SAFETY DATA SHEET

112339000 SEMIDOL K 2

Version Revision Date: SDS Number: Date of last issue: -

1.0 30.10.2023 PR-1123390 Date of first issue: 30.10.2023
(CLP_GB)

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Trade name : SEMIDOL K 2

Substance name : Dolomite (CaMg(CO3)2), calcined

CAS-No. : 83897-84-1

EC-No. : 281-192-5

1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Sub- : Water supply
stance/Mixture wastewater management
Manufacture of chemical products
pH-regulating agents
Water Treatment

1.3 Details of the supplier of the safety data sheet

Company : Omya International AG
Baslerstrasse 42
4665 Oftringen

Telephone : +41627892929

Telefax : +41627892077

E-mail address of person : sdb.ch@omya.com

responsible for the SDS

1.4 Emergency telephone number

Emergency telephone : Chemtrec +44 20 3807 3798
number

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) as amended by GB-CLP Regulation, UK

SI 2019/720, and UK SI 2020/1567)

Skin irritation, Category 2 H315: Causes skin irritation.

Serious eye damage, Category 1 H318: Causes serious eye damage.
Specific target organ toxicity - single ex- H335: May cause respiratory irritation.
posure, Category 3, Respiratory system

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SAFETY DATA SHEET

112339000 SEMIDOL K 2

Version Revision Date: SDS Number: Date of last issue: -

1.0 30.10.2023 PR-1123390 Date of first issue: 30.10.2023
(CLP_GB)

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008) as amended by GB-CLP Regulation, UK SI

2019/720, and UK SI 2020/1567)

Hazard pictograms :

Signal word : Danger

Hazard statements : H315 Causes skin irritation.

H318 Causes serious eye damage.
H335 May cause respiratory irritation.

Precautionary statements :
Prevention:
P261 Avoid breathing dust.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P304 + P340 + P312 IF INHALED: Remove person to fresh
air and keep comfortable for breathing. Call a POISON
CENTER/ doctor if you feel unwell.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if pre-
sent and easy to do. Continue rinsing. Immediately call a
POISON CENTER/ doctor.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumula-
tive and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or
higher.

SECTION 3: Composition/information on ingredients

3.1 Substances
Substance name : Dolomite (CaMg(CO3)2), calcined

EC-No. : 281-192-5

Chemical nature : Contains quartz, respirable fraction < 1 %.

Components
Chemical name CAS-No. Concentration (% w/w)
EC-No.

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SAFETY DATA SHEET

112339000 SEMIDOL K 2

Version Revision Date: SDS Number: Date of last issue: -

1.0 30.10.2023 PR-1123390 Date of first issue: 30.10.2023
(CLP_GB)

Dolomite (CaMg(CO3)2), 83897-84-1 >= 90 - <= 100

calcined 281-192-5

SECTION 4: First aid measures

4.1 Description of first aid measures

If inhaled : Move to fresh air in case of accidental inhalation of dust or
fumes from overheating or combustion.
If symptoms persist, call a physician.

In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.

In case of eye contact : Flush eyes with water as a precaution.

Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.

If swallowed : Clean mouth with water and drink afterwards plenty of water.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.

4.2 Most important symptoms and effects, both acute and delayed
Risks : Causes skin irritation.
Causes serious eye damage.
May cause respiratory irritation.

4.3 Indication of any immediate medical attention and special treatment needed
No data available

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media : Use extinguishing measures that are appropriate to local cir-
cumstances and the surrounding environment.
Not combustible.

5.2 Special hazards arising from the substance or mixture

Specific hazards during fire- : Do not allow run-off from fire fighting to enter drains or water
fighting courses.

Hazardous combustion prod- : No hazardous combustion products are known

ucts

5.3 Advice for firefighters

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters

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SAFETY DATA SHEET

112339000 SEMIDOL K 2

Version Revision Date: SDS Number: Date of last issue: -

1.0 30.10.2023 PR-1123390 Date of first issue: 30.10.2023
(CLP_GB)

Further information : Collect contaminated fire extinguishing water separately. This

must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Avoid dust formation.

