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Chemical

bonding
Achemical bondisalastingattractionbetweenatomsthatenablestheformationofchemicalcompounds.Thebondmayresultfromtheelectrostaticforce
ofattractionbetweenatomswithoppositecharges,orthroughthesharingofelectronsasinthecovalentbonds.Thestrengthofchemicalbondsvaries
considerably;thereare"strongbonds"or"primarybond"suchasmetallic,covalentorionicbondsand"weakbonds"or"secondarybond"suchas
Dipole-dipoleinteraction,theLondondispersionforceandhydrogenbonding.
Sinceoppositechargesattractviaasimpleelectromagneticforce,thenegativelychargedelectronsthatareorbitingthenucleusandthepositivelycharged
protonsinthenucleusattracteachother.Anelectronpositionedbetweentwonucleiwillbeattractedtobothofthem,andthenucleiwillbeattractedtoward
electronsinthisposition.Thisattractionconstitutesthechemicalbond.Duetothematterwavenatureofelectronsandtheirsmallermass,theymustoccupy
amuchlargeramountofvolumecomparedwiththenuclei,andthisvolumeoccupiedbytheelectronskeepstheatomicnucleirelativelyfarapart,as
comparedwiththesizeofthenucleithemselves.Thisphenomenonlimitsthedistancebetweennucleiandatomsinabond.
Ingeneral,strongchemicalbondingisassociatedwiththesharingortransferofelectronsbetweentheparticipatingatoms.Theatomsinmolecules,crystals,
metalsanddiatomicgasesindeedmostofthephysicalenvironmentaroundusareheldtogetherbychemicalbonds,whichdictatethestructureandthe
bulkpropertiesofmatter.

ExamplesofLewisdot-stylerepresentationsofchemicalbondsbetweencarbon(C),hydrogen(H),andoxygen(O).Lewisdotdiagramswereanearlyattempttodescribe
chemicalbondingandarestillwidelyusedtoday.
Allbondscanbeexplainedbyquantumtheory,but,inpractice,simplificationrulesallowchemiststopredictthestrength,directionality,andpolarityofbonds.
TheoctetruleandVSEPRtheoryaretwoexamples.Moresophisticatedtheoriesarevalencebondtheorywhichincludesorbitalhybridizationandresonance,
andmolecularorbitaltheorywhichincludeslinearcombinationofatomicorbitalsandligandfieldtheory.Electrostaticsareusedtodescribebondpolarities
andtheeffectstheyhaveonchemicalsubstances.

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