Jr.

INTER CHEMISTRY MODEL PAPER

INTERMEDIATE PUBLIC EXAMINATIONS, MARCH 2012
CHEMISTRY PAPER I
(ENGLISH VERSION)
TIME: 3 HOURS
Max. MARKS: 60
SECTION A
Very Short Answer Type Questions
10 2 = 20
Note: Answer all Questions
1. What are the Coordination numbers of NaCl and CsCl
Crystals?
2. What is 'deuterolysis'? Give an equation for deuterolysis?
3. Which of the two ions Ca+2 and Zn+2 is more stable? Why?
4. Calculate oxidation numbers of N in NH4NO2 and Mn in
KMnO4?
5. State Dalton's Law of partial pressures?
6. Give two effects of acid rains.
7. What is 'Wurtz reaction'?
8. Give the formulae of 'Beryl' and 'Barytes'
9. Define B.O.D. and C.O.D.
10. What is Ozonolysis? Name the products formed on
Ozonolysis of C2H4 followed by hydrolysis?

SECTION B
Short Answer Type Questions
Note: Answer any six questions
6 4 = 24
11. Write the MOED of N2
12. Balance the following equation in acid medium by
ion electron method
+2 + SO -2
MnO4- + SO-2
3 Mn
4
13. State 'Graham's law of diffusion. 100 cm3 of CO2 gas is diffused in 25 seconds through a porus membrane. How much
time does the same volume of SO2 take to diffuse?
14. How does H2O2 react with the following
a) Cl2 b) Ag2O c) KI d) PbS
15. Give the Chemical reactions of outer compartment and
middle compartment in the manufacture of NaOH by
Castner-Kellner Process. How does NaOH reacts with
NH4Cl?
16. Explain the structure of Diborane.
17. Give one method of preparation of Ethylene. Give the
equation for the reactions of ethylene with

INTERMEDIATE PUBLIC EXAMINATIONS, MARCH 2012

{ - B
yp - vo
: C- 6 vo- -- . 6 4 = 24
11. N2 Js- h-n Eo U.
12. x - C u ----Z l-A u
.

CHEMISTRY PAPER I
TIME: 3 HOURS

(TELUGU VERSION)

{ - A

Max. MARKS: 60

A-yp - vo
10 2 = 20
: Eo vo- --Ly
1. NaCl, CsCl p -Jf-- u- -.
2. 'u--L- N? DE T O----Eo-y.
3. Ca+2, Zn+2 -x n-i C?-x?
4. NH4NO2 N, KMnO4 Mn q-- u \-.
5. d ~ - E-Eo -.
6. x--{ p-L- -E -.
7. 'd- u N?
8. 'j , 'j- t-- .
9. B.O.D., C.O.D. Ey-*-.
10. '--L- N, C2H4 -L- , y
Nx- h p -n--N?

+2 + SO -2
MnO4- + SO-2
3 Mn
4

. 'v u E-Eo -. 100 .O.3 CO2

-*av - y 25 -x -u- --C- -- -Jn-x
-- - -J--- --o SO2 u
C?
14. C- H2O2 J u- N-J-.
13

a) Cl2

b) Ag2O

c) KI

d) PbS

15.

do---o l-A NaOH E -----p , u

x J - u -.
NH4Cl NaOH u --C?
16. j- Et-Eo N-J-.

Sr. INTER CHEMISTRY MODEL PAPER

INTERMEDIATE PUBLIC EXAMINATIONS, MARCH 2012
CHEMISTRY PAPER II
(ENGLISH VERSION)
TIME: 3 HOURS
Max. MARKS: 60
SECTION A
Very Short Answer Type Questions
10 2 = 20
Note: Answer all Questions
1. What are isotonic Solutions?
2. Find the molarity of a mixed solution formed by adding 250 ml
of 0.2M NaOH to 100 ml of 0.5M NaOH Solution.
3. What are Lewis acids and Lewis bases?
4. Find the pH of 0.005M Ba(OH)2 solution?
5. Write the systematic names for the following?
(a) K3 [Fe (CN)6] (b) [Co (NH3)3 Cl3]
6. What are food preservatives? Give 2 examples.
7. What is Paracetamol? How is it prepared?
8. What is vulcanization? Name 2 compounds that can
INTERMEDIATE PUBLIC EXAMINATIONS, MARCH 2012
CHEMISTRY PAPER II
(TELUGU VERSION)
TIME: 3 HOURS
Max. MARKS: 60

{ - A
A yp - vo
10 2 = 20
: Eo vo- --
1. --E v- N?
2. 250 N.M. 0.2M NaOH v-Eo 100 N.M. 0.5M NaOH
v-E -L- p- Nv v -J ?
3. x, ~- N?
4. 0.005M Ba(OH)2 v pH N ?
5. -C t--- j l-A x .
(a) K3 [Fe (CN)6]

6.

