Question Paper [CODE - 31438]

12th_ Batch 25(Astar to A11 DA-Star) Anushasan 25ALA1 to 25ALA7 Eng _ [Mains Pattern]
12th JEE (M) - Phase 1
KOTA

Date: 21-Jul-2025 Duration: 3 Hours Max Marks: 300

 SYLLABUS
Maths
Relation & Function(C),ITF(C),Limit(C),Continuity(C),Differentiablity(C),MOD(C),Indefinite
Integration Till (Elementry Integral)

Physics
Electrostatics-1,Electrostatics-2 (C),Gravitation(C),Current electricity (C),Capacitance-Till
(combination of capacitor)

Chemistry
Isomerism (C),Alkyl Halide(C),Grignard Reagents(C),Hydrocarbon(C),Chemical Bonding
(C),Cordination (C),Liquid Solution Till (Roault’s Law)
 MATHS

1. −1, − 2 ≤ x < 0 4. Statement-1 : The function f (x) =

Let f (x) ={ and [[x]] − 2[x − 1] + [x + 2] is discontinuous at all
2
x − 1, 0 < x ≤ 2

then the number of points

g(x) = |f (x)| + f (|x|)
integers.
Statement-2 : [x] is discontinuous at all integral
at which g(x) is non differentiable is.......
values of x.
(A) at most one point Note : [[y] denotes the largest integer less than
(B) 2 or equal to y.]

(C) exactly one point (A) Statement- 1 is true, statement- 2 is true

and statement-2 is correct explanation for
(D) infinite statement-1.
2. If f(x) = [loge x] + √{log x} , x > 1, where [.]
e
(B) (B) Statement-1 is true, statement-2 is true
and {.} denote the greatest integer function and statement-2 is NOT the correct explanation
and the fractional part function respectively, for statement-1.
then -
(A) f(x) is continuous but non - differentiable at (C) Statement- 1 is true, statement- 2 is false.
x=e
(B) f(x) is differentiable at x = e (D) Statement-1 is false, statement-2 is true.
(C) f(x) is discontinuous at x = e 5. If the function f defined as f (x)=
1
−
k−1
,
x e
2x
−1

(D) None of these x ≠ 0, is continuous at x = 0 then the ordered

3. Let f(x) = pair (k, f (0)) is equal to:
n
πx

(A)
2
1
⎧
⎪
ax(x−1)(cot ) +(px +2)
( , 2)
⎪ 4
3
lim n
, x ∈ (0, 1) ∪ (1, 2)
(B)
πx
⎨ n→∞
(cot ) +1 (3, 2)
4

⎪
⎩
⎪
0 x = 1 (C) (2, 1)

If f(x) is differentiable for all x∈(0, 2) then (a2 (D) (3, 1)

+ p2) equals
6. If f(x) = (x + 1)x + xx+1, then f ′(1) is equal to
(A) 20
(A) log (4e2)
(B) 12
(B) log (4e3)
(C) 6
(C) log (4 e–3)
(D) 18
(D) log (3e4)
7. A curve is represented parametrically by the
t

equation x = f (t) = a
ℓnb
and
t

y = g (t) = b
−ℓna
a, b > 0 and a≠1, b ≠ 1,
2
d y
where t ∈ R , the value of 2
at the point
dx

where f(t) = g(t) is :

(A) 0

(B) 1

(C) 1
(D) 2
8. If y1/n = {x + √1 + x2 }, then (1 + x2)y2 + xy1 14. ∫
dx
is equal to
sinxsin(x+α)
is equal to
∣ ∣
(A) n2y (A) cosec α ln
sinx
+ C
∣ sin(x+α) ∣

(B) ny2 (B) cosec α ln ∣ sin(x+α)

∣
+ C
∣ sinx ∣
(C) n2y2 sec(x+α)
∣ ∣
(C) cosec α ln ∣ ∣
+ C
(D) ny sec x

∣ ∣
9. √1+x −1
2
(D) cosec α ln secx
+ C
The derivative of tan
−1
(
x
) with respect ∣ sec (x+α) ∣

15.
is equal to
2
2x√1−x
to tan
−1
(
2
) at x = 0, is ∫ √1 + 2 tan x (tan x + sec x)dx
1−2x

