5/6/24, 11:01 AM Tetrahydrofuran "THF/Tetrahydrofuran" | Products | Mitsubishi Chemical Corporation

Corporate Information

Business・Products
Innovation

Investor Relations 日本語

Contact UsEnglish Search 
中文
Sustainability

News Releases

Home Products Chemicals THF/Tetrahydrofuran

Tetrahydrofuran
THF/Tetrahydrofuran
Mitsubishi Chemical Corporation
Print
Language
Chemicals Polymers / Resins / High Performance Chemicals

THF (Tetrahydrofuran) is a stable compound with relatively low boiling point and excellent
solvency. It is widely-used for dissolution and reaction of various substances. Also it is used
as a starting material for the synthesis of poly(tetramethylene ether) glycol (PTMG), etc. Since
1982, Mitsubishi Chemical's Yokkaichi plant has produced high-purity, high-quality THF from
butadiene using our proprietary technology.
CAS: No. 109-99-9 (T)
EINECS: No. 203-726-8
Japan, Chemical Substances Control Law: METI-No. 5-53
Japan, Industrial Safety and Health Law: No. 5-53, ID No. 367 (SDS required)
Japan, Poisonous and Deleterious Substances Control Law: Not applicable.
Japan, Fire Services Law: Hazardous Material Class 4 Petroleums No.1 (water-soluble
liquid). Hazardous Rank II
U.N. Class: 3
U.N. No.: UN2056

Characteristics Applications Specifications/Quantities

Characteristics [close]

https://www.m-chemical.co.jp/en/products/departments/mcc/c4/product/1201006_7922.html#:~:text=Taking advantage of excellent solubility,for vinyl a… 1/6

5/6/24, 11:01 AM Tetrahydrofuran "THF/Tetrahydrofuran" | Products | Mitsubishi Chemical Corporation
THF is a 5-membered-ring heterocyclic compound containing oxygen --- a cyclic ether.

Tetrahydrofuran,
1,4-epoxy-butane, oxolane,
Butylene oxide,
Common Names cyclotetramethylene oxide,
oxacyclopentane,
diethylene oxide,
tetra-methylene oxide

Structure

CAS No. 109-99-9

Japan, Chemical Substances Control (5)-53
Law METI-No.
Japan, Poisonous and Deleterious Not applicable
Substances Control Law
Japan, Fire Services Law Hazardous Material Class 4 Petroleums No.1 water-soluble liquid Hazardous Rank II
Molecular Weight 72.1
Appearance Clear colorless liquid
Odor Ether smell
Specific Gravity (25/4℃) 0.888
Viscosity(mPa･s) 0.58（at 20℃）
Boiling Point (℃) 66
Melting / Freezing Point (℃) -108.5
Flash Point (℃) -17
Flammability Range / Explosive Limits upper：11.8
(vol% in air) lower：2.0
Vapor Pressure (kPa) 18.9（20℃）
Heat of Vaporization (kJ/mol) 29.6（66℃）
Heat Capacity (kJ/kg･K) 1.77（20℃）
Thermal Conductivity (W/m･K) 0.18（20℃）
Surface Tension (N/m) 26.4×10-3（25℃）
Volume Resistivity (Ω･cm) 1.3×103（23℃）
Using butadiene as the raw material, Mitsubishi Chemical's proprietary technology enables production of high-purity, high-grade THF.
Thorough quality control makes it possible to offer product with low moisture content.
https://www.m-chemical.co.jp/en/products/departments/mcc/c4/product/1201006_7922.html#:~:text=Taking advantage of excellent solubility,for vinyl a… 2/6
 Applications
5/6/24, 11:01 AM Tetrahydrofuran "THF/Tetrahydrofuran" | Products | Mitsubishi Chemical Corporation

[close]

Surface Coating
Due to the strong solubility of vinyl chloride, even at a high degree of polymerization, THF is used as a solvent for synthetic leather
coatings.
Adhesives
Taking advantage of excellent solubility and diffusion properties, THF is used as a solvent for vinyl and epoxy adhesives.
Film Casting
THF is used for vinyl chloride heat-shrinkable film and for desiccant.
Printing Inks
THF is suitable for printing inks, because slightly soluble inorganic compounds can be dissolved and evaporation is quick.
Other Uses
THF is widely used as a solvent for special resins such as photosensitive resins, because even at room temperature it can dissolve
various resins, and it is miscible with water and most organic solvents. In, addition, it is used as a solvent for Grignard and Wittig
reactions. Also in pharmaceutical and agricultural manufacturing, it is used as a solvent for reaction and purification.

