CHM 2045

Final Exam

Spring 2009

Form Code A

Instructions: On your scantron enter and bubble in your name, UF ID number, and Form Code (see above). Careful! Bubbling errors will not be negotiated. 1. A sample of zinc metal reacts completely with an excess of hydrochloric acid: Mn(s) + 2HCl(aq) MnCl2(aq) + H2(g) The hydrogen gas produced is collected over water at 25.0C. The volume of the gas is 7.80 L, and the pressure is 0.980 atm. Calculate the mass (g) of manganese metal consumed in the reaction. (Vapor pressure of water at 25C = 23.8 mmHg.) (1) 4.6 g Mn (2) 16.6 g Mn (3) 19.8 g Mn (4) 21.7 g Mn (5) 24.6 g Mn 2. The boiling point of a glucose solution (d = 1.16 g/mL) is 100.21 C. Calculate the osmotic pressure of that solution at 298K. (glucose = 180.2 g/mol ; kfp for water = 1.86 oC/m ; kbp for water = 0.520 oC/m) (1) 9.4 atm (2) 10.5 atm (3) 157 atm (4) 2.99 atm (5) 31.6 atm 3. What is the strongest intermolecular force that exists between SO2 and I2? (1) dipole-dipole (2) ion-dipole (3) London dispersion (4) dipole-induced dipole (5) ion-induced dipole 4. The solubility of NH4Cl at 20C = 37g per 100 g H2O. If a solution is prepared by dissolving 95 g of NH4Cl in 200.0 g H2O at 60C, what mass of NH4Cl will recrystallize when the solution is cooled to 20C? (1) 21 g (2) 58 g (3) 37 g (4) 74 g (5) 48 g 5. Copper crystallizes in a face-centered cubic unit cell, and copper has an atomic radius of 128 pm. What is the density of copper? (1) 1.35 g/cm3 (2) 2.71 g/cm3 (3) 4.98 g/cm3 (4) 7.66 g/cm3 (5) 8.90 g/cm3 6. Arrange NH3, PH3, and CH4 in order from lowest to highest boiling point. (1) PH3 < CH4 < NH3 (2) NH3 < CH4 < PH3 (3) CH4 < NH3 < PH3 (4) PH3 < NH3 < CH4 (5) CH4 < PH3 < NH3 7. Predict the formula of a tellurium-fluorine molecule (or ion) with a square pyramidal molecular geometry. (1) TeF5 (2) TeF5 (3) TeF5+ (4) TeF4 (5) TeF6 8. Which of the following diatomic species are predicted by molecular orbital theory to be stable? He2+2; He2 ; He2+1 (orbital sequence: 1s, *1s, 2s, *2s) (1) He2+2; He2 ; He2+1 (2) He2+2; He2 (3) He2 ; He2+1 (4) He2+1 (5) He2+2; He2+1 9. A mixture of butene, C4H8, and butane, C4H10, is combusted. When 2.86 g of the mixture is combusted, 8.80 g of CO2 is produced. What is the mass % of butene in the mixture closest to? C4H8(g) + 6 O2(g) 4 CO2(g) + 4 H2O(g) 2 C4H10(g) + 13 O2(g) 8 CO2(g) + 10 H2O(g) (1) 44.8% butene (2) 55.6% butene (3) 27.6% butene (4) 72.4% butene (5) 88.7% butene 10. NH3(g) reacts with O2(g) to produce NO(g) and H2O(). The maximum mass of NO(g) which can be produced from a reaction mixture of 2.00 mol each of ammonia and oxygen is closest to (1) 30.0 g (2) 24.0 g (3) 17.0 g (4) 37.5 g (5) 48.0 g 11. If 130.5 mL of 1.50 M K2Cr2O7 is added to a 500-mL volumetric flask and diluted to the mark with thorough mixing, the potassium ion concentration, [K+], in the resulting solution will be closest to (1) 0.180 M (2) 0.360 M (3) 0.783 M (4) 3.00 M (5) 12.5 M 12. A 12.000 g sample of CoCl2xH2O is dried in an oven. When the anhydrous salt is removed from the oven, its mass is 7.718 g. What is the value of x? (1) 1 (2) 2 (3) 3 (4) 4 (5) 6 13. The density of carbon tetrachloride is 1.59 g/mL. How many chlorine atoms are present in 155 mL of carbon tetrachloride? (1) 3.4 1023 atoms (2) 5.4 1023 atoms (3) 1.4 1024 atoms (4) 8.1 1027 atoms (5) 3.9 1024 atoms 14. An equilibrium mixture for the reaction 2H2S(g) 2H2(g) + S2(g) was found to contain 1.0 mol H2S, 4.0 mol H2, and 0.80 mol S2 in a 4.0 L vessel. Calculate the equilibrium constant, Kc, for this reaction. (1) 1.6 (2) 3.2 (3) 12.8 (4) 0.64 (5) 0.8 15. Which of the following is paramagnetic? (1) Mg (2) Mg2+ (3) Mn4+ (4) Ti4+ (5) Zn2+

