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  • EDC Section Project Presentaion 1 (Intro Capacity M&E Balaces)

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    NOMAN ASHRAF
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    The document describes the water gas shift reaction for producing hydrogen fuel from methane. It discusses how temperature conditions impact the reaction and hydrogen production. Low temperature conditions increase hydrogen production while reducing carbon monoxide. Medium temperatures use copper-zinc catalysts but are impacted by sulfur pollution. High temperatures use iron-chromium catalysts and produce more carbon monoxide. The mechanism of the water gas shift reaction involves the adsorption, formation, and desorption of water, carbon monoxide, hydrogen, and carbon dioxide on the catalyst surface.

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    The document describes the water gas shift reaction for producing hydrogen fuel from methane. It discusses how temperature conditions impact the reaction and hydrogen production. Low temperature conditions increase hydrogen production while reducing carbon monoxide. Medium temperatures use copper-zinc catalysts but are impacted by sulfur pollution. High temperatures use iron-chromium catalysts and produce more carbon monoxide. The mechanism of the water gas shift reaction involves the adsorption, formation, and desorption of water, carbon monoxide, hydrogen, and carbon dioxide on the catalyst surface.

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    © All Rights Reserved
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    8 views5 pages

    EDC Section Project Presentaion 1 (Intro Capacity M&E Balaces)

    Uploaded by

    NOMAN ASHRAF
    The document describes the water gas shift reaction for producing hydrogen fuel from methane. It discusses how temperature conditions impact the reaction and hydrogen production. Low temperature conditions increase hydrogen production while reducing carbon monoxide. Medium temperatures use copper-zinc catalysts but are impacted by sulfur pollution. High temperatures use iron-chromium catalysts and produce more carbon monoxide. The mechanism of the water gas shift reaction involves the adsorption, formation, and desorption of water, carbon monoxide, hydrogen, and carbon dioxide on the catalyst surface.

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
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    of 5

    Low Temperature Condition

    Medium Temperature
    Condition

    High Temperature Condition

    Water Gas Shift


    Reaction
    Methanol Synthesis from
    Wood Feedstock
    1
    Description of Process

    • Production of pure H2 fuel • Exothermic reaction


    • Steam reforming of methane • HTC increase rate of
    • LTC increase H2 production reaction
    • Equilibrium constant
    dependence on
    WGS temperature
    CO & H20
    Reaction
    Combination Nature

    Scale Up Reaction
    Production Conversion
    • Multiple adiabatic step process
    • HTC led by LTC • Optimization using
    • Internal cooling system catalyst
    • Favorable at low
    temperature
    2
    Comparison of Temperature Condition for Process

    Low Temperature Condition Medium Temperature Condition High Temperature Condition

    • Reduce production of CO & • Syngas source that has no • No appreciable levels of


    Increase production of H2 significant levels of Sulphur Sulphur
    •

    • Zn-Cu catalyst use • Copper zinc alumina • copper-promoted iron-


    • Polluted by Sulphur chromium catalyst
    • Polluted by Sulphur

    • 0.2 % CO formation HTC • 0.5 % CO formation in MTC • 2.5 % CO formation in LTC


    led by LTC
    • Temperature range 325°F to • Temperature range 600°F to
    •• H
    Temperature range 350°F to 625°F 800°F
    500°F

    3
    Mechanism of WGS

    Adsorption of H2O & CO on Catalyst Surface

    Formation of H2 and CO2 on catalysts Surface

    Desorption of H2 & CO2 on Catalyst Surface

    4
    References

    1. I. L. Junior, J.-M. M. Millet, M. Aquino, and M. do Carom Rangel, “The role of vanadium on the properties of iron
    based catalysts for the water gas shift reaction,” Applied Catalysis A: General, vol. 283, no. 1-2, pp. 91–98, 2005.
    2. C. Martos, J. DuFour, and A. Ruiz, “Synthesis of Fe3O4-based catalysts for the high-temperature water gas shift
    reaction,” International Journal of Hydrogen Energy, vol. 34, no. 10, pp. 4475–4481, 2009.
    3. A. Boudjemaa, C. Daniel, C. Mirodatos, M. Trari, A. Auroux, and R. Bouarab, “In situ DRIFTS studies of high-
    temperature water-gas shift reaction on chromium-free iron oxide catalysts,” Comptes Rendus Chimie, vol. 14, no.
    6, pp. 534–538, 2011.

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