room
alumina. The open porosity, which is important temperature and even lower when tested in hot
for corrosion resistance, is in the same range conditions (1200° C).
or lower. BSA 96-based monolithic formulations
have a lower material demand and thus The higher sinter reactivity of BSA 96 can
a lower specific cost at the same or even also be noticed when used in AluMagCar-
better corrosion resistance than brown fused bon (AMC) bricks. The spinel formation rate is
alumina-based products. increased and expansion is seen at lower tem-
peratures than with fused aggregates.
Higher sinter reactivity The slag resistance of an AMC brick based on
When compared to fused aggregates, BSA 96 BSA 96 was found to be comparable to fused
exhibits a higher sinter reactivity resulting in high high alumina aggregate.

APPLICATION: Delta section of electric BSA 96 (middle) shows no melt-outs


arc furnace roof compared to BFA (right);
tabular alumina (left) for comparison
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REFRACTORY AGGREGATES REFRACTORY AGGREGATES

Calcium Hexa-aluminate (CA6)


Unique sinter aggregates INDUSTRIES USING
Almatis offers an exclusive range of aggregates The dense CA6 aggregate Bonite is the material ALMATIS CA6 PRODUCTS:
based on high purity calcium hexa-aluminate. of choice in applications where high corrosion
resistance is the major focus. Bonite LD (low • Steel
Calcium hexa-aluminate (CA 6) is a highly
refractory mineral that exhibits a particular density) offers reduced thermal conductivity but • Aluminum
combination of properties: still a sufficient level of corrosion resistance. • Glass
• Low thermal conductivity when compared • Foundry
to other aggregates of comparable density The super lightweight aggregate SLA-92 offers • Cement
• High chemical resistance in an alkali
ultimate heat insulation at high temperatures • Petrochemical
environment and outperforms even ceramic fibers.
• Low wettability by molten metals and slag
(ferrous and non-ferrous)
• Low solubility in iron containing slag
• High stability in reducing atmospheres, Calcium Hexa-aluminate
e.g., CO Chemical Composition [%] SLA-92 Bonite Bonite LD
Al2O3 91.0 91.0 91.0
Almatis CA6 products are composed of about CaO 8.5 7.6 7.7
90% calcium hexa-aluminate with only a minor Na2O 0.40
content of corundum and traces of CA2. The SiO2 0.07 0.9 0.5
Almatis CA6 products are differentiated mainly Fe2O3 0.04 0.09 0.08
by their densities and porosities.
Physical Properties
Bulk Specific Gravity [g/cm3] 0.8 3.0 2.8
Apparent Porosity [vol. %] 70 – 75 9.8 24

Phase Composition (X-ray diffraction peaks)


Calcium Hexa-aluminate (CA6) main phase main phase main phase
Corundum (AI203 ) minor phase minor phase minor phase
CA2 trace none none

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REFRACTORY AGGREGATES REFRACTORY AGGREGATES

Bonite / Bonite LD (CA6)


Thermal conductivity of refractory materials Low thermal conductivity Aluminum resistance at >1200° C Alkali resistance BENEFITS OF ALMATIS BONITE:
used for steel ladle permanent lining Low thermal conductivity is inherent to calcium Reduced heat loss combined with high resistance For aluminum applications, bonite provides an Applications such as glass and cement require
3.0 hexa-aluminate (CA6) based aggregates and against slag make bonite-based refractory ma- anti-wetting effect at temperatures >1200° C a refractory material that is resistant to attack • High refractoriness
THERMAL CONDUCTIVITY [W/mK]

