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Palm Oil
Palm Oil
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Oil palm – tree
Palm oil – obtained from fruits of oil
palm
Nursery
pollination proc
oil palm
8” height
plantations
(area wt plenty rainfall and good
drainage system)
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Structure of oil palm fruit
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Uses of palm oils and biomass in
food and manufacturing industries
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Extraction of crude palm oil
1. Bunch reception
- Bunches transported to mill by road
trucks or lorries or cages running on
specially built railway system
- Fruits graded as unripe (10 loose
fruitlets), ripe (10 or > loose fruitlets),
overripe ( excessive loose fruits), rotten
(loose fruits detached)
- Fruits carried to loading ramps once
grading report approved
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2. Loading ramp
- FFB unloaded into ramp hopper
then fruit cages pushed by
locomotive or skid loader to
sterilizer yard
- Old fruits taken out for processing
to avoid accumulation of old fruits
that rot and creating high FFA
problem (< 5%)
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3. Sterilization
- Fruits charged into steriliser usg saturated
steam 40 psig
- 5 functions of sterilising:
a. prevention of further rise of FFA
b. facilitation of mechanical stripping
c. preparation of fruit pericarp
d. preconditioning of nuts to minimise kernel
breakage
e. coagulation of protein material & hydrolysis of
mucilaginous material
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6. Oil extraction
- By pressing usg screw press consist of
perforated cage runs in single or double
screw
- Screw press made from tough & wear
resistant steel
- Press cages from SS
- Discharge fr screw press consists of
crude oil liquor & a matte of oily
fibre&nuts
- Crude oil to vibrating screens to be
separated from solids for clarification
- Fibre&nuts carried by steam jacketed
conveyor before splitting separate ways
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7. Clarification & purification of CPO
- Crude oil prod. by pressing contains water &
impurities
- 66% oil, 24% water and balance as non-oily
solids
- Clarification: water & impurities removed to give
clear stable prodt of acceptable appearance
- Water removed by gravity settling or
centrifuging
- Crude oil diluted first wt hot water to reduce
viscosity, screened to remove coarse fibrous
material
- Then heated to 90-95oC, pumped to continuous
settling tank
- Retention in tank enable oil to rise to surface
and overflow into reception tank
- Further purified by centrifuging reduces dirt to
0.01% or <
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- Moisture still exist in oil removed by
evaporation in dehydrator with or without
vacuum
- In practice, some moisture retain to avoid
oxidation in oil
- Underflow from settling tank: sludge
containing some oil which can be
recovered by centrifuging
- Rest of sludge sent to effluent treatment
plt.
- Anaerobic digestion of POME produces
methane used to generate in-house
electricity
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8. Nut & kernel station
- Nuts & fibres separated in
depericarper station
- Fibres act as fuel to boiler
- Wet nuts elevated to nut bin (60-
77oC)
- Dry nuts separated from shells usg
nut cracking machines
- Shells as fuel for boiler
- Kernels stored in silo
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Processing of Palm Oil and Palm Kernel Oil
Palm Oil and palm kernel oil - two different
oils or fats which can be extracted from the
fruit of the oil palm (Elaeis guineensis)
semi-solid at room temperature
fractionated into solid and liquid fractions
known as stearins and oleins respectively
processed through physical or chemical
refining to yield either refined, bleached and
deodorized (RBD) or neutralized, bleached
and deodorized (NBD) palm oil and palm
kernel oil
Combinations of these processes lead to
various types of palm oil and palm kernel oil
products (see figure 1)
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Refining of crude palm oil
Composition of palm oil: fatty acids namely
palmitic (45%), stearic, oleic, linoleic, free
fatty acids, mono & diglycerides and
impurities ( trace metals n oxidation prodts)
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1. Degumming
- Process to remove gums containing calcium n
magnesium that give oil inferior quality n
shorter shelf-life
- Concentrated phosphoric acid 0.1% wt is
sufficient to remove phosphatides
2. Neutralisation
- Oil is neutralised by NaOH resulting in soapstock
n separated usg centrifuge n washing with water
- Any soap retained removed by adding citric or
phosphoric acid to final wash prior to oil drying
- Losses occur normally attributed to the
followings:
a. FFA