(A) 1
(A) ln |tanx (secx − tanx)| + C
8

(B)
1
(B) ln |tanx (secx + tanx)| + C
4

(C)
1 (C) ln |secx (secx − tanx)| + C
2

(D) 1 (D) ln |secx (secx + tanx)| + C

16.
y
10. 2 3
If cos
−1
x − cos
−1
= α, then
at is
d –1 3a x–x
tan [ ] x = 0 2
2 2
dx
is equal to (x > 0, y >
a(a –3x ) 2 2
4x − 4 xy cosα + y

(A) 1
0)
a

(B)
3 (A) 2 sin 2α
a

(C) 3a (B) 4

(D) 3 (C) 4 sin2 α

11. 2x − [x], x ≥ 1
(D) − 4 sin2 α
The function f (x)= {
πx 17. The set of values of x for which the identity cos–
sin( ), x < 1
2
1 x + cos–1( 2
x
+
1
√3 − 3x2 )=
π
holds good,
(A) is continuous at
2 3
x = 2
is
(B) is differentiable at x = 1
(A) [0, 1]

(C) is continuous but not differentiable at x = 1

(B) [0,
1
]
2
(D) None of these
(C) [
1

2
, 1]
12. log ( 1+x+x
2
) + log ( 1−x+x
2
)
The value of lim
sec x−cos x
is (D) {–1, 0, 1}
x→0

equal to 18. Let a curve y = f (x) be detined parametrically

(A) −1 as y = t3 + t2 + 1, x = t2 + 2, t > 0. If g(x) is
inverse finction of f (x) then g''(3) is
(B) 1

(A)
3

(C) 0 4

(B)
3
−
(D) 2 4

(C)
6
−
13.
2
x −4x√x+6x−4√x+1
The value of the integral
125
∫ dx
(D)
x−2√x+1 6

is equal to 125

3
19. Let f : (−∞, ∞)→(
−π
,
π
) such that f(x) =
2 2

(A) 2tan–1(2013x) –
2
x

2
+ x + c
π

2
, then
2 3

(B) (A) f(– 3) + f(3) = 0

x 4
− x2 + x + c
2 3

(B) f(–2) – f(2) = 0

3

(C)
x
x3 + + c
2
3
(C) f(x) is a decreasing function
(D)
2
x3 + c
3

(D) f2(5) – f2(–5) is non zero

20. Let f : R − {0} → R be a function satisfying
f (x)
for all . If
x
f ( ) = x, y, f (y) ≠ 0
y f (y)

′
f (1) = 2024 , then

(A)
′
xf (x)−2024f (x)= 0

(B)
′
xf (x)+2024f (x)= 0

(C)
′
xf (x)+f (x)= 2024

(D)
′
xf (x)−2023f (x)= 0
 MATHS

21. If f(x) is twice differentiable function such that 23.

n

If is non-zero finite, then n is equal

x sin x
lim n n

f(a) = 0, f(b) = 2, f(c) = – 1, f(d) = 2, f(e) = 0,

x −sin x
x→0

where a < b < c < d < e, then the minimum to

number of zeroes of g(x) = {f'(x)}2 + f"(x). f(x) 24. Let f(x) = 2tan–1x and g(x) be a differentiable
in the interval [a,e] is x+2y g(x)+2 g(y)
function satisfying g( )= ∀x,
22. sgn(x − 2)⋅[log x], 1 ≤ x ≤ 3
3 3

and g'(0) = 1, g(0) = 2.

e
If f(x) = {
2
y ∈ R
{x }, 3 < x ≤ 3. 5
Find the number of integers satisfying f2(g(x)) –
(where [.] denotes the greatest integer 5f(g(x)) + 4 > 0 where x ∈(−10, 10).
function and {.} represents the fractional part
function), then the number of points of 25. Qx−1
If where
1 P −1
∫ dx = tan ( ) + C
discontinuity is
2
x −x+1 √R √R

C is arbitrary constant of integration. then find

the value of P+Q+R.
 PHYSICS

1. How many electrons flow per sec through the 4. The effective capacitance between A and B is
filament of a 220 V and 110 W electric bulb ?
(A) 6.25 × 1018
(B) 1.25 × 1018
(C) 3.125 × 1018
(D) 3.5 × 1017
2. If R = 1 Ω , the current in the branch x is :
(A) 1μF

(B) 2μF

(C) 1. 5μF

(D) 2. 5μF

5.

