No.

EX-230339
Issued [Link].2003

TECHNICAL LEAFLET :

PENGUIN FOAM #3151 (E)

Formed In-Place Gasket System
( Mechanical Foaming )

Braking-Sunstar S.p.A
Pirolweg 21, D-97990 Weikersheim, Germany Checked by :
( M. Takada )
Tel. +49 79 34 99 39 11
[Link]@[Link] Prepared by :
( S. Bessho )
TECHNICAL DATA PENGUIN FOAM SYSTEM

Outline
PENGUIN FOAM SYSTEM provides uniform foam by mixing single component paste materials with gas,using our patented
mechanical foaming device, FOAMPLY .this unique system, is an innovative foaming system , that could be used on a wide
range of manufacturing processes such as mould injection , foam filling and/or molding and as robot applied gasket. This new
system is totally environmentally friendly with no toxic waste or poisonous gas and it improves your working environment and
contributes the waste reduction.
The single component urethane paste PENGUIN FOAM ; Due to our own developed catalyst , PENGUIN FOAM
reacts to high elastic formed elastomer , instantly after be exposed to heat of 80℃. This new flexible formed elastomer system
enables you to optimize manufacturing processes , improve products quality and reduces largely the production costs.
Mechanical Foaming Unit FOAMPLY
Gas injection cylinder Robot Application
ST
Pre-mixer
Compressed
Compressed Flow control cylinder
Air Gun
Air

One component polyurethane

PENGUIN FOAM
Ｍ
To aging process:
Heat curing type
Foaming Gasket -PENGUIN FOAM #3150(Low hardness)
Foaming Elastomer -PENGUIN FOAM #3151(Low hardness)
-PENGUIN FOAM #3160(High strength)
Moisture curing type
-PENGUN FOAM #3112(Low hardness)
Primary pump

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TECHNICAL DATA PENGUIN FOAM SYSTEM

Feature of PENGUIN FOAM #3151

Elastic material enabling the snap curing(a few minutes at 80 degrees C) and superior adhesion
to various types of plastic materials. It provides 1 part superior applicability compared to two part
type materials. Also Penguin Foam#3151 possesses enhanced heat resisting property which has
never been achieved with urethane materials before.

• 1 Component: No need for controlling pot life which plagued 2 part type applications.
Also the time it takes for the maintenance of mixing part and purging can be greatly reduced.
• Low [Link] curing: We have developed the original curing agent technology which enable
fast curing at 80 degrees to produce the elastic state of the cured material.
Urethane Polymer
Cure • Low temp. curing is compatible with plastic which easily
deforms from the heating of ordinary curing material(20～30
minutes at 140 degrees)
<5 seconds at 80 degrees full cures 500μm this layer>
（ more than •Stable at room temperature(20 -30°C)
80°
Curing agent(capsule) °C ) Fast Cure
• Micro Capsule foaming: The specialized mechanical foaming system provides micro cell foaming.
The robot application(foaming) at room temperature enables string(line) formation, injection molding,
foam filling, and other molding applications.
• Low hardness: PENGUIN FOAM #3151 demonstrates flexible rubber like property and provides very good
gasket applications. Foaming magnification rate can be easily adjusted with the setting of the special
equipment.(up to 300％)
(Enhanced heat resisting property)
Also it has achieved far enhanced heat resisting property compared to #3150(the same type but old).

EX-230339 ([Link].2003) SUNSTAR ENGINEERING INC. R&D Center

TECHNICAL DATA PENGUIN FOAM SYSTEM

PENGUIN FOAM #3151Typical Properties

( Heat curing / Low hardness Type )

PENGUIN FOAM PENGUIN FOAM

Properties Test Method
#3151 #3150
Appearance Black paste Gray paste Visual

Physical Density 20℃ 1,16 1,17 JIS K6833 Density cup method
property Viscosity 20℃ 100 Pa･s 70 Pa･s JIS K6833 Brookfield BHtype viscometer, spidleNo.7, 20rpm

Non-Volatile content 105℃3hours 99,9% 99,9% JIS K6833 (1atm., 105℃×３hours)