b. mucillage, colouring matter n impurities
c. saponification of neutral oil
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3. Drying
- Reduce moisture content <0.06% usg vacuum
dryer
- Why?? Moisture cause FFA rise due to
autocatalytic hydrolysis
4. Bleaching n filteration
- Purpose of bleaching:
a. to obtain the lightest colour possible
b. to remove traces of soaps present
c. to remove traces of nickel
- Bleaching carried out usg adsorbent clay or
carbon in absence of O2 under steam, N2
blanket or vacuum
- 0.5 - 2% bleaching agent quantity
- 80 – 180 oC temperature
- Once bleaching complete, oil pumped thru a
filter n recycle until filter cake formed, then
transferred to continuous deodoriser 30
5. Deodorisation
- Final stage of oil refining
- To reduce oil to odourless n tasteless by
removing volatile odiferous n flavoured
substances (aldehydes, ketones n FFA)
- Steam distillation under vacuum
- Process x reduce trace metals or
phosphatide levels
- Oil cooled to 55oC exiting deodoriser
6. Polishing
- Oil pumped thru polishing filter giving
finished oil its final sparkle
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Physical refining
- Actually combining neutralization n
deodorisation usg steam distillation under
vacuum
- Operation cost > than chemical refining
but less hassle wt byprodts hence
preferable
- Suitable for high quality vegetable oil wt
low FFA
- Better quality oil (FFA distill to 95%)
- Proc also removed tocopherols hence
special precaustions taken drg storage
(short time only) n shipping (antioxidant
control)
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Fractionation flowscheme
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Fractionation
- A thermomechanical process by which raw
material is separated into two or more portions
- Normally usg distillation n crystallization
- But distillation not suitable for triglycerides
mixtures becoz low vap pressure n low stability at
high T
- Oil composition crystallized by controlled cooling
followed by separation yielding liquid 30-40%
olein n solid 60-70% stearin
- Also, minor component of original oil became
concentrated n give effect on oxidative stability of
fractions
- Constant monitoring of proc n prodts to ensure
prodt quality
- 3 methods for fractionation of palm oil
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1. Dry process
- Oil crystallized and separated usg
filtration
- Oil first heated 70-75 oC to melt all
crystal nuclei n passed to crystaliser
- Crystallization proceeds by initially
cooling to 45oC in 45 mins
- Further cooling 18-20 oC abt 4-8
hrs before pump to filter
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2. Detergent process
- Oil crystallized but separated by employing
aqueous detergent solution n centrifuge
- Similar crystallization step to dry process
- A continuous supply of slurry mixed wt
detergent soln (sodium lauryl sulphate) pumped
to crystallizer
- Solution displaced oil fr stearin crystal surface
- On centrifuge, olein discharged as oil phase n
stearin forms part of aqueous phase
- Aqueous phase heated 90-110 oC to break away
stearin from emulsion
- Cooled n centrifuged to recover stearin
- Detergent recycled to plant
3. Solvent process
- Employs crystallization n filtration but least
preferred in industries hence not quite
established 36
Oleochemicals
chemicals derived from oils and fats
analogous to petrochemicals which are
chemicals derived from petroleum
based on C12-C14 and C16-C18 chain
lengths have a variety of uses
Tallow and coconut oil have been the
traditional raw materials used for the
production of C16-C18 and C12-C14 chain
lengths respectively
The hydrolysis or alcoholysis of oils and fats
formed the basis of the oleochemicals
industry
The five basic oleochemicals are fatty acids,
fatty Methyl esters, fatty alcohol, fatty
nitrogen compounds and glycerin.
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1. Fatty Acids
High temperature and high pressure splitting of Palm Oil or Palm kernel
Oil to produce crude fatty acids and glycerin as a by product
Distillation of the crude fatty acids to produce distilled or fractionated
fatty acids which is a high purity fatty acids
3. Fatty Alcohol
Hydrogenation of distilled or fractionated methyl ester at high
temperature and pressure in the presence of catalyst to produce crude
fatty alcohol
Distillation to produce distilled fatty alcohol
5. Glycerin
Glycerin is a valuable co-product of the oleochemicals industry.
It has many applications such as in pharmaceuticals and cosmetics
industry. 38
Biodiesel
1. What is biodiesel?
Biodiesel is a substitute for fuel, for diesel engines made from renewable
fats and oils such as palm oil, soybean and rapeseed oil. Biodiesel contains
no added sulfur and burns much cleaner than diesel fuel from petroleum
based product. Biodiesel can be used in existing diesel engines with little
or no modification.