SYNTHESIS OF MOF

PRESENTED BY –SAMAHITA CHAKRABORTY

ROLL NO. -CM19232
PUNJAB UNIVERSITY
Dr. S.S.Bhatnagar U.I.C.E.T.
SUBMITTED TO – Dr. Ritu Gupta
 INTRODUCTION
• Consist of a regular organic or inorganic structure ,
supporting a periodic porous system
INTRODUCTION
 REVIEW OF METAL-ORGANIC
FRAMEWORK
• Metal-Organic framework ,abbreviated to MOF , is a coordination
polymer ( or alternatively coordination network ) with an open
framework containing potential voids

• MOF are self- assembled metal clusters with organic ligands ,are well
known for their structure , permanent porosity ,and tunable
properties and have shown great prospect for various applications
 STRUCTURAL FEATURES
• MOF are structures made up of inorganic nodes , which can either be
single ions or cluster of ions , and organic linkers
• They contain potential voids which can be used for various application

• Very low density

• Crystalline
• Large voids
• Significant van der waals interaction
• Complex unit cell
PREPARATION OF METAL-ORGANIC
FRAMEWORKS
 SYNTHESIS OF MOF
• The 2D structures with grid shape are generally synthesized with a
molar ratio between ligand and the metal center of 1:2

• Example : The MOF is constituted by cobalt metal centers and ligands

N –(3-PYRIDYL) Nicotinamide

• The metal ions are coordinated with four molecules of ligand , which
result in a two dimensional flat - shaped structure
SYNTHESIS OF MOF
 APPLICATIONS OF MOF
• Gas separation
• Catalysis
• Hydrogen storage
• Gas adsorption
• Gas purifications
• Ion – exchange
• Sensor materials
• Bio-Medical field
 ADVANTAGES OF MOF
• Gas separation
• Catalysis
• Hydrogen storage
• Gas adsorption
• Gas purifications
• Ion – exchange
• Sensor materials
• Bio-Medical field
 DISADVANTAGES OF MOF
• High fabrication cost

• Poor selectivity

• Low capacity

• Difficulties in recycling / regeneration

 SCOPE FOR FUTURE WORK
• Super capacitor applications

• Hydrogen storage

• Catalytic activity

• Pollution control

• Electrochemical energy storage and conversion

 CONCLUSION
• MOFs are uniform structured porous materials suitable for solid-phase extraction.
• The application of MOFs materials for SPE needs to consider a wide range of sample
properties to achieve the desired extraction performance.
• The water stability of MOFs-based sorbent is the first concern. Some MOFs can be
used directly with aqueous samples, such as the MIL series, ZIF series and UiO series
but not the IRMOF series sorbents.
• Postsynthesis modification with hydrophobic groups, composite materials with water-
repellent components and carbonization are alternative approaches to improve water
stability of moisture-sensitive MOFs.
• Beyond water stability, the selectivity of MOFs-based sorbents for the extraction of
target analytes is another concern.
• The adsorption of analytes by many MOFs affords only low selectivity.
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