Tack free time 20℃65%RH 24hours over 24hours over JIS A5757

Perfor- Hardness Asker C 65 60 JIS K6253 Asker C durometer hardness tester

mance
Tensile strength 2.5 MPa 1.6 MPa JIS K6251 Dumbbell#2 Curing condition:80℃×10min
(Non-
foamed) Elongation 300% 250% Cross-head speed of 200mm/min

Cure condition 80℃×5min. 80℃×5分 Bead size: W8mm, H4mm (80℃ oven)

Hardness Asker C 17 16 JIS K6253 Asker C durometer hardness tester

Elongation 0.28 MPa 0.25 MPa JIS K6251 Bead size: W8mm, H4mm, length 50mm

Perfor- Curing time 180% 180% Curing condition:80℃×10min, Cross-head speed of 200mm/min
mance 20℃24hours 8% 9% JIS K6262 Bead size: W8mm, H4mm, length 50mm
(Foamed) Compression set
Foaming 80℃24hours 10% 80% Compression ratio 50%
ration=3.0
Water absorption 20℃water 24hours 3% 4% JIS K6911 Bead size:W8mm,H4mm,length 50mm Non-compression

Ozone Resistance 40℃24hours Non-crack Non-crack JIS K6259 Ozone concentration50±5pphm, 20%tensile

Weathering Test Weather meter500H Non-change Non-change JIS D0205 Sunshine Weather meter (Black panel temp.63℃)

EX-230339 ([Link].2003) SUNSTAR ENGINEERING INC. R&D Center

TECHNICAL DATA PENGUIN FOAM SYSTEM

Gas Pressure and Foaming Magnification

Test Result Test Method

• Material : PENGUINFOAM#3151
4.0
(Heat curing type Urethane resin)
#3151 #3150 PENGUINFOAM#3150
Foaming Magnification (times)

3.5 (Heat curing type Urethane resin)

• Test Method :
3.0 Gas pressure force to introduce into machine foaming
equipment "FOAMPLY" varies, and foaming magnification
(the measurement by a specific gravity cup) is measured.
2.5

*Gas pressure is material determining mixing ratio of

2.0 material in equipment and air,
and foaming magnification on calculation is demanded
by the following equation
1.5 Foaming magnifications =(Gas pressure ×10.2)+ 2
0.00 0.05 0.10 0.15 0.20

Gas Pressure (MPa)

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TECHNICAL DATA PENGUIN FOAM SYSTEM

Foaming Magnification and Hardness

Teat Result Test Method

• Material : PENGUINFOAM#3151
80 (Heat curing type Urethane resin)
PENGUINFOAM#3150
70 #3151 #3150 (Heat curing type Urethane resin)

60
• Test Method :
Hardness (Asker C)

50
•Test Piece Figure 1.

40
•Temperature 20℃

30
•Method JIS K6253
Asker C durometer Hardness Tester
20
Figure 1.
Φ60mm
10

0
1.0 1.5 2.0 2.5 3.0 3.5 48mm

Foaming Magunification (times)

EX-230339 ([Link].2003) SUNSTAR ENGINEERING INC. R&D Center

TECHNICAL DATA PENGUIN FOAM SYSTEM

Compressive Stress

Test Result Test Method

• Material : PENGUINFOAM#3151
160 (Heat curing type Urethane resin)
PENGUINFOAM#3150
#3151(3.0 times) (Heat curing type Urethane resin)
140
#3151(2.0 times)
120 #3150(3.0 times) • Test Method :
Compressive-stress (N/50mmL)

#3150(2.0 times)
100 •Test Piece Figure 1.

