P Prayaas 2.

0
W

APS by PS-17
(Anjaam Practice Sheet by Pankaj Sir)
O
14 15 D+
N N C
1. NO2

The possible products of the above reaction are:

NO2
O
14 15
+ O
(a) D N N (b) 14 15
C
N N D +

NO2
O
14 15
+ O
(c) D N N (d) 14 15
D N N +
C

1 Equivalent
2. Br – Cl

The major product is:

Cl Br

(a) (b)
Cl
Br

Br
(c) (d)
Br
Cl Cl

3. COOH
D2SO4
D

The possible major product of the above reaction is:

O O O O
(a) (b)
D D
D O O
O
(c) (d)
D
Prayaas 2.0 P
W

NH2
4. NaNO2 Base
HCl/0-5°C D

The possible final product of this reaction is:

(a) (b) (c) (d)

5.
HBr

The major product of the reaction is:

Br Br
Br
(a) (b) (c) (d)

Br
O

6. Br Br
NaNH2 O
(excess) Z D W

The compound ‘W’ is:

O

O O
O
(a) (b) O (c) (d)
O O
O
O O
O O
O O
O
7. An unknown saturated amine A yields an alkali soluble derivative when reacted with benzenesulfonyl chloride. Compound A on reaction
with nitrous acid gives an alcohol B, which responds to the haloform reaction. Hydrochloride of A contains 37.2% of chlorine. Find
numbers of carbon atoms in A.
Br
HBr
8. *Reactant

Br
The reactant ‘X’ can be:

(a) (b) (c) (d)

P Prayaas 2.0
W

9. *Which of the following indicates correct feasible products?

O
H
N
(a)
(i) CH3C N,conc. H2SO4
(ii) H3O+

OH

MgBr CHO

(b) HC(OC2H5)3 +

(c) (i) CH3Li (i) O3 (i) OH–

(ii) H3O+ (ii) Me2S (ii) D

CCl3

(d) Peroxide
+ CHCl3

10. *Which of the following are correct statements.

(a) A nitroso (– N O) group activates ortho-and para-positions towards both electrophilic and nucleophilic aromatic substitutions.
(b) Mg can be used in place of Zn in the Reformatsky reaction
(c) Furan has a lower boiling than pyrrole
NH2 C N
(d) has a lesser dipole moment than

N N

Answer Key
1. (d) 2. (c) 3. (a) 4. (c) 5. (b) 6. (a) 7. (3) 8. (b, c, d)
9. (a, b, c, d) 10. (a, c)