6.2 Environmental precautions

Environmental precautions : Try to prevent the material from entering drains or water
courses.
No special environmental precautions required.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up : Neutralise with acid.
Sweep up and shovel.
Keep in suitable, closed containers for disposal.

6.4 Reference to other sections

Not applicable

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on safe handling : For personal protection see section 8.
No special handling advice required.
Advice on protection against : No special precautions required.
fire and explosion

Hygiene measures : General industrial hygiene practice.

7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage : Keep container tightly closed in a dry and well-ventilated
areas and containers place.

Advice on common storage : No special restrictions on storage with other products.

Further information on stor- : No decomposition if stored and applied as directed.

age stability
7.3 Specific end use(s)
No data available

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SAFETY DATA SHEET

112339000 SEMIDOL K 2

Version Revision Date: SDS Number: Date of last issue: -

1.0 30.10.2023 PR-1123390 Date of first issue: 30.10.2023
(CLP_GB)

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure Limits

dust of any kind 10 mg/m3
Value type (Form of exposure): TWA (Inhalable)
Basis: GB EH40

4 mg/m3
Value type (Form of exposure): TWA (Respirable fraction)
Basis: GB EH40

Contains no substances with occupational exposure limit values.

Derived No Effect Level (DNEL):
Substance name End Use Exposure routes Potential health ef- Value
fects
Dolomite Workers Inhalation Long-term systemic 1 mg/m3
(CaMg(CO3)2), cal- effects
cined
Workers Inhalation Acute systemic ef- 4 mg/m3
fects
Consumers Inhalation Long-term systemic 1 mg/m3
effects
Consumers Inhalation Long-term systemic 4 mg/m3
effects
Predicted No Effect Concentration (PNEC):
Substance name Environmental Compartment Value
Dolomite (CaMg(CO3)2), cal- Fresh water 0,465 mg/l
cined
Marine water 0,303 mg/l
Sewage treatment plant 2,85 mg/l
Soil 1023,1 mg/kg
8.2 Exposure controls

Personal protective equipment

Eye/face protection : Safety glasses
Hand protection
Material : PVC
Break through time : 8h
Glove thickness : 0,5 mm
Directive : Equipment should conform to EN 374

Remarks : Before removing gloves clean them with soap and water.
For prolonged or repeated contact use protective gloves.
Skin and body protection : Equipment should conform to EN 13982
Footwear protecting against chemicals, EN ISO 20345

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SAFETY DATA SHEET

112339000 SEMIDOL K 2

Version Revision Date: SDS Number: Date of last issue: -

1.0 30.10.2023 PR-1123390 Date of first issue: 30.10.2023
(CLP_GB)

Protective suit
Respiratory protection : Respirator with a half face mask
Equipment should conform to EN 149
Filter type : P1 filter

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance : fine powder, granular
Colour : white, light grey
Odour : odourless
Odour Threshold : Not relevant

pH : 10,6 (20 °C)

Saturated solution

Melting point : > 450 °C

Method: Regulation (EC) No. 440/2008, Annex, A.1

Boiling point/boiling range : Decomposition: Decomposes below the boiling point.

Flash point : does not flash

Flammability (solid, gas) : The product is not flammable., Will not burn

Burning number : 1

Upper explosion limit / Upper : Not applicable

flammability limit

Lower explosion limit / Lower : Not applicable

flammability limit

Vapour pressure : < 10 Pa (20 °C)

Density : 2,76 g/cm3

Solubility(ies)
Water solubility : slightly soluble Method: Regulation (EC) No. 440/2008, An-
nex, A.6

Partition coefficient: n- : Not applicable

octanol/water
Auto-ignition temperature : Not applicable

Decomposition temperature : > 600 °C

Not applicable

Explosive properties : Not explosive

Not explosive

Oxidizing properties : Not applicable

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SAFETY DATA SHEET

112339000 SEMIDOL K 2

Version Revision Date: SDS Number: Date of last issue: -

1.0 30.10.2023 PR-1123390 Date of first issue: 30.10.2023
(CLP_GB)

