Rayat Shikshan Sanstha's 16 Pages
Karmaveer Bhaurao Patil Mahavidyalaya,
(Arts, Science,Commerce &H.S.C. Vocational) Pandharpur
RayatMOdel Answer Anuatxamination 2023 - 2024
subject -CHEMSTRY Class - XL Exam. No.
Paper Section
Date 04-04-2o 24
No. of Suppliments - 1 + Jr. Supervisors
Stpawar 143@gMajl coM) Signature Pawa sT.
Section QNo. /A2/B3/cs7D 5 6 7 8 10 11 12 Total
|Marks 8||6 24||2 70
Signature of Examiner q07563233)
SectionQ. No. 2 Total
A Marks00
Start WritingFrom Here
Section- A
MeQ
DPhenol AA Renzeme: In tthis rea hon
the seagent A' S
2)Oxidahion of sulehur dioxide to suphe
+oxide Witts OXyGeM C02)
|of nitie oXide in galeos phase act as.
J b ) homogeNeDus catalyst.
Which of tie fallouwing speies wilL
have tae langelt siee
a)Fe
4) ASoluh'on ic pxepred loy adding 2gm
2 gnn of
Suostace A to 8 0f water, He mase
teent of slute is
2
ITotal
Section Q. No.
Marks
js
s) Whiceh of the follo0}ng electolytes
netality
Used to maintain eletoica
in tne Daniel cel 2
6) Tmpude Common Salt Can be puii
b) C4stalli2ation.
t
1) Tue egulibium, H 0 a a
b) Physicat
3) The missina paatide foom the nucleaN
eaetion is
A) + He
The coYEt stutemeRnt degaadi ng.
electaophile is
d) Eletoophile Can be eitheN neut
Aom a' bond by aleepting a pa of
ele ctaons foom a nueleophile.
1o) hich of t e follooing is used asa
weak antiseptic for e&S.?
d) Dilyte aqueoui Soluion of boe
acd
Total
SectionQ. No.
Marks
VSA
The swbetaees
ohic arae used to enovesten
2)|AVo9qdao's law
Equa Volymes of all qases ad tthe
Contain
same temperatue k Pressuse
eual numbes of molecwes
3) Bond odey of Molecule
= Nb- Na
t
Allcai met G80-I elements.
)Isuface teneion Tue foce actingpes
unit lemgtti pepeydieulao to the line
tdeawn on the Curface of tiqud is
Called Suzfale tencion.
IUPAC na We
Ettayl pDpaMo ade
) Mole ule having loánana lbond cname)
Diboane
Wavelensth (A) The distmee between tuoo
Consecwtive coe sts 0 touhs is Cale
|wave length
SectionQ. No.3 6 I0W 124 13|14 Total
7
B Marks 222222|2-2
Neat lebelled oiagam of paniel cel).
clectron Voltmctcr electron
flow flow
Salt bridge
Ion
Zinc flow
electrode Copper
electrode
(anode)
(cathode)
Zinc
salt Copper
Salt
solution solution
Numbex of significant Aguresi
2
a) oooo 20 kg
b) -So X61 mm 3
Ssteps involved in hybidzahon
i) Fpmation of excted shte
"The paied electoons in tue ga0und stale
Aae un coupled one electon s paoM3
ted o Vacat oobital
ES. EC:
D) MXng & eLaling of oitae having
6abita boith same shape
(5)
Section Q. No. Total
Marks
Stautue orf BontËchlo1de
) Boson aoy issp hyledized having
One Vacaut unhybhdeedp osital.
i ) Bobon in Bca has n Complee octet .
hì) Bcl is non-polq toigon plannar
molecwle
8) 20
chasa cteisties of eauilibium Contn.
he value of e0 constavt is independpnt
poducts i) Ke R Ke châvye toiHa teme.
i) Jt hae ctaaacteihe value for a peo
LCutaevenile reaoy baay ted can)
at a gven temmpebatue
v) Hi_ley Value of kekp mean mose
Concentaton of Poodult is fosMed.
oxidation state of (oooup l4
(osoup oxidation state -+y
otues oxidaon states +24
Outes Eetonic confauaon of
ns n
SectionQ. No. Total
Marks
a) MetameisMt is a tyre crf
isomeojsm in ohich Compounds havetthe
Same molecutay fosimula Lsut diffeoet alXyl
g»pups on either side ef Aunctena! gaou
ase called metanmeos ¢ tuis phenomenon is
metaesm
b) Case0 Cation AA caton atom having
sextet of eletoon ad a positve che
Castocation.
a) Acton of O0ne
o20ne on -benzene
BeMeenetozoni de
b) cl in wwignt on bemeene
BHC
Antmioloiau
Any dous thatnhikits ox Kills micobi
cells taat include bactena fun4i &viugeg.
