Review of Literature

1.
Price, D. J., Willis, K., Richardson, T.,
Ungar, G. & Bruce, J. Mater. Chem[1]

Exhibited nematic and smectic A phase

2.

Kato, T. et al. . Liq. Cryst[2]

Complex exhibit smectic phase where as
H bond donor shows nematic phase

3.

Willis, K., Price, D. J., Adams, H., Ungar, G.

& Bruce, J. Mater. Chem [3]
H bond acceptor exhibit smectic B &
smectic E phase, complexes shows
smectic A & nematic phase
Review of Literature
contd......

4.
Paleos, C. M. & Tsiourvas,
Angew. Chemie Int. [4]
Complex exhibited smectic phase

5.

S. Sreehari Sastry, Research

journal of physical sciences[5]

Crystal G phase
Design
Coumarin Benzothiazole

Fluorescent materials Used in DSSC, LC, NLO etc

Used in OLED, laser dyes etc

LC compound

Expected outcome
Synthesis of Calamite LC containing single side chain

R= 10, 12, 14, 16

F10, F12, F14, F16

(i):abs. ethanol, glacial acetic acid, reflux 4h

Synthesis of Hydrogen bonded donor

D2

D1
Synthesis of Hydrogen bonded complex
Series 1

R = 10, 12, 14, 16

Series 2

R = 10, 12, 14, 16

Result and Discussion
UV-Visible studies

D2+F10
D1+F16
1
HNMR spectrum of 4-(2-amino-3-cyano-5-oxo-4, 5-dihydropyrano [3, 2-c] chromen-4-yl) benzoic acid (D1)

Chemical shift Multiplicity Coupling No. of protons

constant(Hz)
4.564 s - 1

7.418 d 8 2

7.524 d 7.6 1

7.485 m - 2

7.938 m - 3

7.749 dt 8.4 1
 IR spectrum of Hydrogen bond donor (D1)
65

60

55

50

45
% Transmittance
40

35
2243-3110
30

25

20

15

1608 ---
10 1686 -- --- 1294

4000 3500 3000 2500 2000 1500 1000 500

-1
Wavenumber (cm )

Table : IR Stretching frequencies of D1

Stretching frequency (cm-1) Assignment

2243-3110 O-H stretching frequency
1686 C=O stretching frequency
1294 C-O stretching frequency