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23november Paper 1
23november Paper 1
Chemistry
Higher level
Paper 1
2 November 2023
1 hour
Instructions to candidates
Do not open this examination paper until instructed to do so.
Answer all the questions.
For each question, choose the answer you consider to be the best and indicate your choice on
the answer sheet provided.
The periodic table is provided for reference on page 2 of this examination paper.
The maximum mark for this examination paper is [40 marks].
8823 – 6107
17 pages © International Baccalaureate Organization 2023
The Periodic Table
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
1 2
1 H He
1.01 4.00
3 4 Atomic number 5 6 7 8 9 10
2 Li Be Element B C N O F Ne
6.94 9.01 Relative atomic mass 10.81 12.01 14.01 16.00 19.00 20.18
11 12 13 14 15 16 17 18
3 Na Mg Al Si P S Cl Ar
22.99 24.31 26.98 28.09 30.97 32.07 35.45 39.95
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
4 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39.10 40.08 44.96 47.87 50.94 52.00 54.94 55.85 58.93 58.69 63.55 65.38 69.72 72.63 74.92 78.96 79.90 83.90
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
–2–
5 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85.47 87.62 88.91 91.22 92.91 95.96 (98) 101.07 102.91 106.42 107.87 112.41 114.82 118.71 121.76 127.60 126.90 131.29
55 56 57 † 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
6 Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132.91 137.33 138.91 178.49 180.95 183.84 186.21 190.23 192.22 195.08 196.97 200.59 204.38 207.2 208.98 (209) (210) (222)
87 88 89 ‡ 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118
7 Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Rg Cn Unt Uug Uup Uuh Uus Uuo
(223) (226) (227) (267) (268) (269) (270) (269) (278) (281) (281) (285) (286) (289) (288) (293) (294) (294)
† 58 59 60 61 62 63 64 65 66 67 68 69 70 71
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
140.12 140.91 144.24 (145) 150.36 151.96 157.25 158.93 162.50 164.93 167.26 168.93 173.05 174.97
1. Ammonia reacts with oxygen to produce nitrogen (II) oxide and water.
___ NH3 (g) ___ O2 (g) ___ NO (g) ___ H2O (l)
A. 2:5
B. 4:5
C. 1:1
D. 2:1
2. Metal M reacts with 16.0 g of sulfur to produce 26.0 g of the compound MS2. What is the relative
atomic mass of M?
A. 5
B. 10
C. 20
D. 40
4. Gallium (Ar 69.72) consists of two stable isotopes, Ga-69 and Ga-71. What is the relative
abundance of Ga-71?
A. 36 %
B. 40 %
C. 60 %
D. 64 %
Turn over
–4– 8823 – 6107
5. The first three ionization energies for two elements, X and Y, are:
X
6. Which one of the following observations provides evidence that matter is composed of atoms?
B. Sodium chloride is soluble in water and conducts electricity in the aqueous state.
C. Water is a liquid at room temperature, but hydrogen sulfide and hydrogen selenide
are gases.
①
D. 12.0 g of carbon combines with either 16.0 g or 32.0 g of oxygen but never any other ratio.
A. Li, Be, B, C
C. K, Ca, Br, Kr
8. Which aqueous solutions would have a different wavelength of maximum absorbance from
0.10 mol dm 3 FeSO4?
A. I and II only
D. I, II and III
9. For which molecule can resonance structures be used to describe the bonding?
A. HCN
B. H2CO3
C. PCl3
D. SO2
10. Which substance has high volatility in its pure state and high electrical conductivity in
aqueous solutions?
A. C6H5Cl
B. HCl
C. NaCl
D. HCN
11. Which substance exhibits only London (dispersion) forces between molecules?
A. PF5
B. SF4
C. SO2
D. XeO2
Turn over
–6– 8823 – 6107
12. Which is the correct structure of SO3, based on the lowest formal charge?
A.
B.
C.
D.
13. What bond angle is most likely found with an sp2 hybridized carbon as the central atom?
A. 90°
B. 109.5°
C. 120°
D. 180°
–7– 8823 – 6107
A. I and II only
O
D. I, II and III
15. Which expression represents the calculation used to obtain the HÖ value for the conversion of
oxygen to one mole of ozone (O3)?
Ö
, kJ
A. 566 992
B. 566 992
Turn over
–8– 8823 – 6107
II
Enthalpy I
III
A. I II
B. II I
C. I III
D. II III
1
Na (s) H2O (l) NaOH (aq) H2 (g)
2
I. Atomization
II. Ionization
III. Hydration
A. I and II only
D. I, II and III
18. Which combination of values of H and S belongs to a reaction which is spontaneous at low
temperatures but not spontaneous at high temperatures?
