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Term Okimi A
Term Okimi A
900C
400C
greater thermal energy
6.2
Thermochemistry is the study of heat change in chemical
reactions.
The system is the specific part of the universe that is of
interest in the study. SURROUNDINGS
SYSTEM
6.2
3. Pengantar Termodinamika
E = Ef-Ei
E = E produk – E Reaktan
Esis + Eling = 0
Esis = - Eling
E = q + w 1
Is H negative or positive?
Endothermic
H > 0
Is H negative or positive?
Exothermic
H < 0
6.3
Thermochemical Equations
1 mol P4 3013 kJ
266 g P4 x x = 6470 kJ
123.9 g P4 1 mol P4
6.3
5. Calorimetry
The specific heat (s) of a substance is the amount of heat (q)
required to raise the temperature of one gram of the
substance by one degree Celsius. J/g
The heat capacity (C) of a substance is the amount of heat
(q) required to raise the temperature of a given quantity (m)
of the substance by one degree Celsius. J/0C
C = ms
6.4
How much heat is given off when an 869 g iron bar cools
from 940C to 50C?
s of Fe = 0.444 J/g • 0C
6.4
Constant-Volume Calorimetry
Reaction at Constant V
H = qrxn
H ~ qrxn
No heat enters or leaves!
6.4
Constant-Pressure Calorimetry
Reaction at Constant P
H = qrxn
aA + bB cC + dD
Hrxn
0
= [ cH0f (C) + dH0f (D) ] - [ aH0f (A) + bH0f (B) ]
Hrxn
0
= nH0f (products) - mHf0 (reactants)
Hrxn
0
= nH0f (products) - mHf0 (reactants)
Hrxn
0
= [ 12H0f (CO2) + 6H0f (H2O)] - [ 2Hf0 (C6H6) ]
Hrxn
0
= [ 12x–393.5 + 6x–187.6 ] – [ 2x49.04 ] = -5946 kJ
-5946 kJ
= - 2973 kJ/mol C6H6
2 mol
6.5
Calculate the standard enthalpy of formation of CS2 (l)
given that:
C(graphite) + O2 (g) CO2 (g) Hrxn 0
= -393.5 kJ
S(rhombic) + O2 (g) SO2 (g) Hrxn
0
= -296.1 kJ
CS2(l) + 3O2 (g) CO2 (g) + 2SO2 (g) H0rxn = -1072 kJ
1. Write the enthalpy of formation reaction for CS2
6.6
The Solution Process for NaCl