Btylated hydowxy toluene Molecular fobmla
sction . No. Total
Marks
12:
Benzoyct,e-B3
Pesoxide
a) TUPAC ngme' rbmo-2-metuylpoopqne
peooride:
b)Yule'- AntiMakonikov ule
effe cokha Sch-MayO effe t
a) Electoon gain enthapy'
|The enthaley chage that takes pl4ce oheM
Lanelecton is added an solaed qaseous
latom in itk sound state is Called ele(tooy
gan enttyapy
b) Shieldins effe ctiThe inney electoon
shield the outey ele cfoon foom theyUes
|hence outer eeoton are held lees iglht ls
by tthe nudeus this is caled shielding effeco.
chn m
atosaphie technies
A) Adsorpson chsomatogaphy
2) Thin layex coopmatogply cTLe)
B) PAition chsomatgphy
paper choomatbaahy
iniple underlyiny chaoMatogaphy'
Dependng on the oelative affinity of the
ComponeAti to lwqrds tue stutonay phale
Mobile phase they remain on tue sufale of
stho nay phase oy move alony wjty mobile phase
K goadually get SRpDAted.
(8
SectionQ. No.|S 6 | 7 9 2 0 | 2 ) 2223|24226 To
C Marks 3 3
3 3 3 3 33 3 AAA24
BlocK, Peiod d Gooup of element
a)_VC223
Dt isdr bl0ck lRmet
Menmber of 4th pesod Go0up noS
sbcz= s)
Tt is P-blokelRment
membes of sth pesd & ooup No. 1
Q16 Le-chateliex pin aple- when a Sysiem
lat eslibumis subie ted to a clhange in
any of the fi otoYs detesminivg the eauiibvM
Condihons of a System, Sytem wil
es pond in such a wqy as to minimiee
e etfect of chanye:
sta gaered & eclipsed Conformahon of
ettane
a) Sawhose poDjechon
H
Eeipsed stagsee.
) Newman poojection
H
H
Londl CoValent
conmits
of phosphou
tt 2Red
les. tetahed
P4 descete of
sist phosphoad
l-TÀ (yello
) w)White
phesphou Allo+pes
of
dimensionale
colide
two goapheMe.
a is Tt called s
e of
layey Isolated Goasheme
XX2t-2)8 +2)x3+
Cag(PD4)
dide 3odium
NaHea 2
y on met um
Sodi Achion
of L)
Hzt 2
dgey Cotalyst
Dioxygen
on of
Achon a)
one
ch electoirg Unpased to 0f
PAoamaqnetic
to
due moleeeis 02
2
(*
molecuei raramaAneis
O, of
Marks|
otal No. tion
Q
9
(10)
SectionQ. No.
Total
Marks
ASked
Given'
th382 dayS
[Link]
N oo-99 0
O643 O653
ty 3- 82
2:303
o1914
40g16
t2303 40
t b1814
2 203 y33dayt
Q20atoss affechng adsoaption of qa on lolid
)Natyee ot adeosbate csa)
2)Natue of ad cosbent
)Su fale goea of adsoemt
Hunds e of
maximummuttiplicity
Pain of ele tton in the otoitl
|Lelonging to the Sewe Subshell doe nst occure
Unless each ooitz has qot one eleTU
each.
11)
Total
SectlonQ, No,
Marks
2| Adsopion isofherrm: The elationchip
botweey ue amound od a [Link]
adcoxbed p unit maLS f adoztent
qnd
t Conktnt eme is calteJ
adeoption ísotem:
Electonic Cantiubason of
a) chlone c z = 1 )
2
L)Zinec2=3o) J
Q22- iVen Asked
S 20|37.
