EQUILIBRIO LIQUIDO-VAPOR, ECUACIÓN DE CLAUSIUS CLAPEYRON

In this case, the molar volume of the liquid is often negligible compared to
the volume of the vapor:
  (Assumption I )
Therefore,
  𝑙
𝑣 ≈0 Away from the critical point

If additionally we consider the vapor to obey the ideal gas model

(Assumption II )
 EQUILIBRIO LIQUIDO-VAPOR, ECUACIÓN DE CLAUSIUS CLAPEYRON

the coexistence equation for vapor–liquid equilibrium becomes:

 And represent the enthalpy of vaporization and the saturation

pressure, respectively, of species i at temperature T.

Clausius–Clapeyron equation
 EQUILIBRIO LIQUIDO-VAPOR, ECUACIÓN DE CLAUSIUS CLAPEYRON
It can be rewritten in the form:
(1)

If we assume the enthalpy of vaporization is independent of temperature, that is

Assumption III

integrate Equation between state 1 and state 2 to get

Assumption III is not valid
over large temperature
ranges
or write the indefinite integral of Equation (1):

Usen esta ecuación para resolver el ejercicio