(A) infinite
(B) 0.8 A
(C) 0.5 A
(D) 1 A
3. The acceleration due to gravity on the surface of
Three charges are placed as shown in figure.
earth is g & radius R. A ball is projected
The magnitude of q1 is 2.00 μC, but its sign and
horizontally from point P1 on the surface of
earth (as shown in the figure). If the maximum the value of the charge q2 are not known.
height attained by the ball above the earth Charge q3, is +4.00 μC and the net force on q3
surface is 3R, then speed of projection v0 is is entirely in the negative x-direction. The
(neglect cosmic dust resistance & earth’s magnitude of q2 is
(A) 64 μC
27
motion).
(B)
27
μC
32

(C)
13
μC
32

(D)
13
μC
64

6. The potential gradient along the length of a

uniform wire is 10 volt / metre . B and C are
the two points at 30 cm and 60 cm point on a
(A)
8
√
5
gR meter scale fitted along the wire. The potential
difference between B and C will be
(B) √2 gR
(A) 3 volt
(C) √gR
(B) 0. 4 volt

(D)
6
√
5
gR
(C) 7 volt

(D) 4 volt
7. A capacitor of capacitance C carrying charge Q 11. The resistance and the magnitude of the current
is connected to a source of emf E. Finally, the depend on the path that the current takes. The
charge on capacitor would be drawing shown three situations in which the
current takes different paths through a piece of
(A) Q
material. Each of the rectangular pieces is made
(B) Q + CE from a material whose resistivity is ρ and the
unit of length is L0 . Each piece of material is
(C) CE
connected to a battery of EMF V. Find the ratio
(D) None of these of current in a, b & c.

8. The thickness of air layer between the two

coatings of a spherical capacitor is 2 cm. The
capacitor has the same capacitance as the
sphere of 1.2 m diameter. Find the radii of its
surfaces.
(A) 14 cm , 16 cm
(B) 12 cm , 14 cm
(A) 2 : 4 : 1
(C) 10 cm , 12 cm
(B) 16 : 1 : 4
(D) 11 cm , 13 cm
(C) 1 : 2 : 4
9. An electric pump is used to fill an overhead tank
of capacity 9m3 kept at a height of 10 m above (D) 1 : 16 : 4
the ground. Water comes in tank with negligible 12. The electric field at 20 cm from the centre of a
speed. If the pump takes 5 minutes to fill the uniformly charged non-conducting sphere of
tank by consuming 10 kW power, the efficiency radius 10 cm is E. Then at a distance 5 cm
of the pump should be : (Take g = 10 ms−2 ) from the centre it will be:
(A) 60 % (A) 16 E

(B) 40 % (B) 4 E

(C) 20 % (C) 2 E

(D) 30 % (D) Zero

10. A hemisphere of radius R as shown in figure is 13. The potential difference between points a and b
uniformly charged with a surface charge density of circuit shown in the figure is
σ. The electric field at the centre C is

(A) σ
E1 +E2
(A)
ε0
( ) C2
(B) σ

2ε0
C1 +C2

E1 –E2

(C) σ
(B) (
C1 +C2
) C2
4ε0

√2σ E1 +E2
(D) ε0
(C) (
C1 +C2
) C1

E1 –E2
(D) (
C1 +C2
) C1
14. A satellite is revolving round the earth with 16. A charge passing through a resistor is varying
orbital speed vo. If it stops suddenly and with time as shown in the figure. The amount of
released, the speed with which it will strike the heat generated in time ' t ' is best represented
surface of earth would be (ve= escape velocity (as a function of time) by :
of a particle on earth's surface):
2
ve
(A) v0

(B) v0

(C)
2 2
√ve − v
0

(D) 2
√ve − 2v
2
0

15. Which of the following electric field pattern in

correct inside the conductor having three
materials of resistivity?