Storage and Handling

THF is classified under the Japanese Fire Services Act as a hazardous material, Class 4, Petroleums No.1, water soluble, Hazardous Rank
II. Since it is highly volatile and flammable, the storage container should be tightly sealed and stored in a well-ventilated place. When
handling take precautions against fire. Like other ethers, explosive peroxides will be generated if THF is exposed to oxygen or air. For
this reason the container should be sealed with dry nitrogen.
THF is irritating to the membranes and skin of the eyes, nose, and throat. Exposure to the vapor for long time periods may cause organic
solvent poisoning symptoms such as nausea and dizziness. Use adequate ventilation to avoid high concentrations of vapor. When using
or handling, always use proper safety equipment such as protective gloves and goggles.

Specifications/Quantities [close]

Product Specifications
Item Specification
Hue (Hazen) <10
Moisture (%) <0.02
Specific Gravity (20/4℃) 0.886～0.889
Purity (%) >99.95
Peroxide (ppm) <100
As an antioxidant, 250 ppm of BHT (2,6-di-tert-butyl-4-methylphenol) are usually added.
Available Quantities
Tanker Truckload (Lorry) 10ton
Drum 180kg
Oilcan 15kg

https://www.m-chemical.co.jp/en/products/departments/mcc/c4/product/1201006_7922.html#:~:text=Taking advantage of excellent solubility,for vinyl a… 3/6

5/6/24, 11:01 AM Tetrahydrofuran "THF/Tetrahydrofuran" | Products | Mitsubishi Chemical Corporation

Inquiries Concerning Products

Contact Form

Mitsubishi Chemical Corporation

C4 ＆ PBT Dept.

View the products of C4 ＆ PBT Dept., Mitsubishi Chemical

Corporate Information
Corporate Information
Corporate Information
Basic Information
Message from the President
Corporate Profile / Access
∟Mitsubishi Chemical Group Corporation
∟Mitsubishi Chemical Corporation
∟Mitsubishi Tanabe Pharma Corporation
∟Nippon Sanso Holdings Corporation
Leadership
Organization Chart
Global Network
Number of Subsidiaries
History
Corporate Brochure
Evaluation by Outside Parties
Approach to Corporate Activities
Group Concept
Charter of Corporate Behavior
Value Creation Model
Health and Productivity Management
Management Strategy
Management Policy
Business Strategy
∟Specialty Materials
∟Industrial Gases
∟Health Care
∟MMA
∟Petrochemicals and Carbon Products
Governance
Corporate Governance
∟Corporate Governance Guidelines
Risk Management
Compliance
Media
KAITEKI Solution Center
Digital Showroom
Social Media
∟LinkedIn account
https://www.m-chemical.co.jp/en/products/departments/mcc/c4/product/1201006_7922.html#:~:text=Taking advantage of excellent solubility,for vinyl a… 4/6
5/6/24, 11:01 AM Tetrahydrofuran "THF/Tetrahydrofuran" | Products | Mitsubishi Chemical Corporation
∟X account
∟YouTube channel
Business・Products
Business・Products
Innovation
Innovation
Innovation
Innovation Strategy
Intellectual Property Strategy
Mitsubishi Chemical Corporation R&D
Main R&D Organization
Award History
Paper Submission
Investor
Relations
Investor Relations
Investor Relations
Management Policy
Management Policy
Disclosure Policy
IR News
IR News
TSE Filings
Basic Information
Chart
IR Calendar
Financial Data
Evaluation by Outside Parties (ESG Index)
Other IR Information
∟FAQ on IR
∟Contact on IR
∟IR Sitemap
IR library
Financial Results
Operating Summaries
Analysts Meeting Materials
Integrated Reports
Securities Reports
Report in Line with the Recommendations of the TCFD
To Our Individual Investors
The Mitsubishi Chemical Group in Numbers
Stock and Bond Information
Sustainability
Sustainability
Sustainability
Sustainability Activities
Sustainability approach and promotion structure
Material Issues and Sustainability(MOS) Indices
ESG Initiatives
Environment
Society
Governance
Sustainability Data
Sustainability (MOS) results
Non-Financial Data Sheets
GRI Standards
KAITEKI Solution Center
News Releases
Information
Digital Showroom

https://www.m-chemical.co.jp/en/products/departments/mcc/c4/product/1201006_7922.html#:~:text=Taking advantage of excellent solubility,for vinyl a… 5/6

5/6/24, 11:01 AM Tetrahydrofuran "THF/Tetrahydrofuran" | Products | Mitsubishi Chemical Corporation
Contact Us
FAQ

The Mitsubishi Chemical Group Official Accounts

Sitemap
Terms of Use
Privacy Policy
Social Media Terms of Use
Copyright © Mitsubishi Chemical Group Corporation.

https://www.m-chemical.co.jp/en/products/departments/mcc/c4/product/1201006_7922.html#:~:text=Taking advantage of excellent solubility,for vinyl a… 6/6