can be transferred to refractory products, mono- terials the ideal choice when energy reduction where commonly used anti-wetting additives by alkalis. The destructive effect, called alkali-
• Low thermal conductivity
2.5 lithics and bricks. is desired while keeping high safety levels. decompose. Corundum formation and build-up bursting, is caused by the formation of new
in aluminum melting furnaces are significantly mineral phases combined with high volume • Low solubility in iron containing slag
The combination of the three commercially
reduced. At the same time, heat losses are expansion within the lining. Because of its spe- • High stability in reducing
2.0 available products, Bonite/Bonite LD as dense atmospheres, e.g., CO
reduced due to the lower thermal conductivity cial mineralogical structure, bonite exhibits a high
aggregates and SLA-92 as a super lightweight Castable – Bonite of bonite-based refractory materials in the wear resistance against alkali attack. Alkali ions like • High chemical resistance in
1.5 material, allows the developer of refractory + +
lining. The relocation of the Al- liquidus line to Na and K can be incorporated into the crystal alkali environment
products to create tailor-made solutions taking
the front of the refractory lining is an addition- structure without significant change of volume. • Low wettability by molten metals
1.0 into account density, strength and thermal
al safety aspect. Therefore, calcium hexa-aluminate based and slag (ferrous and non-ferrous)
insulation.
refractories show much higher volume stability
0.5 under alkali attack compared to other high-
300 600 1000 1200
Energy saving and safety alumina refractories, providing that the matrix is
Castable BON 1
TEMPERATURE [°C]
High-alumina aggregates, like bauxite and designed accordingly.
BEFORE AFTER
BAUXITE BD:
BD: 2.70
2.70 g/cm
3
BAUXITE g/cm3 andalusite, have widespread use in various
ANDALUSITE
ANDALUSITE
BONITE
BD: 2.50
BD: 2.50 g/cm
BD: 2.85
g/cm33
2.85 g/cm
g/cm33
industries, including materials for steel ladle Castable – Bauxite
BONITE BD:
BONITE
BONITE LD
LD BD: 2.70 g/cm
BD: 2.70 g/cm3
3 safety linings.
BONITE/SLA-92 BD:
BD: 1.60
1.60 g/cm
3
BONITE/SLA-92 g/cm3 In comparison with these standard materials, the
corrosion resistance of bonite-based castables
shows superior performance against steel slag
at comparable porosity levels. The thermal con-
ductivity of a bonite-based castable is 30-40% BEFORE AFTER
lower than for the typical bauxite-based material.
Bonite corrosion resistance against
aluminum; comparison with bauxite-
Bauxite Forsterite Andalusite Bonite
based castable with anti-wetting
additive APPLICATION: Aluminum melting furnace Bonite corrosion resistance against steel slag APPLICATION: Steel ladle / heat loss

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REFRACTORY AGGREGATES REFRACTORY AGGREGATES

SLA-92 – Super Lightweight Aggregate (CA6)


Thermal conductivity of High-purity insulation Fiber-free linings BENEFITS OF ALMATIS SUPER
high temperature, lightweight aggregates SLA-92 is a non-fibrous, high-purity insulating SLA-92 can be used throughout all high The use of SLA-92-based insulating castables Aluminum transport ladles are lined with this LIGHTWEIGHT AGGREGATE SLA-92:
1.2 aggregate based on calcium hexa-aluminate temperature industries where increased process and gunning mixes overcomes concerns about highly insulating material. It is also used in
THERMAL CONDUCTIVITY [W/mK]

(CA6). temperatures, along with the need for energy potential health hazards. petrochemical applications due to its high • Constant low thermal conductivity
1.0
Due to a special production process, SLA-92 savings due to new environmental laws, require The change from traditional fiber linings to a resistance in reducing atmospheres. Even under • Very good insulation,
has a high microporosity that hampers the heat efficient high temperature refractory insulation monolithic lining with SLA-92-based castable severe conditions, for example exposure to even at high temperatures
0.8
transfer by radiation at temperatures >1200° C. material. The main use of SLA-92-based refractory requires, in most cases, some re-engineering harsh thermal shock conditions or alkali attack,
• High open porosity
0.6 The pore structure remains stable up to 1500° C, products is in applications for the following work. Nevertheless, high-insulating SLA-92 SLA-92-based refractory products have proven
industries: their high performance. • Very good thermal stability
which makes SLA-92 perform even better than castables have successfully replaced hazardous
0.4
ceramic fiber at high temperature. • Steel fiber linings in various applications. • Excellent thermal shock resistance
• Aluminum • High refractoriness
0.2 Prefabricated shapes made of SLA-92 are
• Foundry used in steel reheating furnaces, significantly • High purity
0 • Petrochemical improving the energy performance of the units.
200 400 600 800 1000 1200 1400
TEMPERATURE [°C]
BUBBLE ALUMINA CASTABLE
BUBBLE ALUMINA CASTABLE
HIGH ALUMINA INSULATING FIREBRICK
HIGH ALUMINA INSULATING FIREBRICK
SLA-92 CASTABLE (1.1 g/cm³)
SLA-92 CASTABLE (1.1 g/cm³)
SLA-92 BRICK (1.3 g/cm³)
SLA-92 BRICK (1.3 g/cm³)
CERAMIC FIBER MODULE
CERAMIC FIBER MODULE

ALMATIS SLA-92 microstructure (SEM) APPLICATION: Liquid aluminum transport APPLICATION: Walking beam furnace APPLICATION: Steel, fiber-free APPLICATION: Insulation of ducts
insulation for sub-entry nozzles
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CALCIUM ALUMINATE CEMENTS AND BINDER CALCIUM ALUMINATE CEMENTS AND BINDER