9.2 Other information

Self-heating substances : Not applicable

Particle size : No data available

Self-ignition : Not applicable

SECTION 10: Stability and reactivity

10.1 Reactivity
Exothermic reaction with acids.
Stable under recommended storage conditions.
10.2 Chemical stability
No decomposition if stored and applied as directed.
10.3 Possibility of hazardous reactions
Hazardous reactions : Reacts with acids. It forms carbon dioxide (CO2). This
displaces the oxygen in the air in closed spaces. (danger of
suffocation).
10.4 Conditions to avoid
Conditions to avoid : No data available

10.5 Incompatible materials

Materials to avoid : Acids

10.6 Hazardous decomposition products

Carbon dioxide (CO2)

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity
Not classified based on available information.
Components:

Dolomite (CaMg(CO3)2), calcined:

Acute oral toxicity : LD50 Oral (Rat): > 2.000 mg/kg
Method: OECD Test Guideline 425

Skin corrosion/irritation
Causes skin irritation.

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SAFETY DATA SHEET

112339000 SEMIDOL K 2

Version Revision Date: SDS Number: Date of last issue: -

1.0 30.10.2023 PR-1123390 Date of first issue: 30.10.2023
(CLP_GB)

Components:

Dolomite (CaMg(CO3)2), calcined:

Species : Rabbit
Assessment : irritating
Method : OECD Test Guideline 404
Result : irritating
Remarks : Irritating to skin.

Serious eye damage/eye irritation

Causes serious eye damage.
Components:

Dolomite (CaMg(CO3)2), calcined:

Species : Rabbit
Assessment : Corrosive
Method : OECD Test Guideline 405
Result : highly irritating
Remarks : May cause irreversible eye damage.

Respiratory or skin sensitisation

Skin sensitisation
Not classified based on available information.
Respiratory sensitisation
Not classified based on available information.
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
Not classified based on available information.
Reproductive toxicity
Not classified based on available information.
STOT - single exposure
May cause respiratory irritation.
Components:

Dolomite (CaMg(CO3)2), calcined:

Exposure routes : Inhalation
Target Organs : Respiratory system
Assessment : May cause respiratory irritation.

STOT - repeated exposure

Not classified based on available information.
Aspiration toxicity
Not classified based on available information.

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SAFETY DATA SHEET

112339000 SEMIDOL K 2

Version Revision Date: SDS Number: Date of last issue: -

1.0 30.10.2023 PR-1123390 Date of first issue: 30.10.2023
(CLP_GB)

Further information

Product:
Remarks : No data available

SECTION 12: Ecological information

12.1 Toxicity

Components:

Dolomite (CaMg(CO3)2), calcined:

Toxicity to fish : LC50 (Barbus barbus (barb)): 50,6 mg/l
Exposure time: 96 h

LC50 (Marine species): 457 mg/l

Exposure time: 96 h

Toxicity to daphnia and other : EC50 (Bulinus globosus (Freshwater snail)): 49,1 mg/l
aquatic invertebrates Exposure time: 48 h

EC50 (Gammarus salinus (seawater shrimp)): 158 mg/l

Exposure time: 96 h

Toxicity to algae/aquatic : EC50 (Scenedesmus capricornutum (fresh water algae)):

plants 184,57 mg/l
Exposure time: 72 h

NOEC (Scenedesmus capricornutum (fresh water algae)): 48

mg/l
Exposure time: 72 h

12.2 Persistence and degradability

Product:
Biodegradability : Remarks: The methods for determining biodegradability are
not applicable to inorganic substances.

12.3 Bioaccumulative potential

No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment

Product:
Assessment : This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher.

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SAFETY DATA SHEET

112339000 SEMIDOL K 2

Version Revision Date: SDS Number: Date of last issue: -

1.0 30.10.2023 PR-1123390 Date of first issue: 30.10.2023
(CLP_GB)

12.6 Other adverse effects

Product:
Endocrine disrupting poten- : The substance/mixture does not contain components consid-
tial ered to have endocrine disrupting properties according to
REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at
levels of 0.1% or higher.
Additional ecological infor- : There is no data available for this product.
mation

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Product : Offer surplus and non-recyclable solutions to a licensed dis-
posal company.

