Smart Polymers and Their Applications

INSTRUCTOR: Van Pham Dan Thuy.Ph.D

STUDENTS: Pham Quoc Phu _B1703290

Nguyen Hong Ngoc_B1710101

Content
Introduction

Part I: Overview of Classification

Smart Polymers

Synthesis

Drug Delivery

Part II: Application of Oil Recovery

Smart Polymers

Textile Engineering

Part III: Conclusion

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Part I: Overview of Smart Polymers
1. Introduction
Smart polymers are high – performance polymers that change in the environment like as:
- Temperature, humidity, pH and chemical compound.
- Intensity of light, an electrical, magnetic field and mechanical strength.

Figure 1: The effects of stimuli of smart polymer in drug delivery

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2. Classification
Table 1: Stimuli - Responsive Smart Polymeric Materials
Types of Stimulus Responsive Polymer Material
pH *dendrimers

*poly(L-lysine) ester

*poly(hydroxyproline)

*Lactose-PEG grafted poly(L-lysine) nanoparticle

*poly(L-lysine)-g-poly(histidine)

*poly(propyl acrylic acid)

*polysilamine

*Eudragit S-100

*Eudragit L-100

*Chitosan

*PMAA-PEG copolymer

Light *poly (axit acrylic)

*polyimide

*polyamide

*poly (ethyl acrylate)

*poly ( N - (2-hydroxypropyl) methacrylamide)

*poly ( N -isopropylacrylamide) –PNIPAM

*poly (2-dimetylaminoetyl metacrylat) -PDMAEMA

Temperature PNIPAAm
Magnetic field PNIPAAm hydrogel containing ferromagnetic material PNIPAAm-co-
acrylamide
2.1 pH sensitive smart polymers
The smart polymers contain some groups as functional acid or basic
- Accepting or releasing protons with pH changes.
- Application for drug delivery and wastewater

Figure 2: Structure and states depending on the ionization of the ionic chain groups of pH - responsive
polyelectrolytes (A) poly(acrylic acid) and (B) poly (N,N-dimethylaminoethylmethacrylate)

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2.1.1 Polymers with functional acid groups
The polyacids or polyanion are pH sensitive polymers in their structure contain the acidic groups
For example: Polyacrylic acid can accept ion metals in solution when pH scales increase.

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spectrum of visible located between historically been
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 Let’s review some concepts

Yellow Blue Red

Is the color of gold, butter and
ripe lemons. In the spectrum
of visible light, yellow is found
between green and orange.
Is the colour of the clear sky
and the deep sea. It is located
between violet and green on
the optical spectrum.
Is the color of blood, and
because of this it has
historically been associated
with sacrifice, danger and
courage.

Blue Yellow Red

Is the colourIsofthe
thecolor
clearofsky
gold, butter and Is the color of blood, and
ripe lemons. In
and the deep sea. It is located the spectrum because of this it has
of visible
between violet light,on
and green yellow is found historically been associated
between
the optical spectrum. green and orange. with sacrifice, danger and
courage.

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