(b) [Co (NH3)3 Cl3]

Ey--- N? ----L-y.
7. - -- N? Eo ---h?
8. \-j-- N? DEo - E --Lq
j -n- -.
9. Lx N? j @-- N -.

accelerate this process?

9. What are lipids? Give two biological functions of lipids?
10. What is insulin? Give its structure.
SECTION B
Short Answer Type Questions
6 4 = 24
Note: Answer any six questions
11. Derive Bragg's equation?
12. State and explain Faraday's second law of electrolysis. At
25C the equivalent conductances of Sodium acetate,
Hydrochloric acid and sodium chloride at infinite dilution
respectively are 91.0, 426.16, 126.45 ohm-1 cm2. Calculate
o of CH3COOH.
13. Explain the terms a) Emulsion b) Coagulation
c) Hardy-Schulze rule
d) Gold number
14. State Hess's Law of constant heat summation and explain
with one example. Give 2 applications of it.
15. Discuss froth flotation process. Mention the functions of pine
10

. q-L N? DE Et-Eo -.
{ - B
yp - vo
: j vo- -- 6 4 = 24
11. v O---Eo p-C-.
12. Nu-Cy-x- E-Eo -. 25C l
NM -, jv-x-J-x, xj
v- u -- - 91.0, 426.16, 126.45
1 .O.2 CH3COOH o N ?
13. *a - N-J-.
) -{ G) \ ) Kf-b E ) f u
14. g - E-Eo L, --- N-J-.
DE --h-- -.
15. x vv J* -. vv- j ,
j b- v -.
16. p j J-v-N- ---h?
17. o l v L- t-- Et--

a) hypohalous acid and b) Cold, dil. alk. KMnO4

18. Discuss Markownikoff's rule and Kharasch effect.
SECTION C
Long Answer Questions
2 8 = 16
Note: Answer any Two Questions
19. Mention quantum numbers. Explain the significance of
various types of quantum numbers.
20. a) Write MOED of O2
b) What is hybridization? Mention the types of hybridization
of Central atom in BeCl2, BCl3 and NH3.
21. What is periodic property? How do the following properties
change in a group and period? Explain:
a) Atomic radius b) Ionisation potential and
c) Electronegativity
17.

C-M- - l-AE -.
j-- x b) xE, NM, ~ KMnO4 C J
u O---- -.
18. \-E- E, v-- Ja-.
{ - C
D` vo
: j vo- - . 2 8 = 16
19. y u- \-. NN y u
vuEo N-J-.
20. a) O2 Js- h-n Eo U.
b) -K-- N? BeCl2, BCl3 , NH3 -- xE v--- -K---- -.
21. -h t N? -C t v, J--x N-
-.
a) - ul
b) -j-- -E{-
c) Nut-
a)

oil and Sodium ethyl Xanthate in this process.

16. Explain how Super phosphate of lime is manufactured?
17. Explain the structures of the following complexes using
Werner's theory?
a) CoCl3.6NH3 b) CoCl3.5NH3 c) CoCl3.4NH3 d) CoCl3.3NH3
18. Explain a) Clemmenson reduction b) Reimer-Tieman reaction.
SECTION C
Long Answer Type Questions
Note: Answer any Two Questions
2 8 = 16
19. a) How is bleaching powder prepared industrially?
b) Give the reactions of Ozone with the following and give
equations.
i) KI
ii) PbS
iii) Hg iv) SO2
20. Discuss the Collision theory of reaction rates. Support your
explanation with a relevant diagram.
21. Explain the preparation of ethyl alcohol from Molasses.
Explain the reactions of ethyl alcohol with
a) CH3MgI
b) CH3COOH c) PCl3
d) Conc. H2SO4 at 170C

N-J-.
) CoCl3.6NH3 G) CoCl3.5NH3
) CoCl3.4NH3
-) CoCl3.3NH3
18. ) x-q ~-- G) K--- u- NJ.
{ - C
D` - vo
: j vo- -- . 2 8 = 16
19. ) J-v-N- Hx* ---h?
G) C- J u -.
i) KI

20

ii) PbS

iii) Hg

iv) SO2

. -u- G-- l--E u-Lo -.

O N-- -Jn-.
21. - * j \- -- N-Eo
NJ. j \- C- J u -.
) CH3MgI
G) CH3COOH
) PCl3
) 170C l H2SO4
(- --- -v-o-v-- -NZ -E- -a
...- --C-.)