Calcium Aluminate Cements


High-purity calcium aluminate cements contain are all essential for good and reliable cement
a minimum of 70% AI 2 O 3 and are used as
binders in monolithic refractories.
performance. Intensive quality control is carried
out to ensure high product consistency, which
CA-14 M
results in the high performance and reliability
Almatis produces high purity calcium aluminate
cements with 70% and 80% AI2O3 content.
of monolithic refractory products made with CA-14 S
Almatis calcium aluminate cements.
70% Al2O3: CA-14 / CA-270 / CA-470 Ti /
CA-670 Long shelf life CA-14 W
80% Al2O3: CA-25 All Almatis cements are packed in sealed plas-

CA-25 C
tic bags that prevent reaction with humidity in
Broad CAC portfolio the environment. Therefore Almatis cements
Depending on the type of cement, the curing have a long shelf life, with 24 months guaran-
and setting behavior varies significantly, impact-
ing hardening and strength development. This
teed when stored under adequate conditions,
even when climatic conditions are challenging. CA-25 M
allows the developer to choose from a wide
range of calcium aluminate cements to find the
right one to meet the desired properties.
CA-25 R
Consistent setting
Almatis calcium aluminate cements are tested to
CA-270
reflect customers’ needs. Consistency in chemi-
cal and mineralogical composition, particle size CA-470 Ti
distribution, and in flow, setting, and strength

CA-670

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CALCIUM ALUMINATE CEMENTS AND BINDER CALCIUM ALUMINATE CEMENTS AND BINDER

Calcium Aluminate Cements 70% Al2O3


The CAC 70 family of products includes:
CA-14 CA-270 CA-470 Ti
CA-14 is a well-established product line with CA-270 is characterized by very low water The latest Almatis development is the tempera-
three distinct setting time ranges: demand, excellent flowability and high ture-independent cement CA-470 Ti that shows
CA-14 W short strength development. In established highly clear advantages when compared to standard
CA-14 M medium sophisticated formulations, CA-270 can give 70% Al2O3 cements. CA-470 Ti improves the
CA-14 S long that extra 10% of water reduction to provide setting behavior of castables at low tempera-
ultimate performance. ture whether or not they contain silica fume.
CA-14 type cements are used especially in low
Castables with CA-470 Ti exhibit a much
and ultra-low cement castables and gunning Like all Almatis 70% alumina cements, CA-270
more robust setting and avoid the setting time
mixes for various purposes. does not contain any additives, providing full
variation and uncertainty that are especially
flexibility in product design without any potential
The cements are additive-free and for optimum apparent at low ambient temperatures.
chemical mismatches.
flow properties require the addition of defloccu-
lating additives. The use of Almatis dispersing The flow of silica fume-containing mixes is
aluminas is highly recommended, but CA-14 improved when using CA-470 Ti instead of
cements also work well with common defloccu- CA-14 M.
lating additives like phosphates or acrylates.
70% Cements
CA-14 W CA-14 M CA-14 S CA-270
Setting
short medium long long

Cement Properties in Nortab Mortar

Water Addition [%] 10 10 10 9


Vicat Setting Time [min] 220 300 400 370
(Final setting)
Exothermic Reaction Time [min] 360 400 480 450
(EXO max)
Cold Crushing Strength [MPa] 48 48 48 52
(24 h cured 20° C)
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CALCIUM ALUMINATE CEMENTS AND BINDER CALCIUM ALUMINATE CEMENTS AND BINDER

Calcium Aluminate Cements 80% Al2O3 Alphabond 300


The CAC 80 family of products includes: BENEFITS OF ALMATIS High purity CaO-free hydratable binder BENEFITS OF ALPHABOND:
CALCIUM ALUMINATE CEMENTS: Alphabond 300 is a calcium-free hydratable impact on high temperature properties, notably
CA-25
The 80% alumina cements are represented by: alumina binder for use in no-cement refractory strength (particularly creep) and resistance to • Low water demand
CA-25 R regular grade • High product consistency castable compositions. Alphabond has been slag attack. • Reliable setting behavior
CA-25 M medium grade • Very low mixing-water requirement developed for applications where the chemis-
Castables using Alphabond 300 require • Improved slag resistance
CA-25 C casting grade try of the refractory matrix is critical to product
• Good flowability and setting consistency additional time to wet out after water addition • Increased refractoriness for
performance.
• Very high purity to achieve optimum flow properties at lowest silica fume mixes
They are used in conventional and medium water content. The use of high force compulsory
cement castables, which require fast setting, high • High cured and sintered strength Calcia-free mixers is highly recommended. Apart from that,
early strength development and good strength at • High thermomechanical properties Alphabond 300 contains less than 0.1% CaO they act similar to a typical 80% calcium alumi-
QUALITY CONTROL: Manufacturing excellence intermediate temperatures. and thus avoids the formation of low melting nate cement bonded mix with respect to work-
• Temperature independent product
point silicates in the matrix. Such calcium-alu- ing time, and initial and final setting time.
CA -25 type cements contain deflocculating eases on-site application
minum silicates can have a significant harmful
additives. Any further addition of additives
can lead to undesired effects due to unpredict-
able interaction between the additives used. Mullite
Mullite
1578° C