(A)

(A)

(B)
(B)

(C)
(C)

(D)

(D)

17. The electrostatic potential in space is given by

→ → →
V = a ⋅ r where a is a constant vector and
→
r is the radius vector of a point in the field.
The electric field vector at this point is
→
(A) a
→
(B) − a
→

(C) a

(D) −
a

18. A Daniel cell is balanced on 125 cm length of a

potentiometer wire. Now the cell is short-
circuited by a resistance 2 ohm and the balance
is obtained at 100 cm. The internal resistance
of the Daniel cell is
(A) 0. 5 ohm

(B) 1. 5 ohm

(C) 1. 25 ohm

(D) 4/5 ohm

19. Two capacitors each of 1 μF capacitance are 20. A non-conducting ring of radius r has charge q
connected in parallel and then are charged by distributed uniformly over it. If it rotates with
200V D.C. supply. The total energy stored in angular velocity ω about its axis, then the
joules is- equivalent current is -
(A) 0.01
qω
(A) 2π

(B) 0.02 (B)

2π

qω

(C) 0.04 (C)

qω

2πr

(D) 0.06 (D) qωr

 PHYSICS

21. The potential difference across the 6 ohm 23. Three charges 0.1 coulomb each are placed on
resistance in the given circuit is 48 V. The the corners of an equilateral triangle of side 1
potential difference across a to b is 51 × α Volt. m. If the energy is supplied to this system at
then find the value of α. the rate of 1 kW, the time required to move one
of the charges onto the midpoint of the line
joining the other two is 1.8 × 10k sec. Find the
value of k ?
24. Charge is uniformly distributed in a long
cylindrical volume of radius R, with volume
charge density ρ. The electric field at distance
ρR
R from the axis of cylinder is Nϵ0
. Find ' N '

25. In the given figure, the value of V0 will be …. V

22. Three identical plates are arranged as shown in

figure. The plates make two capacitor in series
and capacitance between each plate is same
ε0 A
and equal to C =
d
. Now at t = 0 middle
plate start moving with constant velocity 2
mm/s. If equivalent capacitance at t = 2 sec is
given as C/N. Then find the value of N.
 CHEMISTRY

1. Which of the following compound are non-polar 4. Identify the strucure of X

in nature.

(A)

(vi) C6H6 (vii) B3N3H6

(B)

Select the correct option:

(A) only (i), (ii) and (iv)
(C)
(B) only (iv), (v), (vi) and (vii)
(C) only (iv), (vi) and (vii)
(D) only (vi) and (vii) (D)
2. The vapour pressure of pure benzene and
toluene are 160 and 60 torr respectively. The 5. The complex which exhibits cis-trans isomerism
mole fraction of toluene in vapour phase in as well as can be resolved into d and l forms:
contact with equimolar solution of benzene and
toluene is - (A) [Be(acac)2]

(A) 0.50 (B) [Ir(H2O)3(NH3) 3]3+

(B) 0.6 (C) [Cr(en)3]3+

(C) 0.27 (D) [Rh(H2O)2(en)2] 3+

(D) 0.73 6. The vapour pressure of a solution having 2g of

solute X ( molar atomic mass = 32 g mol ) in
−1

3. Electrolysis

CH3–COOK −−−−−−→ CH3 – CH3 100 g of CS2 (vapour pressure = 854 torr) is
848.95 torr. The molecular formula of the solute
In the above reaction pH of solution with is :
respect to time.
(A) X
(A) pH will constant
(B) X2
(B) pH will decrease
(C) X4
(C) pH will increase
(D) X8
(D) None
7. 9. Benzene and naphthalene form ideal solution
over the entire range of composition. The
vapour pressure of pure benzene and
naphthalene at 300 K are 50.71 mm of Hg and
32.06 mm of Hg respectively. What will be the
mole fraction of benzene in vapour phase if 80
g of benzene is mixed with 100 g of
naphthalene?
(A) 0.0675
(B) 0.675
Identify the product of the following elimination (C) 0.35
reaction X and Y respectively with
streochemistry : (D) 0.5
10.
(A)

A and B are respectively :

(B)
(A) Both,

(B) ,
(C)
(C) ,

(D) (D) ,

11. Consider a binary solution of two volatile liquid

+ components 1 and 2. x1 and y1 are the mole
8. The structure of ICl2 would be :
fractions of component 1 in the liquid and
vapour phase, respectively. The slope and
intercept of the linear plot of x1 vs y1 are
(A)
1 1

given respectively as :
o o o
P P −P
(A)
2 2 1
o , o
P P
1 2

o o o
P P −P
(B) P
1
o
,
1

P
o
2

2 2

o o o
P P −P
(C) 2
,
1 2

(B)
o o
P P
1 2

o o o
P P −P
(D)
1 2 1
o , o
P P
2 2

(C)

