KIM TRA BI C

- Th in cc chun ca kim loi l g?

- Xc nh E Mg2+/Mg.Bit E0 Pin (Mg H ) l 2,37 V ?
2
 TIT 36: BI 20: DY IN HA CA KIM LOI (tit 3)

I. KHI NIM V CP OXI HO - KH:

II. PIN IN HO: Dy th in cc
III.TH IN CC CHUN CA KIM chun ca kim loi l
LOI: g?
IV. DY TH IN CC CHUN CA KIM
LOI: Tnh oxi ha ca ion kim loi tng dn
Li+ K+ Ba2+ Ca2+ Na+ Mg2+ Al3+ Mn2+ Zn2+ Cr3+ Fe2+ Ni2+ Sn2+ Pb2+ 2H+ Cu2+ Fe3+ Hg 2+ Ag+ Pd 2+ Au3+

Li K Ba Ca Na Mg Al Mn Zn Cr Fe Ni Sn Pb H2 Cu Fe2+ Hg Ag Pd Au
-3,01 -2,93 -2,90 -2,87 -2,70 -2,37 -1,66 -1,18 -0,76 -0,74 -0,44 -0,26 -0,14 -0,13 0,00+0,34+0,77+0,79+0,80+0,99+1,50
Tnh kh ca kim loi gim dn
Theo chiu t tri sang phi: Tnh
oxi ha ca ion kim loi v tnh
- Dy th in cc chun ca kim loi l kh ca kim loi bin i nh th
dy sp xp cc kim loi theo th t tng no?
dn th in cc chun.
Theo chiu E0Mn+/M tng:
+Tnh oxi ha ca ion kim loi cng tng. So snh s ging v khc nhau gia
+Tnh kh ca kim loi cng gim. dy in ha ca kim loi v dy
hot ng ha hc ca kim loi?
 TIT 36:BI 20: DY IN HA CA KIM LOI (tit 3)

I. KHI NIM V CP OXI HO - KH:

II. PIN IN HO: Da vo yu t no
III.TH IN CC CHUN CA KIM LOI: so snh tnh oxh kh
IV. DY TH IN CC CHUN CA KIM ca cc cp oxh kh
LOI: vi nhau?
V. NGHA DY TH IN CC CHUN
CA KIM LOI:
1.So snh tnh oxi hakh:
- Da vo th in cc chun ca cp
oxh kh so snh. p n BT1:
- Tnh OXH mnh nht:Cu 2+
BT 1: Tnh oxi ha ca ion KL no
- Tnh kh mnh nht: Mg
mnh nht, tnh kh ca KL no mnh
nht ? bit :
EMg2+/Mg = -2,37V; EAl3+/Al= -1,66V;
E Cu 2+ /Cu = 0,34V
Hy rt ra quy lut so snh
Th in cc chun E0 Mn+/ M cng ln th: tnh oxi ha kh khi da
+ Tnh oxi ho ca cation Mn+cng mnh. vo th in cc chun?
+ Tnh kh ca kim loi M cng yu
v ngc li.
 TIT 36:BI 20: DY IN HA CA KIM LOI (tit 3)

I. KHI NIM V CP OXI HO - KH:

II. PIN IN HO:
III.TH IN CC CHUN CA KIM LOI:
IV. DY TH IN CC CHUN CA KIM p n BT2:
LOI:
1. So snh tnh oxi hakh: 2Ag+ + Cu
Cu 2+ + 2Ag

2. Xc nh chiu ca p oxi ha kh:

BT2: cho bit:

EAg+/Ag = +0,80 V; E Cu2+/Cu= +0,34 V
Cu 2+
Cu
Ag +
Ag
Vit ptp xy ra gia cc cp oxi ho-
kh.