1800
80% Cements 40 <1390° C 1600
40

00

00
13
CA-25 R CA-25 M CA-25 C

14
1600

We
Anorthite 50
Setting short medium long 5% MgO
30

0
ight
3AI2O3 -2SiO2

180
00
~1850

%
60
Cement Properties in Nortab Mortar 15 Spinel Corundum ~1840

AI 2O
20
Melilite
Water Addition [%] 10 10 9 2000

3
70 0
QUALITY CONTROL: X-ray diffraction testing 160
0
Vicat Setting Time [min] 4MgO 5AI2O3 -5SiO2
70 110 140 10
(Final setting) Spinel 80
Corundum
Vibration Flow [cm]

20
00
C3A5 90
1850
F10 18 18 18 0
F30 13 17 17 50 40 30 20 10 0
50 60 70 80 90 100
Cold Crushing Strength [MPa] Weight % CaO AI2O3
Weight % AI2O3 MgO - AI2O3 MAI2O3
35 30 38
(24 h cured 20° C) 2135 2020

29 30
CALCINED / REACTIVE ALUMINAS CALCINED / REACTIVE ALUMINAS

Calcined Aluminas
Competence in alumina conversion BENEFITS OF CALCINED ALUMINAS:
Almatis offers a large product range of calcined Calcined aluminas are classified by soda
aluminas that are produced with the latest content, particle size and degree of calci- • Enhanced refractoriness and
state-of-the-art production technology. Calcined nation and are widely used in the matrix of: performance
aluminas are alpha-aluminas that consist primar- • Refractory bricks • Improved mechanical strength
ily of sintered agglomerates of individual alumi- • Castables
na crystals. The size of these primary crystals • Gunning and shotcrete mixes
• Abrasion resistance
depends upon the degree of calcination and • Isostatically pressed pieces • Thermal shock resistance
the agglomerate size on the subsequent grind- • Sliding gate plates • Reduced water demand
ing steps. The majority of calcined aluminas
are supplied ground (< 63µm) or fine-ground All Almatis aluminas are produced to tight
(< 45µm). The agglomerates are not fully product specifications for chemistry, particle
broken down during the grinding, which is size distribution and specific surface area/
a significant difference from reactive aluminas BET. Many years of experience guarantee high
that are fully ground by a batch grinding process. lot-to-lot consistency supporting the production
of highly reliable refractory products.

Calcined aluminas with different degrees of calcination: low - medium - hard (SEM X4000)

31 32
CALCINED / REACTIVE ALUMINAS CALCINED / REACTIVE ALUMINAS

Calcined Aluminas
Reliable matrix enhancer
Ground and fine-ground calcined aluminas are The water demand of calcined aluminas is de-
used as a matrix filler to upgrade the product fined by the amount of residual agglomerates
performance of formulations predominantly and the surface area. Therefore, calcined
based on natural raw materials. Calcined aluminas with low surface area are preferred
aluminas have a particle size similar to ground as fillers in bricks and castables. Special
mineral aggregates and can therefore easily calcined aluminas with higher surface area,
replace aggregates with lower purity. By such as CT 10 SG and A 13 -325 mesh, can
increasing the overall alumina content of the successfully replace clay as the plasticizer in
mixes and improving their particle pack- gunning and ramming mixes. Refractory prod-
Sagging behavior of castable ing through the addition of fine alumina, ucts modified by these products keep their
with (upper) and without (lower) the refractoriness and mechanical properties, good installation characteristics but show
calcined alumina addition such as hot modulus of rupture and abrasion significantly reduced shrinkage after drying
resistance, are improved. and firing.

