KULIAH 11

TERMOFISIK
TOPIK
Kapasitas panas
◦ Kapasitas panas pada volume konstan
◦ Kapasitas panas pada tekanan konstan
Kapasitas panas campuran
Kapasitas panas
Assuming ideal-gas behavior, calculate the
heat that must be transferred in each of the
following cases.
A stream of nitrogen flowing at a rate of
100 mol/min is heated from 20°C to
100°C.
Nitrogen contained in a 5-liter flask at an
initial pressure of 3 bar is cooled from
90°C to 30°C.
Penyelesaian
 Soal
1. ΔH(kJ/mol) for toluene vapor going from 40°C to 300°C.
2. ΔH(kJ/mol) for solid calcium carbonate going from 40°C to
300°C.
3. Chlorine gas is to be heated from 120°C and 1 atm to 180°C.
a. Calculate the heat input (kW) required to heat a stream of
the gas flowing at 15.0 kmol/min at constant pressure.
b. Calculate the heat input (kJ) required to raise the
temperature of 15.0 kmol of chlorine in a closed rigid
vessel from 120°C and 1 atm to 180°C. (Suggestion:
Evaluate ΔU directly from the result of the first calculation,
so that you do not have to perform another integration.)
 Kasus kapasitas panas campuran

Hitunglahentalpi dari campuran gas

dengan komposisi sebagai berikut :
CO2 = 9,2%
CO = 1,5%
O2 = 7,3%
N2 = 82%
Yang didinginkan dari suhu 200oC sampai
80oC, abaikan uap air dalam gas