Luminescence properties of Sm3+ doped Li3BaSrLn3(MoO4)8

red‐emitting phosphors for solid‐state lighting

Presented by
R.Sivaji Naik
415CY5009
Under the guidance of
Dr.V. Sivakumar

Department of Chemistry
National Institute of Technology Rourkela,
Rourkela, Odisha, INDIA-769008
CE
 OEL

Contents:
 Introduction
 Synthesis of phosphor
 Results and discussion
- XRD
- FT-IR
- PL Excitation and emission spectrum
- Concentration quenching studies
- Lifetime
- LED
 Conclusion

OEL, Dept. of Chemistry, NIT Rourkela 2

 Introduction OEL

• Phosphor is any kind of material which can emit light by absorbing various energies with
out heat generation.
• Various process occurring in phosphor materials which is shown below.
• Combining near-ultraviolet (near-UV) LED chips with tri-colour (red, green, and blue)
phosphors are developed. Green and blue colour LED chips are commercially available
• For synthesis of red phosphor we choose one host lattice Li3BaSrLn3(MoO4)8 where (Ln =
La,Gd, Y) with samarium (Sm3+) doped .

H H H H

H S A H

H H H H

OEL, Dept. of Chemistry, NIT Rourkela 3

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Li3Ba2La3(MoO4)8:Eu3+

Li3BaSrLa3(WO4)8:Eu3+
Arturas Katelnikovas et.al., J. Mater. Chem., 2012, 22, 22126–22134

Kasturi Singh and Sivakumar Vaidyanathan., ChemistrySelect 2017, 2, 5143 – 5156

OEL, Dept. of Chemistry, NIT Rourkela 4

 Experimental OEL

Motivation of the present study

Molybdate based Sm3+ activated phosphor orange red phosphor.
Molybdate based phosphor can give broad excitation band.
MoO4 can transfer energy to Sm3+.

Synthesis Sm3+ doped Li3BaSrLn3(MoO4)8 :

BaCO3, La2O3, Sm2O3, Gd2O3, Y2O3, Li2CO3, SrCO3, MoO3,

 500οC for 12 hrs and 850οC for 12 hrs

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 XRD of Li3BaSrLn3(MoO4)8 OEL

Li3BaSrGd3(MoO4)8: Sm3+ Li3BaSrY3(MoO4)8 : Sm3+ Li3BaSrLa3(MoO4)8: Sm3+

 Lattice parameters are a=5.2805 A˚, b=12.7174 A˚, c=18.8233 A˚,

and α = γ = 90° and β ≠ 90° Li3BaSrY3(MoO4)8
 Crystal structure is monoclinic with space group C21/c

OEL, Dept. of Chemistry, NIT Rourkela 6

Crystal structure Li3BaSrY3(MoO4)8: Sm3+ OEL

Ba/Sr Y/Li (1)

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 SEM & FT-IR OEL

 Sharp peak placed at 416.8 and 433.3 cm-1 which is responsible for stretching
vibrations of O-Mo-O of MoO4 group in the host lattice.

 Small peak at 1700cm-1 for O-H stretching of H2O molecules.

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 PL-Excitation of Li3BaSrLn3(MoO4)8: Sm3+ OEL

Li3BaSrGd3(MoO4)8
Li3BaSrY3(MoO4)8
Sm3+
Mo6+ f-f

406 nm
Li3BaSrLa3(MoO4)8 O2- O2-
OEL, Dept. of Chemistry, NIT Rourkela 56
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 Emission of Li3BaSrLn3(MoO4)8: Sm3+ OEL

Li3BaSrY3(MoO4)8 Li3BaSrGd3(MoO4)8

Li3BaSrLa3(MoO4)8
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 Asymmetric ratio OEL

Li3BaSrY3(MoO4)8
Electric dipole Magnetic dipole
R1 > R2 Concentration R1 R2

0.03 7.4291 3.0003

R1 = I(4G5/2/6H9/2)/I(4G5/2/6H5/2) 0.05 8.0807 3.1081

0.1 7.9549 3.1357

R2 = I(4G5/2/6H7/2)/I(4G5/2/6H5/2)
0.3 7.5700 3.0735
Li3BaSrGd3(MoO4)8
0.5 7.4185 3.0483
Concentration R1 R2
Li3BaSrLa3(MoO4)8
0.03 7.3552 2.9637
Concentration R1 R2
0.05 8.0757 3.0475
0.03 8.4392 2.9290
0.1 7.7080 3.0140
0.05 7.8525 2.8411
0.3 7.2455 3.0326
0.1 7.7371 2.8819
0.5 7.4006 3.0662
0.3 8.5093 3.0292
Lili Wang et al., RSC Adv., 2015, 5, 89290 0.5 8.1553 3.0218

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Energy transfer Mechanism OEL

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 Concentration quenching study OEL

Li3BaSrY3(MoO4)8 Li3BaSrGd3(MoO4)8

Li3BaSrLa3(MoO4)8

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 log (I/C) Vs log C Calculation OEL

Li3BaSrGd3(MoO4)8
Li3BaSrY3(MoO4)8

Huang description
 
Li3BaSrLa3(MoO4)8

Energy transfer between Sm3+ ions inside the

particles
Kasturi . S and Sivakumar . V, ChemistrySelect 2016, 1, 5448 – 5462

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 Lifetime data OEL

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 CIE OEL

Li3BaSrY3(MoO4)8:Sm3+ Li3BaSrGd3(MoO4)8:Sm3+

Li3BaSrLa3(MoO4)8:Sm3+

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 LED OEL

OEL, Dept. of Chemistry, NIT Rourkela 17

 Summary and Conclusions OEL

 XRD indicates that purity of crystal structure

 SEM shows phosphor contains irregular morphology and the particles
are aggregated
 IR strong stretching vibration at 406 and 433 cm-1 of O-Mo-O of MoO4.
 Excitation spectra contains broad band in the region of 220-350 nm and
sharp intense peaks in the range of 360-500 nm.
 Emission spectra exhibited the sharp orange red emission at 646 nm, also
it consist of several sharp peaks at 563, 599, 645 and 705 nm.
 Increasing the concentration of the Sm3+ the lifetime values were
decreases gradually.
 All the synthesized phosphor exhibits the orange red emission with
excellent CIE chromaticity coordinates.
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Li3BaSrLn3(WO4)8:Eu3+

Bo Wei et.al., J. Mater. Chem. C, 2015, 3, 12322--12327

OEL, Dept. of Chemistry, NIT Rourkela 56
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