Calcined Aluminas
Physical Properties A 10 -325 A 35 -325 CT 800 FG CT 9 FG A 2 -325 A 13 -325 CT 10 SG
Surface Area low low low low low medium medium
BET/Specific Surface
Area [m2/gm] 0.5 0.7 0.9 0.8 0.6 11.0 13.0

Particle Size 8.3 6.0 3.5 5.0 5.3 4.3 3.0


D50 Cilas [µm]
Chemical Composition

Na2O [%] 0.08 0.11 0.12 0.15 0.25 0.12 0.4

33 34
CALCINED / REACTIVE ALUMINAS CALCINED / REACTIVE ALUMINAS

Typical particle size distributions of

Reactive Aluminas selected reactive aluminas


80 Mono-modal aluminas

AMOUNT %
70
High performance matrix components High performance bricks and sliding gate plates Broad portfolio 60
Reactive aluminas are specially designed for With the use of reactive aluminas, high efficient grinding processes. The average Almatis has the broadest reactive alumina product Specially designed multi-modal aluminas, such
the production of high performance refractories performance bricks and sliding gate plates particle size, D 50 , of mono-modal reactive portfolio available around the globe, with as CTC 50 and CTC 55, are the optimized solu- 50
where defined particle packing, rheology and benefit in water reduction and improved ceramic aluminas, is therefore nearly equal to the diame- products from sub-micron to 3 micron particle tion to achieve reliable self-flowing properties. 40
consistent placement characteristics are as im- sintering when compared to ground calcined ter of their single crystals. size. Particle size distributions, ranging from
portant as the superior physical properties of the aluminas. mono-modal to bi-modal and multi-modal, allow 30
The combination of reactive aluminas with other full flexibility in formulation design and provide
final product.
The agglomerates in calcined aluminas have matrix components, such as tabular alumina the convenience of co-milled engineered reac-
20

Reactive aluminas are applied in: significant open porosity that absorbs water 20 μm or spinel 20 μm, allows the control of the tive aluminas. 10
• Low and ultra-low cement castables during mixing and casting. During firing, the po- particle size distribution to achieve the desired
• No cement castables rosity limits crystal growth at ceramic sintering placement rheology. Otherwise, high mixing Mono-Modal Reactive Aluminas 0
0.1 1 10 100
• High performance gunning and temperatures leading to reduced thermo- water may be required and the product may PARTICLE SIZE µm
Physical Properties A 1000 SG RG 4000 A 152 SG CTC 20 A 20 SG
shotcrete mixes mechanical properties. suffer from inadequate physical properties or
RG 4000 CTC 20
water and aggregate separation after casting. BET/Specific Surface
• High performance bricks and Reactive aluminas are fully ground down Area [m2/gm] 8.2 7.2 4.3 2.0 1.3
sliding gate plates to the primary (single) crystals by highly Particle Size 80
Bi- and Multi-modal aluminas
0.6 0.6 1.2 1.8 3.3

AMOUNT %
D50 Cilas [µm]
70
Chemical Composition
60
Na2O [%] 0.07 0.08 0.06 0.12 0.23
50

Bi-Modal and Multi-Modal Reactive Aluminas 40

Physical Properties CTC 40 CL 370 A 3000 FL E-SY 1000 CTC 30 CTC 50 30

BET/Specific Surface 20
4.8 3.0 2.5 2.0 3.8 4.1
Area [m2/gm]
Particle Size 10
1.2 2.5 2.7 1.7 1.5 1.5
D50 Cilas [µm]
0
20µm 2µm
0.1 1 10 100
Chemical Composition
Model for optimized particle packing Calcined alumina CT 9 FG with residual Reactive alumina RG 4000 fully PARTICLE SIZE µm
agglomerates >20 microns ground to primary crystal Na2O [%] 0.08 0.10 0.07 0.2 0.08 0.16
CL 370 CTC 30 E-SY 1000
-
35 36
CALCINED / REACTIVE ALUMINAS CALCINED / REACTIVE ALUMINAS

Reactive Aluminas
Impact of reactive alumina on water demand Mono-modal aluminas Multi-modal aluminas
and cold crushing strength Mono-modal reactive aluminas provide full flex- The multi-modal reactive aluminas exhibit an ex-
8.00 60 ibility to the refractory designer. Aluminas such tremely broad particle size range that has been
WATER DEMAND [%]

