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Lithographic

Processes

Pattern generation and transfer

Circuit design Pattern data Master mask set


Working mask set Pattern on wafers

Increasing device density reducing minimum feature size


Through-put consideration

Wafer with IC Chips

Patterning by lithography and wet etching


Mask

Etching of Al film

Cr patterned film
transparent glass

photoresist

Si

Al film
SiO2 film

Pattern transfer
to photoresist

Si
UV exposure
Develop solution

Si

Si

Si

Photoresists
Chemical/texture change upon exposure to light (UV), X-ray, e beam

Sensitivity
Adhesive
Etch resistance
Resolution

Negative resists: long-chain organic polymers, cross-linked


upon UV exposure
Kodak Microneg 747: polyisoprene rubber + photoactive agent
Thickness 0.3 1 m, feature size 2 m due to solvent-induced
swelling effect, hard to remove after using

Positive resist: a mixture of alkali-soluble resin, photoactive


dissolution inhibitor, and solvent
PMMA (polymethylmethacrylate)
Thickness 1 - 3 m, no solvent-induced swelling effect, feature
size 2 m, easy to remove after using

UV Sources:
Hg-Xe lamp, ~ 250-290 nm
Excimer lasers, deep UV, 200 nm (e.g. ArF, = 193 nm )

Pathways for pattern transfer

Design
pattern

Optical or ebeam writing

Reticle Projection printing, Working


masks step-and-repeat
masks
5-20
1

E-beam pattern
generation
No diffraction
limitation, minimum
feature size ~ 0.15 m
Reducing the backscattering effects
(proximity effects) by
reducing beam energy
Raster scan mode
Vector scan mode

Pattern transfer to wafer: Printing


Contact printer: highest resolution (minimum feature size ~ 0.15 m),
but damages to masks and/or wafer limit mask lifetime

UV

Mask
photoresist

Si

SiO2 film

Si

Proximity gap printer: 2.5-25 m gap, compromising resolution


(r d), minimum feature size 1 m

Projection: flexible, no damage, limited resolution in single projection


Step-and-repeat projection: high resolution in reduced area,
acceptable throughput due to short exposure time of each frame

A complete lithographic process


Wafer with
mask film (e.g.
SiO2, Al)

Photoresist
coating (spin
coating)

Removal of
exposed
photoresist

Postbake

Etching of
mask film

Removal of
unexposed
resist

Prebake
(softbake)

Mask
alignment

Development

Exposure

Next process
(e.g. implantation,
deposition)

Contact to a diode
(a) Lithography
(b) Metallization
(c),(d) lithography

Lift-off Process
Positive resist
patterning
Metal deposit
Removal of
resist and metal
film above

Capable of forming thick and narrow metal lines


little damage to oxide surfaces

Move to EUV
Source
Mercury lamp

Excimer
Laser

Fluorine laser

Name

Wavelength (nm)

Application feature size (nm)

G-line

436

500

H-line

405

I-line

365

XeF

351

XeCl

308

KrF

248 (DUV)

250 to 130

ArF

193

150 to 70

F2

157

< 100

350 to 250

Multilayer Resists

R1, R2 sensitive to 1, 2

Contrast enhancement

Phase-Shifting Masks

Resolution improvement ~ 2-4 times, pattern-dependent

Electron
Projectio
n
Printing
System
Direct e-beam
writing: ~ 0.15m,
sequential, only for the
smallest features

X-ray printing system

Difficulties: photoresist and optical systems for X-ray

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