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kf
q -k f
ki
r r
ki = k f ≡ k → q = 2k sin(α /2)
• q = momentum transfer
Diffraction scattering
r r
ki = k f ≡ k → q = 2k sin(α /2)
• Measure the scattering intensity as a function of to infer
the distribution of charge in the nucleus, ρ( r′)
r r
€ F ( ki , k f ) = ∫ ψ *f V ( r)ψ i dv
r r
F (q) = ∫e iq • r
V ( r) dv €
V ( r) equation 3.4
4π
F (q) =
q
∫ sin(qr′)ρ e ( r ′) r′dr′
Diffraction scattering
4π
F (q) = ∫ sin(qr ′) ρ e ( r′) r′dr′
q
2
• Measure the scattering intensity F (q) as a function of
to infer the distribution of charge in the nucleus
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Atomic X-rays
• Assume the nucleus is uniform charged sphere.
• Potential V is obtained in two regions:
– Inside the sphere
Ze 2 ⎧⎪3 1 ⎛ r ⎞2⎫
⎪
V ′( r) = − ⎨ − ⎜ ⎟⎬ r≤ R
⎩2 2 ⎝ R ⎠ ⎪
4πε oR ⎪ ⎭
€
Atomic X-rays
• For an electron in a given state, its energy depends on -
*
V = ∫ ψ n Vψ n dv
• Assume ψ does not change appreciably if V pt Vsphere
n
V ′ = ∫ ψ n* V ′ψ n dv + ∫ ψ n* Vψ n dv
€ r<R r>R
• Then, E = Esphere - Ept
• Assume
ψ ncan be giving (3.12)
ψ1,1(1s) , n=1, l =0
€ €
Atomic X-rays
E between sphere and point nucleus for ψ1,1(1s) ΔE1s
2 Z 4e 2 R2 E1s(sphere)
ΔE1s =
5 4πεo ao3 E1s( pt)
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• Compare this E to measurement and we have R. €
€ • €
Problem!
• We will need two measurements to get R --
• Consider a 2p 1s transition for (Z,A) and (Z,A’) where
A’ = (A-1) or (A+1) ; what x-ray does this give?
E Kα ( A) − E Kα ( A′) =
= [ E 2 p ( A) − E1s ( A)] − [ E 2 p ( A′) − E1s ( A′)]
Atomic X-rays
E Kα ( A) − E Kα ( A′) =
= [ E 2 p ( A) − E1s ( A)] − [ E 2 p ( A′) − E1s ( A′)]
= [ E 2 p ( A) − E 2 p ( A′)] − [ E1s ( A) − E1s ( A′)]
3 e2
ΔE C = A2 /3
5 4πε o R o Measure EC; How?
Assume R is same for both nuclides. Why?
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Measurement of nuclear radius
• Three methods outlined for nuclear matter
radius:
– Rutherford scattering
– Alpha particle decay
-mesic x-rays