Contaminated packaging : Empty remaining contents.

Empty containers should be taken to an approved waste han-
dling site for recycling or disposal.

SECTION 14: Transport information

14.1 UN number

ADR : Not regulated as a dangerous good

RID : Not regulated as a dangerous good
IMDG : Not regulated as a dangerous good
IATA : Not regulated as a dangerous good
14.2 UN proper shipping name

ADR : Not regulated as a dangerous good

RID : Not regulated as a dangerous good
IMDG : Not regulated as a dangerous good
IATA : Not regulated as a dangerous good
14.3 Transport hazard class(es)

ADR : Not regulated as a dangerous good

RID : Not regulated as a dangerous good
IMDG : Not regulated as a dangerous good
IATA : Not regulated as a dangerous good

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SAFETY DATA SHEET

112339000 SEMIDOL K 2

Version Revision Date: SDS Number: Date of last issue: -

1.0 30.10.2023 PR-1123390 Date of first issue: 30.10.2023
(CLP_GB)

14.4 Packing group

ADR : Not regulated as a dangerous good

RID : Not regulated as a dangerous good
IMDG : Not regulated as a dangerous good
IATA (Cargo) : Not regulated as a dangerous good
IATA (Passenger) : Not regulated as a dangerous good
14.5 Environmental hazards
Not regulated as a dangerous good
14.6 Special precautions for user
Not applicable
14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable for product as supplied.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
UK REACH List of substances subject to authorisation : Not applicable
(Annex XIV)
UK REACH Candidate list of substances of very high : Not applicable
concern (SVHC) for Authorisation
The Persistent Organic Pollutants Regulations (retained : Not applicable
Regulation (EU) 2019/1021 as amended for Great
Britain)
UK REACH List of restrictions (Annex 17) : Not applicable
GB Export and import of hazardous chemicals - Prior : Not applicable
Informed Consent (PIC) Regulation

Control of Major Accident Hazards Regulations Not applicable

2015 (COMAH)

15.2 Chemical safety assessment

A Chemical Safety Assessment is not required for this substance.

SECTION 16: Other information

Full text of other abbreviations

GB EH40 : UK. EH40 WEL - Workplace Exposure Limits
GB EH40 / TWA : Long-term exposure limit (8-hour TWA reference period)
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways; ADR - Agreement concerning the International Carriage of Dangerous Goods by
Road; AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Test-
ing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regulation; Regula-
tion (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard

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SAFETY DATA SHEET

112339000 SEMIDOL K 2

Version Revision Date: SDS Number: Date of last issue: -

1.0 30.10.2023 PR-1123390 Date of first issue: 30.10.2023
(CLP_GB)

of the German Institute for Standardisation; DSL - Domestic Substances List (Canada); ECHA -
European Chemicals Agency; EC-Number - European Community number; ECx - Concentration
associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergen-
cy Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration as-
sociated with x% growth rate response; GHS - Globally Harmonized System; GLP - Good La-
boratory Practice; IARC - International Agency for Research on Cancer; IATA - International Air
Transport Association; IBC - International Code for the Construction and Equipment of Ships car-
rying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - Interna-
tional Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China;
IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL
- Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization;
KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test popula-
tion; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - Interna-
tional Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified;
NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Ef-
fect Level; NOELR - No Observable Effect Loading Rate; NZIoC - New Zealand Inventory of
Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office
of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic sub-
stance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quanti-
tative) Structure Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European
Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Re-
striction of Chemicals; RID - Regulations concerning the International Carriage of Dangerous
Goods by Rail; SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet;
SVHC - Substance of very high concern; TCSI - Taiwan Chemical Substance Inventory; TECI -
Thailand Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN
- United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous
Goods; vPvB - Very Persistent and Very Bioaccumulative

Further information

The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

GB / EN

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