DETERMINATION OF MOLARITY AND STRENGTH OF KMnO4 BY USING M/20 SOLUTION OF
FERROUS AMMONIUM SULPHATE (MOHR'S SALT) SOLUTION:
AIM: Determinationof molarity and strength of kmno4 by using m/20 solution of ferrous
ammonium sulphate (mohr's salt) solution
CHEMICAL EQUATIONS:
Molecular Equations:
2 KMnO4 + 3H,S0,-’ K,SO, + 2MnsO4 +3H,0 +5[0]
10 FesO,.(NH);SO,.6H,0 +5H,S0, +5[o}’ S Fe,(5O.), +10 (NHA),SO, +65 H;0
2KMnO, + SH2504 +10 FeSO.(NHa);SO,.6H,0- K,SO,+ 10 (NH),SO,+ 2Mns04 +68 H,0
lonic equations:
MnO, + 8H* + 5e-’ Mn +4H,0
5Fe5Fe +5e
MnO, + 8H*+ 5Fe*Mn +4H,0 + 5Fe*
APPARATUS:
Beakers (250ml), pipette (20ml), burette (50ml),burette stand, White tile
CHEMICALS REQUIRED:
KMn04 Solution ( Test solution), M/20 Solution of Mohr's salt
INDICATOR:
KMnO, is a self indicator
END POINT:
Colourless to permanent pink colour (KMn04 in burette)
PROCEDURE:
out 20ml of each in a titration
1. Rinse the pipette with M/20Mohr's salt solution and pipette
flask
2. Rinse and fill the burette with the given KMnO4solution.
the solution in titration flask
3. Add one test tube (nearly 20 ml) full of dilute sulphuric acid to
4. Note the intial reading of the burette
is imparted to the
5. Now add KMn0,solution from the burette till a permenent light pink colour
solution un the titration flask on addtion of last single drop of KMnO4solution
6. Note the final reading of the burette
7. Repeat the above steps 4 to 5 times to get a set of three concordant readings
VOLUMETRIC ANALYSIS
Aim:_To prapare M/20 solution of Ferrous ammonium sulphate(Mohr's salt )& to determine the
Molarity and strength of given potassium permanganate solution by using M/20 soution of
Ferrousammonium sulphate (Mohr's salt).
PREPARATION OF M/20SOLUTION OF MOHR'S SALT:
Theory:
Molecular mass of Mohr's salt, FeSO,.(NHa),SO4.6H,0 = 392
W 1000
M=
GMW V(in ml)
MX GMW XV 0.05 X 392 X 250
W(Mohr's salt required) 1000 1000
=4.9 g.
Weight of watch glass (Wi) = 12.8g
Weight of watch glass + salt (W,) =17.7g
Weight of Mohr's salt (W,-Wi) = 4.9 g
APPRATUS:
Watch glass, weight box,fractional weight box, 250 ml beaker, glass rod, 250ml measuring flask
& wash bottle.
CHEMICALS REQUIRED:
Mohr'ssalt, Conc.H2S04 & Distilled water
PROCEDURE:
1.Weight the clean and dry watch glass & recoed it's weight in the note book.
2.weight accurately 4.9 g of Mohr's salt crystals on the watch glass &record the weightin the note
book.
3.Transfer carefully the weighted Mohr's salt from the watch glass into a clean 250 ml beaker.
Add to this beaker about 5 ml of Conc.H2S04 to check the hydrolysis of the ferrous sulphate.
4.wash the atch glass thoroughly with distilled water to transfer the sticking salt completely into
the beaker.Dissolve the salt in the beaker with gentle stirring.
5. Transfer the entire solution carefully into 250 ml measuring falsk through afunnel.
6.Wash the beaker with distilled water and transfer the washings into the measuring flask.
7.Add enough distilled water to the measuring flask carefully upto just below the etched mark on
it's neck with the help of wash bottle.
8.Add the last few drops distilled water with a pipette until the lower level of the meniscus just
touches the mark on the measuring flask.
9.stopper the measuring flask and shake it gently to make the solution homohgeneous and label it
as M/20 Mohr's salt solution
OBSERVATIONS:
1.Volumne of Mohr's salt solution prepared = 250 ml
2.Molarity of Mohr's salt solution = M/20
3.Volume of Mohr's Salt solution taken for each titration = 20 ml
Burette Reading
S.NO. VOLUME OF MOHR'S SALT Volume of KMnO4 solution (in
SOLUTION (in ml) Initial Final ml)
reading reading (Final reading -Initial reading)
20ml Oml 20.1ml 20.1ml
2 20ml 20.1ml 40.3 ml 20.2ml
3 20ml Oml 20.2ml 20.2ml
20ml 20.2ml 40.4ml 20.2ml
(concordant reading = 20.2ml)
Ferrous ammonium sulphate (Mohr's salt): KMnOa:
MË= Molarity of Mohr's salt solution = M/20 M, = Molarity of KMnO, =?