Elemen mass No: ofmoes of
ertt eement
Simplest
34-62
Cu39-6239'62s
2013A.4290o6290
20-1320-3J32
2-s
|6 06288 4
Empmica fomwa euso
Empiica foomwa mas- 63t32+64t
Empi foma mass mok sr fosmwy y4s
Total
SectionjQ. No.
Marks
Q23 Homolytic Ceavaye!- surnmetncal baen ting
acovalend kond, each atoww gett singe
of
Heteolyic ceaVaqe'Unsymnetsicf
boearins of a. Covaleti bond.
tsoth shared ele tao qo to 0ne Of the
two bo nded aton
ACB
LSoeletonic Speies!
Atome & ione havins tthe sanie nunbeg
Of eleCtOns ase Called iSO eleCtonic
Ax Ca
Q24 Qiven n
T=2c0t23243k
P\0]-3S Kpa As Ked Ve?
=latm.
Va R
V= 24.07 dm
ST Unit of vis cocity loeffaent
NS
Ne4Nton selond per sg ua
1
(13)
SectionQ. No. rotal
Marks
Q2s Type of Hybidizaton k Geometay of NH3
Tàig1al yami dal
22
Numbey of unpaed electoon in
Nkel( 2 2 )
2 unpaied elechos U111 11
tunpaired 4444441 41
26 Boyle's aw'
At ConAtan tempesntuoe f e pregSUe
f ixed amo yYt of a Sey Vsiee
nversely witth it's Volyme.
At conktamt tervAe: pboduet of poelye
Nolyne of ttae tixe mad of a gars
ST unit of ate of dicfueion'
Total
SectionQ. No.27 2%A303
Marks 4444
Q24a) Number of atoms of N in 42 &of N.
No of moles mass bf Nitoogn ctoms
adomic maes of N.
42. 3 moles
23
1 NO 0f GtoM ofN3X6022Xo
b) Alkynesi Atiphatie unsatoated
hytOCALOne Containiy coslaom-CasLoy
ple bond ae calhed allynel
chemica el for combuihoy of butane
Q28 | a) i) Ethane foo ettyt bomi de
CH,-t g 2 CH1 2n,Hely chCH, t HB>
)ethane foom etylmagnesium Lbmi de
Br
Atomnic mas ynit Cam:).
Mass exactly egual toD One twelth of
ne masci of one Caoton-2 atorn.
Molecular ass of ettiyl alcoho
46 am:u,
(15)
Total
SectionQ. No.
Marks
Q29a) Lewis dot sty ctuoe of
i)
(:FOGQC:
H)
Ske fox the eachoy ABc+D
030a) Dishngish bet? siqma (o) pi() bornd
S1qma (s) bond Pi ( ) bod
Fomed by a a | ) Fomed by the laderal
oveslappng of half-cside-ise) overeping
elled atp mic otitaof haf flled ato mie
OYbitas
i)Exists independenty )Eists aloywits obond
yiAils free otaton
taonge than pi bond v) Weaker tuay s bond
The e cloud is SymM-V) here ave two e clouds
etica! about tye lyins abov t lbelow the
ntesnclear aS Iplane of atomi nyce.
b Unit of eg
ea" Contant fo tthe de
Kc= bnz2-(lt|)
nit of Ke= (mole dm
Ke h no Unirt.
(16)
SectionQ, No. Total
Marks
ssium
Q31a) Tmpotance o.f Sodium R pofa
in biolegica system
)Sodiym jon is poeeerf as the laogest
Supply in all extcel|ulaiarde. hole
uids psovide medium foY toqnsPos+irg
nutjets to the cells.
m) The Conc? of NaT in e | a cellula
Hhe membge
R) NAt Pasheipate in the tnsMissioy
|of neve siqnas.
iv) t ion
in the Syitheeis of poofejny e also in
oxidaton
b) Wate two udes of H,o,
) As moutth wah, germi ide, mild
antisepticPoeserVacive fo r mìlk wine
)BleAclny ayent for Soft mateials
) A an antichlo td oemoVe excess
choe foom fabhcs,
V) Tn envionmenta chemi for
Pollaon longol,etoat'on of qobic
Condion to £ewaye wate.
ch Wnte molecular foMula Stauctyne
of
rottao phosphoic aid
O- H
