matter is composed of tiny, indivisible particles called atoms. However, their atomic theory was based only on assumptions. It was not until the early 1800s that experiments were performed to develop models for the structure of the atom. JOHN DALTON
In 1803, John Dalton, a British scientist, did
experiments on mixtures of gases. He studied how the properties of individual gases affect the properties of the mixtures of these gases. He developed the hypothesis that the sizes of the particles making up different gases must be different. JOHN DALTON
After several experiments, he concluded that all
matter is composed of spherical atoms, which cannot be broken down into smaller pieces. He added that all atoms of one element are identical to each other but different from the atoms of another element. Discovery of the Subatomic Particles
The Electrons in the Plum Pudding Model
In 1897, Joseph John Thomson, a British physicist,
proposed an atomic model known as the plum pudding model. His model consisted of negatively charged particles (plum) spread evenly throughout the positively charged material (pudding). The small, negatively charged particles are called electrons. The Protons in the Planetary Model
In the early 1900s, Ernest Rutherford, a New Zealand-
born physicist, established the planetary model which described the atom as small, dense, and has a positively charged core called the nucleus. Inside the nucleus are positively charged particles called the protons. The nucleus is surrounded by negatively charged particles or electrons. The electrostatic attraction between electrons and nucleus mimics the gravitational force of attraction between planets and the sun. The Neutrons
In 1923, James Chadwick proved the existence of
the neutron, which is also situated in the nucleus together with the proton. It has the same mass as the proton but unlike the latter, it has no electric charge. Recent Atomic Models Bohr’s Atomic Model Rutherford’s model showed that the electrons and nucleus have opposite charges which according to the laws of physics, will attract each other. Thus, Rutherford's model would have electrons collapsing into the nucleus, making the atom unstable. Niels Bohr solved this problem by proposing that the electrons orbit around the nucleus in set energy levels. An electron absorbs energy if it moves from lower to higher energy level, and it emits energy if it returns to the lower energy level. Quantum Mechanical Model The quantum mechanical model of the atom states that a nucleus is surrounded by a cloud of electrons called orbitals. It explains that it is impossible to determine the exact location of the electron at a given time, but one can find its probable location. It incorporates the concept of Bohr’s model where the electrons move in one orbital to another by absorbing or emitting energy. Key Points John Dalton described the atom as spherical.
Joseph John Thomson discovered the electron.
Ernest Rutherford proposed that the electrons orbit around the nucleus. He, together with his students, discovered the proton. Niels Bohr proposed that electrons orbit around the nucleus in set energy levels. James Chadwick discovered the neutron. Niels Bohr proposed that the electrons orbit around the nucleus in set energy levels. In the quantum mechanical model, the nucleus is surrounded by a cloud of electrons called orbitals.