STRENGTH [MPA]
as CTC 20 or A 20 SG, with a low surface optimized to reduce the number of matrix com-
7.50
50 area and water demand, are designed to be ponents needed. Their use minimizes formulation
7.00 utilized in combination with silica fume and cal- design time and the effort necessary to achieve
40 cium aluminate cement to achieve the overall extremely good physical and rheological
6.50
particle size distribution required for optimal properties. With the use of CTC 30, CTC 50 or
6.00 30 particle packing and good flow behavior. spinel-containing CTC 55, self-flowing castables
5.50
with high thermomechanical performance can
20 For high demanding applications like spinel- be achieved.
5.00 containing steel ladle materials, the ultrafine
4.50
10 mono-modal reactive aluminas RG 4000 and Soft consistency
A 1000 SG can replace microsilica in the The bi-modal reactive aluminas E-SY 1000 and
4.00
15% 10% 10% 10%
0 formulation to increase thermomechanical stability. E-SY 2000 (which contains spine) offer a solu-
COMP. 80%
CAC20° C
CCS
CA-14 S
5%
CA-270
5%
CA-270
5%
tion to overcoming dilitant rheological behav-
CT 800 FG
HMoR 1500°C
CL 370 CTC 30 Bi-modal aluminas ior, often observed for high alumina-containing
CCS 20° C The use of bi-modal aluminas, such as CL 370 castables, and for achieving a soft working
WATER DEMAND
HMoR 1500°C or A 3000 FL, optimizes the packing density consistency. E-SY-containing castables can be
WATER DEMAND of the matrix and further reduces the water de- handled by shovel but can also be successful-
mand of the castables. They are typically used ly pumped. The soft consistency of E-SY-based
in high purity alumina matrix systems, but also castables permits installations of difficult geom-
work well with mixes containing lower amounts etries, such as small gaps or linings with a high
of microsilica. density of anchors.

37 38
CALCIUM ALUMINATE CEMENTS AND BINDER CALCINED / REACTIVE ALUMINAS

Reactive Aluminas
Spinel-containing aluminas BENEFITS OF ALMATIS
Spinel-containing castables are typically used Spinel-containing aluminas can be used in the REACTIVE ALUMINAS:
for steel ladle linings and prefabricated pieces same way as all other bi- and multi-modal alumi-
such as purging plugs and well blocks. The nas, and allow the formulation of vibrating and • Very low water demand
resistance of these castables against steel slag self-flowing low cement, ultra-low cement and • Low open porosity
corrosion depends largely on the amount and no cement castables with low water demand
the fineness of the spinel. Experience shows and good thermomechanical properties. • Excellent sinter reactivity
that fine-ground spinel in the formulation is • Excellent wear resistance and
essential to achieve best performance. mechanical strength
• Excellent high temperature
Almatis offers reactive aluminas containing performance
super-fine spinel for highly efficient matrix com- • Broad range to support individual
ponents for demanding applications. preferences in formulation
• Improved flowability with
Reactive Aluminas E-SY products
• Ultimate corrosion resistance with
Chemical Composition [%] E-SY 2000 CTC 55
spinel-containing reactives
Spinel Content 50.0 35.0
Na2O 0.1 0.1
MgO 11.0 8.0

Physical Properties
Grain Size Distribution bi-modal multi-modal
BET/Specific Surface 2.3 3.8
Area [m2/gm]
Particle Size 1.4 1.6
D50 Cilas [µm]

39 40
CALCINED / REACTIVE ALUMINAS CALCINED / REACTIVE ALUMINAS

Dispersing Aluminas
Set control by varying dosage of ADS and ADW Efficient deflocculation Set control BENEFITS OF ALMATIS
versions; measured in a low-cement castable. The matrix of refractory low cement castables There are two different product lines of dis- A unique feature of Almatis dispersing aluminas When compared to the classical phosphate- DISPERSING ALUMINAS:
30 contains fine and ultra-fine particles such as persing aluminas available for individual is the possibility of adjusting the setting time of based deflocculating systems, the dispersing
TEMPERATURE [°C]