H S
A. Negative Negative
B. Negative Positive
C. Positive Positive
D. Positive Negative
–9– 8823 – 6107
19. Which statement describes a role that a catalyst might have in increasing the rate of reaction by
providing an alternative mechanism?
- -
O
A. It increases frequency of collisions between molecules
O
C. It increases proportion of molecules colliding in correct orientation
20. The rate of the reaction 2N2O5 (g) 4NO2 (g) O2 (g) can be expressed as rate of change of
concentration of oxygen with respect to time, [O2] / t.
Which expression would give the same numerical value for the rate?
1
A. [N2O5] / t
2
B. 2 [N2O5] / t
1
C. [NO2] / t
4
D. 4 [NO2] / t
Turn over
– 10 – 8823 – 6107
Reaction progress
B.
Potential energy
Reaction progress
C.
Potential energy
Reaction progress
D.
Potential energy
Reaction progress
– 11 – 8823 – 6107
A. Activation energy, Ea
B. Pre-exponential factor, A
C. Rate constant, k
D. Gas constant, R
23. What can increase the amount of CS2(g) present in the following system already at equilibrium?
24. The system 2A(g) B(g) 3C(g) is at equilibrium where the concentrations of A, B and C
are all 2 mol dm 3.
A. 2
B. 3
C. 4
D. 8
25. Sulfur dioxide emissions from coal-fired power plants is a source of acid deposition. Which are
pre-combustion methods of reducing sulfur dioxide emissions?
-
I. Wash flue gases with crushed limestone and water.
II. Crush and wash the coal.
III. Crush and mix coal with a sulfur solvent, then wash.
A. I and II only
O
C. II and III only
D. I, II and III
Turn over
– 12 – 8823 – 6107
26. Which combination will make a buffer solution when 100 cm3 of each is mixed?
pH 14
0
Volume added
A. 2
B. 3
C. 4
D. 5
– 13 – 8823 – 6107
29. The acid H2S reacts with an active metal, M. Which combination shows the correct role of H2S,
and product formed from the reaction?
30. What is formed at the cathode in the electrolysis of 2.0 mol dm 3 sodium chloride solution?
A. Cl2 (g)
B. H2 (g)
C. Na (l)
D. O2 (g)
31. Which combination of atomic mass and charge on ion will result in the largest mass of a metal M
being electroplated by a fixed current for a fixed time?
A. Large High
B. Large Low
C. Small High
D. Small Low
Turn over
– 14 – 8823 – 6107
32. What is the correct classification for the two compounds given?
A. Primary Primary
B. Tertiary Tertiary
C. Tertiary Primary
D. Primary Tertiary
33. Which is the first product of distillation from the reaction of propan-1-ol with acidified
potassium dichromate (VI)?
A. CH3COCH3
B. CH3CH2CH2OH
C. CH3CH2CHO
D. CH3CH2COOH
A. I and II only
D. I, II and III
– 15 – 8823 – 6107
35. Which compound is likely to have the highest SN1 rate of reaction with OH ions?
O
B. (CH3)3CBr in ethanol solvent
36. What are the preferred IUPAC classifications of this structure of 2,3-dichlorobut-2-ene?
Cis-trans E/Z
A. Cis (E)
B. Cis (Z)
C. Trans (E)
D. Trans (Z)
37. Which procedure is most likely to produce a systematic error in determining the original
concentration of NaOH (aq) by titration with HCl (aq)?
B. Using various burettes for each trial instead of the same one
D. Titrating the sample two days after preparing it instead of on the day it was prepared
Turn over
– 16 – 8823 – 6107
38. Which graph shows the relationship between quantity of product formed and quantity of excess
reactant after the limiting reactant is consumed?
A.
mol of product formed
B.
mol of product formed
C.
mol of product formed
D.
mol of product formed
A. IR spectrometer
B. Mass spectrometer
C. Polarimeter
D. NMR spectrometer
3 2 1 0
PPM
A. Propane
B. Propanal
C. Propanone
D. Propanoic acid
Disclaimer:
Content used in IB assessments is taken from authentic, third-party sources. The views expressed within them belong to their
individual authors and/or publishers and do not necessarily reflect the views of the IB.
References:
40. The University of Sydney, n.d. [Interactive NMR spectrum.] [online] Available at: https://scilearn.sydney.edu.au/
OrganicSpectroscopy/NMRSpectraExamples.cfm?ID=25&unit=# [Accessed 13 June 2022].
All other texts, graphics and illustrations © International Baccalaureate Organization 2023