80 •Temperature 20℃

60 •Method
Test piece is set to Instron-tester, and stress
40 in compression is measured. It is compressed every
10%, and it is data sampling after one minute
20 Test speed is about 3-5 mm/min (manual operation)
Figure 1.
0
0 20 40 60 80 4mm
50mm
Compression Rate (%)
8mm

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TECHNICAL DATA PENGUIN FOAM SYSTEM

Compression Set (Temperature dependence)

Test Result Test method

100 • Material : PENGUINFOAM#3151

(Heat curing type Urethane resin)
90 #3151(2.0 times) PENGUINFOAM#3150
#3151(3.0 times) (Heat curing type Urethane resin)
80
#3150(2.0 times)
• Test Method :
Compression Set (%)

70 #3150(3.0 times)
•Test Piece W:8∗H:4mm bead
60

50 4mm

40 50mm
8mm
30
•Heat cure condition 80℃5min (After room temp 24h)
20

10 •Compression Times 22 hours

0 •Compression Ratio 50%

0 20 40 60 80 100 120
Temperature (°C)

EX-230339 ([Link].2003) SUNSTAR ENGINEERING INC. R&D Center

TECHNICAL DATA PENGUIN FOAM SYSTEM

Water Tightness

Test result Test method

• Material : PENGUINFOAM#3151
#3151(2.0 times) #3151(3.0 times) (Heat curing type Urethane resin)
#3150(2.0 times) #3150(3.0 times) PENGUINFOAM#3150
(Heat curing type Urethane resin)
0 • Test Method :
-5 •Test Piece W:8∗H:4mm bead 4mm
Water lebel-variation (mm)

-10
50mm
-15 •Temperature 20℃ 8mm
-20
-25
-30

spacer

spacer
-35 100mm

-40
-45
•Method
-50 By means of jig such as for example fig (10*100*150mmt
0 20 40 60 80 acrylic board), gasket is put with each coefficient of
compressibility. Water is poured into needing with
Compression Rate (%)
100mm depth from gasket bottom, water-level variation
after 24 hours is measured.

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TECHNICAL DATA PENGUIN FOAM SYSTEM

Air Tightness

Test result Test Method

• Material : PENGUINFOAM#3151
(Heat curing type Urethane resin)
20 PENGUINFOAM#3150
(Heat curing type Urethane resin)
18
• Test Method :
#3151(Compression ratio 30%)
•Test Piece Cf. Draft bead
Gasket internal pressure (kPa)

16
#3151(Compression ratio 50%)
14 #3151(Compression ratio 70%)
•Foaming Magnification 3.0
#3150(Compression ratio 30%) •Temperature 20℃
12
#3150(Compression ratio 50%) •Method
10 #3150(Compression ratio 70%)
By means of test jig of figure, air of 20 KPa pressures
gasket. After having closed air valve, internal pressure
8 variation to the every 60 second back is measured for
10 seconds.
6
4mm
4
Pressure
8mm Gage
2
Air Valve
0
0 10 20 30 40 50 60 Pressure Regulator
Times (sec)
Compression Air

70mm

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TECHNICAL DATA PENGUIN FOAM SYSTEM

Tightness Leak

Test Result Test Method

• Material : PENGUINFOAM#3151
#3151(2.0 times) #3151(3.0 times) (Heat curing type Urethane resin)
#3150(2.0 times) #3150(3.0 times) PENGUINFOAM#3150
(Heat curing type Urethane resin)
150 • Test Method :
•Test Piece Cf. Draft bead
Pressure in air leakage (kPa)

125 •Temperature 20℃

•Method
100 Test jig of figure is submerged in the water of 100mm
depth, pressure is raised with 5 KPa step, and visual
observation resembles, and air leak is observed,
75 measurement does the pressure coefficient
Compression Air
50 4mm
Pressure Regulator
8mm
25 Air Valve
Pressure
Gage

0
0 20 40 60 80 100 100mm
Compression Ratio (%)
70mm
Water

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TECHNICAL DATA PENGUIN FOAM SYSTEM

Durability (None-foamed)

Test result Test Method

#3150(Heat Resistance 80°C) #3150(Heat Resistance 100°C)

• Material : PENGUINFOAM#3151
#3150(Water Resistance 50°C) #3150(Humiduty Resistance 85°C85%rh)
(Heat curing type Urethane resin)
#3151(Heat Resistance 80°C) #3151(Heat Resistance 100°C)
PENGUINFOAM#3150
#3150(Water Resistance 50°C) #3151(Humidity Resistance 85°C85%rh)
(Heat curing type Urethane resin)
3.0
• Test Method :
2.8 •Test Piece JIS #2 Dumbbell (3mmt)
(Non-Foamed)
2.6
Tensile Strength (MPa)