29 calcium aluminate cement, reactive alumi- castable concepts: castables, according to specific placement re- aluminas exhibit various advantages: • Reduced water demand of refractory
nas and silica fume. It is essential that all quirements and climatic conditions, without sac- • Lower water demand and, therefore, castable through optimized dispersion
28 • ADS 1 / ADS 3 / ADW 1 for high
27 the matrix components are homogeneously performance silica-free castables with
rificing the final strength development as is the higher mechanical strength and abrasion of finest particles
distributed during mixing with water to take case for other common additives for set control. resistance • Improved flowability
26 alumina fines, and
full advantage of the optimized particle The ratio of the retarding “S” type to the acceler- • Control of working time with low impact
25 • M-ADS 1 / M-ADS 3 / M-ADW 1 for • Adjustable setting times (accelerating
size distribution, and achieve the lowest ating “W” type is varied to achieve set control. on the start of setting
24 fumed silica-containing castables using or retarding) in accordance with
water demand and desired rheological placement requirements and
23 alumina fines. The total amount of dispersing aluminas is
• Aging resistance, for longer shelf life of
behavior. Dispersing agents are commonly temperature conditions
the castables
22 used to de-agglomerate the fine particles of recommended to be about 1% by weight in
Almatis dispersing aluminas are very effi- • Increased homogeneity of dry castable,
21 the matrix. the castable. When keeping the total amount Robust dosage lowers risk
cient additives for optimizing properties of due to easy dosage of additives in
20 unchanged, the dispersing capability of dis- The recommended dosage for the dispersing production
0 1 2 3 4 5 6 7 8 9 10 Almatis dispersing aluminas are widely castables. When compared to traditional
persing aluminas remains stable no matter aluminas is typically 1wt% in total, which
0.6% ADW 1; 0.4% ADS 3 TIME [h] used in castable manufacturing. The combi- dispersing agents such as phosphates, the
0.7% ADW 1; 0.3% ADS 3 which ratio of S/W is used. guarantees a robust dosing for the production of
nation of organic dispersants with alumina water demand can be significantly reduced
EXOTHERMIC REACTION
0.8% 20°ADS
ADW 1; 0.2% C: ADW
3 1 – ADS 3 refractory castables.
and other inorganic materials decreases the to provide improved mechanical properties
0.6% ADW 1; 0.4% ADS 3
castable water demand and allows excellent and better corrosion resistance.
0.7% ADW 1; 0.3% ADS 3
0.8% ADW 1; 0.2% ADS 3 setting control.
Dispersing Aluminas
Product ADS 1 ADS 3 ADW 1 M-ADS 1 M-ADS 3 M-ADW 1
FOR USE IN CASTABLES WITH SILICA FUME <2% CASTABLES WITH SILICA FUME >2%
Effect
Retarding Strong Accelerating Retarding Strong Accelerating
retarding retarding Dispersing
alumina
Chemical Composition [%]
AI2O3 80 76 80 91 95 96
Na2O 0.10 0.10 0.10 1.40 1.40 0.10
B2O3 0.80 2.80 0.03 1.30 2.50 0.55
CaO 1.80 1.80 1.80 0.02 0.02 0.02 Principle of electrosteric dispersion Adjustable setting times

41 42
ALUMINA FOR REFRACTORIES

Alumina Expertise Starts in our Research Labs


Innovation is the driving force for growth. Almatis’ vide the opportunity for our customers to further
leading position in the industry is the result of ten upgrade their own portfolio to stay ahead of
decades of research and development of alumi- their competition. Almatis engineers and market
na-based materials. Today, many refractory ap- development managers are continually enhanc-
plications would not be possible without Almatis ing their application know-how to better support
innovations such as tabular alumina, sintered our customers’ growth strategies.
alumina magnesia spinel or reactive aluminas.
An important part of the service that Almatis
To maintain this level of innovation, Almatis has offers its customers is the application laborato-
increased the staffing of its Product and Market ries that are located in all major geographical
Development organization while also investing regions. These labs have the latest technical
in new application laboratories. An ambitious equipment for enabling us to study the influence
development program has been initiated and of Almatis products on the performance of
basic research work with research centers and our customers’ products. In addition, Almatis
universities has been reinforced. offers its customers the opportunity to join us
in our laboratories for training sessions or joint
Dedicated applications and market develop- development work.
ment managers and engineers provide our cus-
tomers tailor-made technical support to help them
optimize formulations and resolve application
problems. New product developments pro-

43 44
SELECT AN ALUMINA FOR YOUR APPLICATION: PRODUCT PORTFOLIO

AGGREGATES
AGGREGATES CALCIUM
CALCIUMALUMINATE
ALUMINATE CALCINED
CALCINED REACTIVE
REACTIVE DISPERSING
DISPERSING
CEMENTS
CEMENTSAND
ANDBINDERS
BINDERS ALUMINAS
ALUMINAS ALUMINAS
ALUMINAS ALUMINAS
ALUMINAS
INSU-
INSU- SPINEL
SPINEL
DENSE
DENSE LATING
LATING CAC
CAC7070 CAC
CAC8080 MONO-MODAL
MONO-MODAL BI-MODAL
BI-MODAL MULTI-MODAL
MULTI-MODAL
CONTAINNG
CONTAINNG

alumina T60/T64
T60/T64
Almatis is committed to the global and secure Almatis has a worldwide network of technical
supply of premium alumina products. Our focus and sales specialists that understand application

Bonite/Bonite LD
LD
on quality enables us to offer high-performance requirements and the latest market trends. Their