Qui tc Chiu ca phn ng xy ra theo qui

tc ?
Cht OXH yu Cht OXH mnh

Cht kh mnh Cht kh yu

 TIT 36:BI 20: DY IN HA CA KIM LOI (tit 3)

I. KHI NIM V CP OXI HO - KH:

II. PIN IN HO:
III.TH IN CC CHUN CA KIM LOI:
IV. DY TH IN CC CHUN CA KL:
Nhc li cng thc
1. So snh tnh oxi hakh: tnh sut in ng v
2. Xc nh chiu ca p oxi ha kh: sut in ng chun
3.Xc nh sut in ng chun ca pin ca pin in ha.
in ha:

Eopin = Eo(+) Eo (- )

Ch : Eopin >0

BT3: Tnh sut in ng chun ca

p n BT3:
pin in ha ZnCu, bit:
E0pin = E0 Cu2+/Cu - E Zn2+/Zn
E0 Cu2+/Cu = +0,34 V ; EZn2+/Zn = - 0,76V = 0,34 (0,76) = 1,10V
 TIT 36:BI 20: DY IN HA CA KIM LOI (tit 3)

I. KHI NIM V CP OXI HO - KH:

II. PIN IN HO:
III.TH IN CC CHUN CA KIM LOI:
IV. DY TH IN CC CHUN CA KL:
V. NGHA CA DY TH IN CC
CHUN CA KIM LOI:
1. So snh tnh oxi hakh:
2. Xc nh chiu ca p oxi ha kh:
3. Xc nh sut in ng chun ca pin
in ha:
4. Xc nh th in cc chun ca cp p n BT4:
oxihakh: E0pin = E0 Ag+/Ag E0 Zn2+/Zn
BT4: Bit sut in ng chun ca pin E0 Zn2+/Zn = E0 Ag+ /Ag - E0pin
in ha Zn Ag l 1,56 V v th in = +0,80 1,56 = 0,76 V
cc chun ca cp oxi ha kh
Ag+/Ag l +0,80 V. Hy xc nh th in
cc chun ca cp Zn2+/Zn

- Khi bit E0pin v th in cc chun ca

1 cp oxi hakh th tnh c th
in cc chun ca cp oxi hakh
cn li.
 TIT 36: BI 20: DY IN HA CA KIM LOI (tit 3)

I. KHI NIM V CP OXI HO - KH:

II. PIN IN HO:
III.TH IN CC CHUN CA KIM LOI:
IV. DY TH IN CC CHUN CA KIM
LOI:
Theo chiu E0 Mn+/ M tng:
+Tnh oxi ha ca ion kim loi cng mnh.
+Tnh kh ca kim loi cng yu .
V. NGHA CA DY TH IN CC
CHUN CA KIM LOI:
So snh tnh oxi hakh.
Xc nh chiu ca p oxi ha kh.
Xc nh sut in ng chun ca
pin in ha.
Xc nh th in cc chun ca cp
oxi hakh
 CU HI TRC NGHIM 9
8
7
6
5
4
3
2
1
10
Cu 1: Cho (1)E0 Fe2+/ Fe = -0,44 V; (2) E 0 Na+/ Na = -2,70 V;
(3)E0 Cu2+/ Cu = +0,34 V;(4) E0 Zn2+/ Zn = -0,76 V;
(5) E0 Fe3+/ Fe2+ = +0,77 V
A.1, 2, 3, 4, 5.
B.2, 1, 3, 4, 5.
C. 2, 4, 1, 3, 5.
D.5, 3, 1, 4, 2.
 CU HI TRC NGHIM 9
8
7
6
5
4
3
2
1
10
Cu 1: Cho E0 Mg2+/ Mg = - 2, 37 V; E0 2H+/ H2
= 0,00 V;

A. Mg2+ + 2H+ Mg + H2
B. 2H+ + Mg Mg2+ + H2

C. Mg + H2 Mg2++ 2H+

D. Mg2+ + H2 Mg + 2H+
 V NH :
- Lm bi tp: Trang 112 SGK 12 NC
- Chun b:
Cu 1:Tnh cht chung ca Kim loi. Nguyn nhn?
Cu 2:Sut in ng chun ca kim loi ging hay
khc so vi sut in ng ca kim loi.
+ Chun b trc phn bi tp Trang 125,126 SGK 12 NC
BI TP:

Tnh th in cc chun ca cp oxi ha kh Ni2+/ Ni.

Bit E0Pin( Ni-Cu) = 0,60 V v E0 Cu 2+ / Cu = +0,34 V.

GII:
Ta c: E0 Pin( Ni-Cu) = E0 Cu
2+
/ Cu - E0 Ni2+/ Ni
E0 Ni 2+/ Ni = E0 Cu2+/ Cu - E0 Pin( Ni-Cu)
= 0,34 0,60 = -0,26 V