Quantum
numbers
By.1.SoniaSharma
Class:11thB
QuantumNumbers
PRINCIPAL:nenergylevel,
thedistancetheorbitalisfromthenucleus
(1,2,3,4)
ANGULARMOMENTUM:l
(s=0,p=1,d=2,f=3)
shape
MAGNETIC:mlspatialorientation
(0fors;1,0,+1forp;2,1,0,+1,+2ford,etc.)
SPIN:msspin(+1/2or1/2)
Review
Atomicnumber=#electrons
Electronsoccupyorbitalsdefinedbyn,l,m
Eachorbitalcanholdtwoelectrons
Orbitalsdiffuseelectroncloud
lowerenergyelectronclosertonucleus
Outerelectrons:valencemostreactive
Principalquantumnumber
Theprincipalquantumnumberhasthesymboln.
n=1,2,3,4,......shells
(n=K,L,M,N,......)
Theelectronsenergydependsprincipallyonn.
Angularmomentumquantum
number
TheAngularmomentumquantumnumberhasthe
symbol .
=0,1,2,3,4,5,.......(n1)
= s,p,d,f,g,h,.......(n1)
tellsustheshapeoftheorbitals.
Theseorbitalsarethevolumearoundtheatomthatthe
electronsoccupy9095%ofthetime.
Magneticquantumnumber
Thesymbolforthemagneticquantumnumberism,
representing the spatial orientation.
m = - , (- + 1), (- +2), .....0, ......., ( -2), ( -1),
If=0(oransorbital),thenm = 0.
If =1(oraporbital),thenm = 1,0,+1.
z
x
If =2(oradorbital),thenm = 2,1,0,+1,+2.
If =3(oranforbital),thenm = 3,2,1,0,+1,+2,+3.
Theoretically,thisseriescontinuesontog,h,i,etc
Spinquantumnumber
Thelastquantumnumberisthespin
quantumnumberwhichhasthesymbolms.
Thespinquantumnumberonlyhastwo
possiblevalues.
ms=+1/2or1/2
Spinofelectron
Spinquantumnumbereffects:
Everyorbitalcanholduptotwoelectrons.
ConsequenceofthePauliExclusionPrinciple.
Thetwoelectronsaredesignatedashaving
onespinupandonespindown
Spindescribesthedirectionoftheelectronsmagneticfields.
QuantumNumbers
PRINCIPAL:nenergylevel,distancefrom
orbital(1,2,3,4)
ANGULARMOMENTUM:l
(s=0,p=1,d=2,f=3)
shape
MAGNETIC:mlspatialorientation
(0fors;1,0,+1forp;2,1,0,+1,+2ford,etc.)
SPIN:msspin(+1/2or1/2)