800 FG/SG
FG/SG
Tabular alumina

Bonite/Bonite
MR 66
66
AR 78
78

AR 90
90
products with a long service life. in-depth knowledge allows the development of

PRODUCT
PRODUCT

1000 SG
SG
Alphabond
Alphabond

E-SY 1000
1000

E-SY 2000
2000
35 -325
-325

13 -325
-325

3000 FL
FL

M-ADW 1
1
10 -325
-325
CA-470 Ti
Ti

152 SG
SG
Spinel MR

CA-14 W
W
Spinel AR

Spinel AR

10 SG
SG
19 FG
FG
CA-25 M
M

M-ADS 1
1

M-ADS 3
3
CA-14 M
M

2 -325
-325

RG 4000
4000
CA-25 C
C

20 SG
SG
CA-25 R
R
CA-14 S
S
innovative new product solutions to enhance

M-ADW
9 FG
FG
CA-270
CA-270
CA-470

A 3000
CTC 20
20

ADW 1
1
CTC 40
40

CTC 30
30

CTC 50
50

CTC 55
55
BSA 96
96

A 1000
CT 800
SLA-92
SLA-92

M-ADS
M-ADS
CL 370
370
CA-25
CA-25

CA-25
Tabular

CA-14

CA-14

CA-14

ADS 1
1

ADS 3
3
A 152
Spinel

Spinel

Spinel

CT 10
CT 19

ADW
A 35

A 20
Our premium alumina products are made to our customers’ business. Six regional research

A 10

A 13
CT 9

E-SY

E-SY

ADS

ADS
CTC

CTC

CTC
CTC

CTC
BSA

A2

RG
CT

CT

CT

CT

CL
A

A
global standardized specifications to facilitate and application laboratories work in close
Dense
Denseregular
regularcastables
castables supply from any plant to any region. Additionally, cooperation with our customers to optimize
Deflocculated
Deflocculatedcastables
castables we offer tailor-made product solutions to specific formulations and solve all application challenges.
(MCC,
(MCC,LCC,
LCC,ULCC)
ULCC)silica
silicafree
free market and customer needs.
Deflocculated
Deflocculatedcastables
castables(NC)
(NC) For you, our customer, Almatis specialists are
Deflocculated
Deflocculated castables
castables Global quality and health and safety standards here to help.
(MCC,
(MCC,LCC,
LCC,ULCC)
ULCC)containing
containingsilica
silica are rigorously applied in all our locations
Gunning
Gunning around the world. Almatis manufacturing
Insulating
Insulatingcastables
castables facilities comply with EHS standards and
Dry
Dryvibratable
vibratablemixes
mixes ISO 9001, ISO 14001, and OHSAS 18001
Plastic
Plasticand
andramming
rammingmixes
mixes to ensure high and consistent quality, while
Taphole
Tapholeclays
clays protecting the environment as well as our
Mortars
Mortars employees and contractors.
Fireclay
Fireclaybricks
bricks
High-alumina
High-aluminabricks
bricks
AMC
AMCbricks
bricks For solutions to your alumina needs,
ASC
ASCbricks
bricks contact us at refractories@almatis.com
Basic
Basicbricks
bricks
Sliding
Slidinggate
gateplates
plates
Isostatic
Isostaticproducts
products

*All data contained in this brochure represent typical properties obtained by Almatis test methods and are not intended to be taken as guaranteed values or specifications.
45 46
THE ALMATIS WORLD –
CLOSER TO THE CUSTOMER

USA Germany India P.R. China Japan


Almatis, Inc. Almatis GmbH Almatis Alumina Private Limited Qingdao Almatis Co. Ltd. Almatis Limited
501 West Park Road Lyoner Straße 9 Kankaria Estate, 2nd Floor No.1 Song Hua Jiang Road Morimura Bldg.
Leetsdale, PA 15056 60528 Frankfurt 6, Little Russel Street Qingdao Economic & 1-3-1 Toranomon
Kolkata 700-071 Technology Development Zone Minato-ku, Tokyo 105-8451
Phone +1 800 643 8771 Qingdao, 266510
Phone +1 412 630 2800 Phone +49 69 957 341 0 Phone +91 33 2289 4694 Phone +81 3 3502 2371
Phone +86 532 8572 8035

Brazil Germany
Almatis do Brasil Ltda. Almatis GmbH
Avenida Jose de Souza Campos, 243 Giulinstrasse 2
2° Andar – Cambuí 67065 Ludwigshafen
Campinas, SP 13025-320

Phone +55 19 3515 1400 Phone +49 621 5707 0

www.almatis.com © Almatis B.V. 2014

Think
47 alumina, think Almatis.

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