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Rutherford

Ernest Rutherford (1871-1937) PAPER

• Learned physics in
J.J. Thomson’ lab.
• Noticed that ‘alpha’
particles were
sometime deflected
by something in the
air.
• Gold-foil experiment

Animation by Raymond Chang – All rights reserved.


Rutherford ‘Scattering’

• In 1909 Rutherford undertook a series of experiments


• He fired  (alpha) particles at a very thin sample of gold foil
• According to the Thomson model the  particles would only
be slightly deflected
• Rutherford discovered that they were deflected through large
angles and could even be reflected straight back to the source

Lead collimator
Gold foil
 particle
source

Rutherford’s Apparatus
Rutherford received the 1908 Nobel Prize in Chemistry for his pioneering work in nuclear chemistry.

beam of alpha particles

radioactive
substance

circular ZnS - coated


fluorescent screen
gold foil

Dorin, Demmin, Gabel, Chemistry The Study of Matter , 3rd Edition, 1990, page 120
Rutherford’s Apparatus

beam of alpha particles

radioactive
substance

fluorescent screen
circular - ZnS coated
gold foil

Dorin, Demmin, Gabel, Chemistry The Study of Matter , 3rd Edition, 1990, page 120
What he expected…
What he got…
richocheting
alpha particles
The Predicted Result:

expected
path

expected
marks on screen

Observed Result:

mark on
screen

likely alpha
particle path
Interpreting the
Observed Deflections

. . .
.
beam of . .
. . undeflected
alpha particles
particles . .
. .
. .
. deflected particle
. .

gold foil
Dorin, Demmin, Gabel, Chemistry The Study of Matter , 3rd Edition, 1990, page 120
Explanation of Alpha-Scattering Results

Alpha particles Nucleus


+
+
-
-
+
+
-
+
-

+
-
+
-
-
+
-

Plum-pudding atom Nuclear atom


Thomson’s model Rutherford’s model
Results of foil experiment if plum-
pudding had been correct.
Electrons scattered
throughout positive
charges
+ -
+

- +

+ -

+
-

- +

+ -
-

Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 57


Interpreting the Observed
Deflections
deflected particle

. . .
.
beam of . .
. . undeflected
alpha particles
particles . .
. .
. .
.
. .

gold foil
Dorin, Demmin, Gabel, Chemistry The Study of Matter , 3rd Edition, 1990, page 120
Rutherford’s
Gold-Leaf
Experiment

Conclusions:
Atom is mostly empty space

Nucleus has (+) charge

Electrons float around nucleus

Dorin, Demmin, Gabel, Chemistry The Study of Matter , 3rd Edition, 1990, page 120
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