EXTRACTION, REFINEMENT, AND TESTING

OF GREEN BASED INHIBITORS FROM

PLANTS

Realized by: Assisted by:

TOUIL Elmehdi
TAKTOUR Ayoub Pr FISCHER Christian
BEN RAZZOUQ Salah-Eddine

1
Corrosion
 PREVENTION METHODS OF CORROSION

• Metal Type • Protective Coating • Sacrificial Coatings

• Environmental Measures • Corrosion Inhibitors

 CORROSION INHIBITORS

• Definition
• An inhibitor is a chemical
substance or combination of
substances which when added in
very low concentrations in a
corrosive environment effectively
prevents or reduces corrosion
without significant reaction with
the components of the
environment.
inhibitors.
 CLASSIFICATION OF INHIBITORS

• Inorganic inhibitors • Organic inhibitors • Environmental conditioner

• Anodic • Cathodic • Film forming • Scavenger inhibitors

•Passivating •Precipitation • Green inhibitors

inhibitors inhibitors

• Poisoning
inhibitors
 CLASSIFICATION OF INHIBITORS

• Anodic inhibitors
• Passivating inhibitors
Fe→Fe+2+2e-
E CrO4 - +8H + +3e- →Cr+3+4H2O

• Cathodic Tafel slope

• E’corr
• E corr
• Anodic Tafel slope

• I’ corr • I corr I • Ex: chromate inhibitors

 CLASSIFICATION OF INHIBITORS

• Cathodic inhibitors

E
• Cathodic Tafel slope

• E corr
• Anodic Tafel slope
• E’corr

• I’ corr • I corr I
 CLASSIFICATION OF INHIBITORS

• Cathodic inhibitors
• Precipitation inhibitors
SO42- + Ca2+ ==> CaSO4

• Precipitation inhibitors are chemicals that cause

the formation of precipitates on the surface of
the metal. Thus, providing a protective film and
increasing the resistance of the metal.
• Ex: hard water.
 CLASSIFICATION OF INHIBITORS

• Cathodic inhibitors
• Poisoning inhibitors

• Poisoning inhibitors retard 2H+ + 2e  H2 Acidic solution

the evolution of hydrogen
reaction. M  Mn+ + ne
 CLASSIFICATION OF INHIBITORS

• Organic inhibitors

• Physisorption • Chemisorption

These inhibitors are

adsorbed on the surface of
the metal to form a
protective film. The
adsorption can be done in . .
+++ +
---- two different ways. . .
 CLASSIFICATION OF INHIBITORS

• Environment conditioner
• Oxygen Scavenger inhibitors

• These inhibitors react with

O2+ 4H+ + 4e  2H20
dissolved oxygen to
deoxygenate the corrosive
environment and reduce the O2+ H20+ + 4e  4OH-
overall rate of the metal
corrosion. M  Mn+ + ne
 Plant
INHIBITORS PROCESS
Methods

Extraction

Methods

Purification

Methods
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Characterization Inhibitors Electrochemical tests

What? Application How?

 BASIC INFO PARAMETERS OBTAINED WITH SEVERAL PLANT EXTRACTS
EVALUATED AS CORROSION INHIBITORS IN STEEL .

13

Plant Extracts as Green Corrosion Inhibitors for Dierent Metal Surfaces and Corrosive Media: A Review Alan Miralrio 1,* and
Araceli Espinoza Vázquez 2,*
 PLANT

14 • Drying
• Grinding
• screening

Plant Extracts as Green Corrosion Inhibitors for Different Metal Surfaces and Corrosive Media: A Review Alan Miralrio 1,* and Araceli Espinoza Vázquez 2,*
 EXTRACTION METHODS

Percolation

Decoction

Maceration 15

sonication
Soxhlet

Plant Extracts as Green Corrosion Inhibitors for Different Metal Surfaces and Corrosive Media: A Review Alan Miralrio 1,* and Araceli Espinoza Vázquez 2,*
 PURIFICATION METHODS

Purification of organic compounds

Recrystallisation

Sublimation

Purification Distillation

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Solvent extraction

Chromatography

https://www.topperlearning.com/jee/chemistry/purification-and-characterisation-of-organic-compounds
 CHROMATOGRAPHIC CHARACTERIZATION METHODS

• CPG-MS

• HPLC-MS

17
 SPECTROSCOPIC CHARACTERIZATION METHODS
• UV-Visible • NMR
• FT IR

18
 Plant

INHIBITORS PROCESS Methods

Extraction

Methods

Purification

Methods
19

Characterization Inhibitors Electrochemical tests

What? Application How?

 CORROSION TESTS :

• General Corrosion
• Stress Corrosion
• Bimetallic Corrosion
• Atomic Oxygen Corrosion
• Red Plague Corrosion
 GENERAL CORROSION TESTS :

Salt-spray-(foreground) and Humidity

Chamber- both have temperature and
humidity regulators
 BIMETALLIC CORROSION TESTS :

• The bimetallic corrosion

between two materials can
tested in specific liquids and
under any humidity levels.
• The current and voltage
difference as well as the work
electrode vs Calomel as
recorded
 ATOMIC OXYGEN CORROSION TESTS :

Materials for use in space applications in low

earth orbit and exposed to the hostile
combination of atomic oxygen and thermal
cycling have to be screened for their
susceptibility to withstand this environment
over very long periods
 ELECTROCHEMICAL CORROSION TESTS :

• Electrochemical Impedance Spectroscopy

• Polarization Resistance
• Linear Polarization Method (LPR)
• Equivalent Circuit Of An Electrochemical Cell.

• MSN Department Laboratory, 2021

 RESULTS INTERPRETATION :

• the inhibition efficiency • Equivalent Circuit

• D. K. Yadav, D. S. Chauhan, I. Ahamad, and M. A. Quraishi, “Electrochemical behavior of steel/acid interface: Adsorption and
inhibition effect of oligomeric aniline,” RSC Adv., vol. 3, no. 2, pp. 632–646, 2013,
 MECHANISM OF THE GREEN CORROSION INHIBITION:

different states in which inhibitor molecules may exist near interfaces and in the bulk
aqueous phase

• Salama Ibrahim. Corrosion Inhibitors in the Oilfield [Internet]. Version 1. isalama. 2011 May 17 • S. Sharma, X. Ko, Y. Kurapati, H. Singh, and S. Nešić, “Adsorption behavior of organic corrosion inhibitors on
metal surfaces—some new insights from molecular simulations,” Corrosion, vol. 75, no. 1, pp. 90–105, 2019
 CONCLUSION

Green inhibitors are not only low-cost efficient, but also an eco-friendly way to
protect metals against corrosion. Plants are a good source of active principles. Their
efficiency mainly depends on the active material and the mechanism by which they
inhibit or hinder the oxidation of metals. Furthermore, electrochemical tests are
conducted to understand and evaluate their efficiency. Nevertheless, the use of green
inhibitors is not unconditioned, their limitations are defined by some parameters such as
temperature, concentration and the nature of metals on which they were tested.