(D) None of these

12. Match the LIST-I with LIST-II 15. What is the product of the reaction sequence
List-II
below ?
List-I
(Hybridisation of
(Molecules/ion)
central atom)
(A) PF5 (I) dsp2
(B) SF6 (II) sp3d
(C) Ni(CO)4 (III) sp3d2
(D) [PtCl4]2– (IV) sp3
Choose the correct answer from the options
given below:
(A) A-III, B-I, C-IV, D-II (A)

(B) A-II, B-III, C-IV, D-I

(C) A-IV, B-I, C-II, D-III

(B)

(D) A-I, B-II, C-III, D-IV

13. Which of the following pair are diastereomers

(I) and
(C)

(II) and

(D)
(III) and

16. Which of the following molecules has almost

(IV) and negligible tendency to form hydrogen bonds?
(A) NH3
Select the correct answer. (B) H2O
(A) I, II
(C) HF
(B) I, II, III
(D) HI
(C) I, II, IV

(D) Only II

14. A freshly prepared aqueous solution of

Pd(NH3)2Cl2 does not conduct electricity.
It suggests that

(A) On adding excess aqueous AgNO3 to 0.1 L

of 0.1 M solution of the compound, 0.02
mole of AgCl would be obtained
(B) The chlorine atoms must be in coordination
sphere
(C) The van’t Hoff factor of the compound would
be unity
(D) Both B & C
17. Which of the following ethers is not cleaved by 19. There are some possible reactions given below.
concentrated HI even at 525K ?

R1 :

(A)

alc.KOH

R2 : Sec. butyl chloride −−−−−→ P2

(B) H2 / Pd

R3 : But-2-ene −−−→ P3

(C)

In which reaction, different geometrical isomers

may be produced?
(D) (A) R4 only
(B) R1 and R2 only
18. Compound C4 H10 0
(C) R2 and R4 only
(D) R1 , R2 and R3 only
20. Observe the following reaction sequence

Conc.H2 SO4 .(boil)

(1)

(Structural) compound is :
(G) (H) (I)
LiAlH4 H3 P O4 .Δ

(A) (2) (3)

Calculate molecular mass (W) of product (I)

(B) and report your answer is N, where N = W ÷ 3.
(A) 78
(C)
(B) 84
(D)
(C) 79
(D) 85
 CHEMISTRY

21. A solution contain 0.2 mol of H2O and unknown 24.

number of moles of NaCl. The vapour pressure
of solution at 30°C is 24 torr. The vapour
pressure of pure water at this temperature is 32
torr. Calculate number of moles of solute in the
solution.
[Multiply your answer by 30] How many carbons in parent chain in major
product
22. (a) How many unpaired electron(s) is/are
present in t2g orbital of [Fe(NH3)6]2+ complex 25. (a) Total number of stereoisomer in given
ion. compound are?

(b) Write the co-ordination number of central

atom of cis-platin.
(c) How many d-orbital(s) is/are involve in (b) Total number of products on mono-
hybridisation of Fe in K4[Fe(CN)5O2] chlorination of n-pentane in presence of sunlight
are?
(d) How many electron(s) is/are present in eg
orbitals of [Co(C2O4)3]3- . (c) Number of structural isomers of C3H9N are ?
Write answer of part (a), (b), (c) & (d) in the same order (d) How many cyclic alkenes (excluding
and present the four digit number as answer in OMR stereoisomer) will produce methyl cyclohexane
sheet. For example : If answers are 2,1,4,5 then fill as on catalytic hydrogenation.
2145 in OMR sheet.
( a + b + c ) –d

23. How many of the following are tetrahedral? Give value of x = 2

(a) Ni(dmg)2 (b) [Ni(CN)4]2– (c)

4–
[Ni(CN)4]
(d) [Ni(CO)4] (e) [Ni(Cl)4]2– (f) K2Cr2O7
(g) K2CrO4 (h) KMnO4 (i) K2MnO4
(j) CrO2Cl2
ROUGH-WORK
ROUGH-WORK
ROUGH-WORK
ROUGH-WORK
ROUGH-WORK
ROUGH-WORK