V,= volume of KMnO, solution = 20.2ml
V= volume of Mohr's salt solution = 20 ml
n,= no of mloes of Mohr's salt solution =5 n,= no of moles of KMnO, solution =1
M1V1 M2V2
FORMULA:
n1 n2
M1X V1 X n2 0.05 X 20 X1
= 0.0099M
V2 X n1 20.2 X 5
Molarity of KMn0, solution = 0.01M
mass
Strength of of the KMnO, solution (in g/ml) = Molarity XMolar
= 0.0099 X 158 =1.564 g/lit
RESULT: 1) Molarity of KMnO4 =0.0099M
2) Strengthof KMnO4 solution = 1.564 g/lit
SALT-1
AIM: TO IDENTIFY THE ACIDIC&BASIC
RADICALS IN THEGIVEN SALT
PRELIMINARY TEST:
S.NO EXPERIMENT OBSERVATION INFERENCE
1 COLOUR COLOURLESS ABSENCEOF Cu*,Ni.
Fe?,Fe,Mn,& Co?
2 ODOUR AMMONICAL SMELL IS May be NH, is present
OBSERVED
3 SOLUBILITY SOLUBLE INCOLD WATER
4 ACTION OF HEAT: AGASIS EVOLVED WITH May be NH, ispresent
AMMONICAL SMELL
IDENTIFICATION OF ACIDIC RADICAL:
S.NO EXPERIMENT OBSERVATION INFERENCE
2
1 Dilute H2S04 TEST: No gas is evolved Absence of CO,, So,, s
Toa little amount of salt taken NO,
in atest tube add dil H2S04
2 Conc.H2SO4 TEST: To a little Colourless gas with May be C> is present
amount of salt taken in atest pungent smell is evolved
tube add Conc.H2S04 and heat
it.
Confirmation test for Cl: A white precipitate is CI is confirmed
3
Silver nitrate Test: formed which is soluble in
To a little salt solution taken in NH40H
a test tube few ml of dil HNO3
& AgNO3 solution is added
CHEMICAL EQUATIONS:
i)cr + H,SO HSO, + HCI ii) cr + AgNO,’ AgCl + NO
iii) AgCi + 2NH,OH ’ [Ag (NH,)>]Cl + 2 H,0
(soluble complex)
IDENTIFICATION OF BASIC RADICAL:
S.NO EXPERIMENT OBSERVATION INFERENCE
1 TEST FOR NHAION: Agas with ammonical smell May be NH, IS PRESENT
Alittle amount of salt is heated is observed which give
with Conc NaOH white fumes when a glass
rod dipped in dil HCl is kept
near the mouth of the test
tube
2 Confirmation test for NH, :
Nessler's reagent Test: A
brown precipitate is NH,is confirmed
Tothe salt solution taken in a formed
test tube nessler's reagent is
added
CHEMICAL EQUATIONS:
1) NH,Cl + NaOH’ NaCl + H,0 + NH,
2) NH + HCI ’NH,CI
3) 2 K,[Hgla] + NH, + 3KOH ’ H,N.Hg0.Hgl + 7 KI +2H,0
(Brown PPT)
RESULT:
The given salt contain i)acidic radical cr (chloride ion)
ii) Basic radical NH (Ammonium ion)
IDENTIFICATION OF FUNCTIONAL GROUP PRESENT IN THE ORGANIC
COMPOUND
Aim: To identifythe functional group present in
the organic compound.
Physical Examination:
S.NO EXPERIMENT OBSERVATION INFERENCE
PHYSICAL STATE LIQUID STATE BENZOIC ACID IS ABSENT
2 IGNITIONTEST: ASMALL Compound burns with non May be aliphatic organic
QUANTITY OF ORGANIC smoky flame compound.
COMPOUNDISTAKEN IN
A
SPATULA AND BURN IT
SOLUBILITY:
SOLVENTS FUNCTIONAL GROUP
H20 ETHER NaOH NaHCO3 DilHCI May be aliphatic alcohol
Functional group analysis:
S.NO EXPERIMENT OBSERVATION INFERENCE
1 Na (sodium)MetalTest: T Evolutionof gas is observed May be aliphatic alcohol
the or qanic Compond
add Snali peiadSdiumme
2 ESTERIFICATION TEST:A Fruity snmell ester is formed aliphatic alcohol is confirmed.
small compound of
organic compound is
taken in test tube, add
acetic acid and few drops
of Con H,SO, and heat it.
Result: The give organic compound contains" ALIPHATIC ALCOHOL
"functional group.
