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  • Boiler Water Chemistry - 2

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    TSP (sodium triphosphate) is used for boiler water treatment to boost pH levels through a reaction that produces sodium hydroxide. It also removes salts from the system by precipitating them out as sludge during the blow down process. TSP dosing forms calcium and magnesium phosphates from reactions with calcium sulfate and magnesium sulfate, causing these compounds to precipitate out of the water and be removed during blow down. However, high TSP dosing can cause issues like high pH, high conductivity, caustic attack and foaming. Proper TSP dosing is important for effective boiler water treatment.

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    Boiler water Chemistry - 2

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    TSP (sodium triphosphate) is used for boiler water treatment to boost pH levels through a reaction that produces sodium hydroxide. It also removes salts from the system by precipitating them out as sludge during the blow down process. TSP dosing forms calcium and magnesium phosphates from reactions with calcium sulfate and magnesium sulfate, causing these compounds to precipitate out of the water and be removed during blow down. However, high TSP dosing can cause issues like high pH, high conductivity, caustic attack and foaming. Proper TSP dosing is important for effective boiler water treatment.

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    7 views7 pages

    Boiler Water Chemistry - 2

    Uploaded by

    parag14
    TSP (sodium triphosphate) is used for boiler water treatment to boost pH levels through a reaction that produces sodium hydroxide. It also removes salts from the system by precipitating them out as sludge during the blow down process. TSP dosing forms calcium and magnesium phosphates from reactions with calcium sulfate and magnesium sulfate, causing these compounds to precipitate out of the water and be removed during blow down. However, high TSP dosing can cause issues like high pH, high conductivity, caustic attack and foaming. Proper TSP dosing is important for effective boiler water treatment.

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    © All Rights Reserved
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    of 7

    Boiler Water treatment

    TSP dosing

    Parag Agrawal
    23.02.2022
    CPP Aditya Aluminum
    Role of TSP

    pH booster( Reaction gives NaOH)

    TSP (Na3PO4)

    Removes salts as sludge from blow down

    1. Blow down decreases Phosphate and lowers pH

    Hindalco Industries Limited, Aditya


    TSP DOSING AND REACTION IN DRUM

    TEMP 270-340DEG C

    1. Na3PO4 + H2O === NaOH + Na2HPO4

    TSP pH booster
    Sodium hydroxide

    1. Na3PO4+ CaSO4 ==== Na2SO4 +Ca3(PO4)2

    2. Na3PO4+ MgSO4 ==== Na2SO4 + Mg3(PO4)2

    When calcium phosphates is formed it precipitates on the water surface and


    can be easily removed by blow down
    Hindalco Industries Limited, Aditya
    Effect of high dosing of TSP

    • High pH and high conductivity


    • Results Caustic attack , carryover, foaming
    causing starvation.

    Hindalco Industries Limited, Aditya


    Phosphate dosing
    Phosphate dosing
    THANKS

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