Form Code A 16. A rate constant obeys the Arrhenius equation, the factor A being 2.2 1013 s-1 and the activation energy being 150. kJ mol-1. What is the value of the rate constant at 227C, in s-1? (1) 2.1 1013 s-1 (2) 6.7 10-22 s-1 (3) 1.5 1011 s-1 (4) 4.7 10-3 s-1 (5) 5.7 10-4 s-1 17. The half-life for the decomposition of P2O5 is 1400 s and has a rate = k [P2O5]. About how long does it take for the P2O5 concentration to drop from 3.0 M to 0.3 M? (1) 200 s (2) 3000 s (3) 4000s (4) 4208 s (5) 4600 s 18. From the experimental data tabulated in question 20 determine the rate law. (1) rate = k [A] [B]2 [C] (2) rate = k [A]2 [B] [C] (3) rate = k [A]2 [B] [C] 2 2 (4) rate = k [A] [B] [C] (5) rate = k [A] [B] [C]2 19. From the experimental data tabulated in question 20 determine the rate constant. (1) 2.0 (2) 3.0 (3) 4.0 (4) 8.0 (5) 16.0 20. Determine the missing Initial Rate for Experiment 5 in the experimental data tabulated below. (1) 2.5 x 10-2 mol/L s (2) 4.0 x 10-2 mol/L s (3) 4.0 x 10-1 mol/L s (4) 2.9 x 10-2 mol/L s (5) 1.6 x 10-2 mol/L s Exp. 1 2 3 4 5 Initial [A] (mol/L) 0.10 0.20 0.20 0.10 0.15 Initial [B] (mol/L) 0.10 0.10 0.20 0.10 0.15 Initial [C] (mol/L) 0.10 0.10 0.10 0.20 0.40 Initial Rate (mol/L s) 8.0 x 10-4 1.6 x 10-3 3.2 x 10-3 3.2 x 10-3 ???????

21. When solid ammonium nitrate was dissolved in 125 g of water in a coffee-cup calorimeter of negligible heat capacity at an initial temperature of 23.5 C, the water lost 5.28 kJ of thermal energy. What was the final temperature of the solution (the specific heat of the solution = 4.184 J/gC)? (1) 13.4 C (2) 33.6 C (3) 10.5 C (4) 36.9 C (5) 23.4 C 22. Liquid NCl3 in a 2.50 L closed container is heated until it decomposes completely to gaseous products. The resulting mixture exerts a pressure of 422 mm Hg at 95 oC. What was the mass of the original sample? (1) 3.54 g (2) 5.34 g (3) 2.76 g (4) 4.89 g (5) 10.3 g 23. The electron-pair geometry of sulfur tetrachloride (SCl4) is best described as (1) tetrahedral (2) trigonal bipyramidal (3) square planar (4) see-saw (5) octahedral 24. Consider the heterogenous equilibrium: CaCO3(s) CaO(s) + CO2(g) At 800C, the pressure of CO2 is 0.236 atm. Calculate Kc for the reaction at this temperature. (1) 0.236 (2) 2.36 x 10-3 (3) 2.68 x 10-3 (4) 0.286 (5) 0.118 25. There is one atom of cobalt in each molecule of vitamin B12. The mass percent of cobalt in vitamin B12 is 4.34 %. Calculate the molar mass of vitamin B12. (1) 58.9 g/mol (2) 257 g/mol (3) 1.36 x 103 g/mol (4) 2.72 x 103 g/mol (5) 4.34 x 103 g/mol 26. In which of the following molecules would you expect the nitrogen-to-nitrogen bond to be the shortest? (1) N2 (2) NO2 (3) N2O4 (4) N2H4 (5) all the same 27. Given the average bond dissociation enthalpies provided of the data sheet, estimate the closest value to the standard molar enthalpy of formation of chlorine trifluoride, ClF3(g). (1) 765 kJ/mol (2) 363 kJ/mol (3) 147 kJ/mol (4) 405 kJ/mol (5) 810 kJ/mol 28. The energy from condensing steam water is used to melt ice at 0oC. How much ice can be melted by condensing 334 g of H2O vapor? (Hfus of ice = 6.01 kJ/mol Hvap of water = 40.7 kJ/mol) (1) 6.77 kg (2) 23.4 kg (3) 0.148 kg (4) 2.26 kg (5) 0.336 kg 29. In a fireworks device, the heat of reaction between a strong oxidizing agent and an organic fuel excites the metal ion in the salt. In this case, 1.40 g of strontium chloride salts are used, and red light is observed. Considering that all metal ions become excited and each excited ion emits a single photon at 439 nm, what is the total energy released ? (1) 4.36 kJ (2) 2.41 kJ (3) 2406 kJ (4) 4.00 x10-24 kJ (5) 7.23 x10-21 kJ