2.4 •Curing condition:80℃×10min

2.2
•Method JIS K6251
2.0 , Cross-head speed of 200mm/min
Temperature 20℃
1.8
1.6
1.4

1.2
1.0
0 200 400 600 800 1000 1200
Times (hours)

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TECHNICAL DATA PENGUIN FOAM SYSTEM

Durability (Foamed)

Test Result Test Method

#3150(Heat Resistance 80°C)

#3150(Heat Resistance 100°C) • Material : PENGUINFOAM#3151
#3150(Water Resistance 50°C) (Heat curing type Urethane resin)
#3150(Humiduty Resistance 80°C85%rh)
"#3151(Heat Resistance 80°C) PENGUINFOAM#3150
"#3151(Heat Resistance 100°C) (Heat curing type Urethane resin)
"#3150(Water Resistance 50°C) • Test Method :
"#3151(Humiduty Resistance 80°C85%rh)
0.50
•Test Piece W:8∗H:4mm bead

0.45 4mm

0.40 50mm
8mm
Tensile Strength (MPa)

0.35
0.30
•Foaming Magnification 3.0

0.25 •Curing condition:80℃×10min

0.20
•Method JIS K6251
0.15 Cross-head speed of 200mm/min
Temperature 20℃
0.10

0.05
0.00
0 200 400 600 800 1000 1200
Times (hours)

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TECHNICAL DATA PENGUIN FOAM SYSTEM

Water Absorption

Test Result Test method

Material
Foaming
Ratio
Skin N
Before
Dipping (g)
After Water
Dipping (g) Absorption (%)
Average • Material : PENGUINFOAM#3151
1 1.1581 1.1911 2.8%
(Heat curing type Urethane resin)
2.0 With 2 1.1592 1.1958 3.2% 2. 8% PENGUINFOAM#3150
3 1.1568 1.1828 2.2% (Heat curing type Urethane resin)
1
2.0 Without 2
0.7710
0.7722
0.7974
0.7968
3.4%
3.2% 3. 2%
• Test :
3 0.7701 0.7927 2.9% The foaming bead which applied is cut in fixed dimension.
#3151
1 0.8020 0.8163 1.8% Water absorption of the bead is measured.
3.0 With 2 0.8012 0.8206 2.4% 2. 3% In addition, test of similar is executed in the bead
3 0.8003 0.8224 2.8% which cut surface skin layer simultaneously.
1 0.5379 0.5627 4.6%
3.0 Without 2 0.5306 0.5568 4.9% 4. 8% • Condition
3 0.5318 0.5571 4.8% 1. Cross section average bead dimension:
1 1.1682 1.1999 2.7%
2.0 With 2 1.1638 1.2062 3.6% 3. 0%
3 1.1638 1.1960 2.8%
1 0.7689 0.7974 3.7%
2.0 Without 2 0.7726 0.8108 4.9% 4. 5% 3.0 times with skin:High;5.0mm,Width;8.0mm,Length;50mm
3 0.7708 0.8088 4.9%
3.0 times without skin:High;4.0mm,Width;7.0mm,Length;50mm
#3150
1 0.8090 0.8503 5.1%
2.0 times with skin:High;5.0mm,Width;8.0mm,Length;50mm
3.0 With 2 4. 6% 2.0 times without skin:High;4.0mm,Width;7.0mm,Length;50mm
0.7983 0.8333 4.4%
3 0.7896 0.8237 4.3% *But it is assumed that it seals, and cut side of gasket handles.
1 0.5396 0.5767 6.9% 2. Examination
3.0 Without 2 6. 5%
0.5305 0.5666 6.8% 20 Degree C ,24hours, 1 atm.
3 0.5312 0.5620 5.8%

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TECHNICAL DATA PENGUIN FOAM SYSTEM

Microphotograph of Test Sample Without Skin (Foamed Bead of 2 times)

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