Professional Documents
Culture Documents
proceeding:
This document is confidential and intended solely for the educational purpose of
RMK Group of Educational Institutions. If you have received this document through
email in error, please notify the system manager. This document contains proprietary
information and is intended only to the respective group / learning community as
intended. If you are not the addressee you should not disseminate, distribute or copy
through e-mail. Please notify the sender immediately by e-mail if you have received
this document by mistake and delete this document from your system. If you are not
the intended recipient you are notified that disclosing, copying, distributing or taking
any action in reliance on the contents of this information is strictly prohibited.
PHYSICS FOR COMPUTER
SCIENCE AND INFORMATION
TECHNOLOGY
21PH101
UNIT IV
SEMICONDUCTOR PHYSICS
Batch/Year : 2021-2022 / I
Date : 28-11-2021
TABLE OF CONTENTS
S. No. CONTENTS
1 Course Objectives
2 Prerequisites
3 Syllabus
4 Course Outcomes
5 CO - PO/PSO Mapping
6 Lecture Plan
4.1 Introduction
Solved Problems
Comprehensive Quiz
9 Assignment
11 Part B – Questions
On completion of this course, the students will gain knowledge and will be able to
CO1: Know the principle, construction and working of lasers and their
applications in fibre optic communication.
C03: Analyze the classical and quantum electron theories and energy band
structures.
PO PO PO PO PO PO PO PO PO PO PO PO
COs
1 2 3 4 5 6 7 8 9 10 11 12
CO1 3 2 3 2 - - - - - - - -
CO2 3 2 3 2 - - - - - - - -
CO3 3 2 3 2 - - - - - - - -
CO4 3 2 3 2 - - - - - - - -
CO5 3 2 3 2 - - - - - - - -
CO6 3 2 3 2 - - - - - - - -
LECTURE PLAN
No.
Actual Taxono
S.N Topics to be of Pertaini Propos Mode of
Lecture my
o. Covered Perio ng CO ed Date Delivery
Date Level
ds
Introduction to
Semiconductors,
Energy band
PPT, Chalk
1 diagram and Direct 1 CO4 K1
& Talk
and indirect
bandgap
semiconductors
Introduction to
intrinsic
semiconductor PPT, Chalk
2 1 CO4 K2
Concentration of & Talk
electrons in the
conduction band
Concentration of
holes in the
valance band PPT, Chalk
3 1 CO4 K1
Effect of & Talk
temperature on the
Fermi energy level
Determination of
energy bandgap of PPT, Chalk
4 1 CO4 K2
intrinsic & Talk
semiconductor
Effect of
PPT, Chalk
5 temperature on 1 CO4 K3
& Talk
Fermi function
Extrinsic
semiconductor – n- PPT, Chalk
6 1 CO4 K1, K2
and p- type & Talk
semiconductors
Variation of Fermi
level with
PPT, Chalk
7 temperature and 1 CO4 K1
& Talk
impurity
concentration
Hall effect and its PPT, Chalk
8 1 CO4 K1, K2
applications & Talk
PPT, Chalk
9 Problems 1 CO4 K3
& Talk
ACTIVITY BASED LEARNING
1. One experimental setup for the determination of bandgap, obtained from the
Physics lab, will be taken to the class. A demonstration will be given in detail to
determine the bandgap of a semiconductor. It would be interesting to visualize
the one which has been derived in the theory class.
2. Do a web investigation of semiconductors and photovoltaic cells using the
following websites:
http://www1.eere.energy.gov/solar/index.html
http://electronics.howstuffworks.com/diode.htm
http://www.electronics-tutorials.ws/diode/diode_3.html
Use the information from the websites to answer the following questions:
a. What is the primary element used to make semiconductors?
b. Describe what it means to use doping in reference to silicon? Why is this
necessary?
c. Describe N-type doping.
d. Describe P-type doping.
e. Describe a diode and how it is used?
f. What is happening in a photovoltaic cell?
g. Describe some of the common uses of photovoltaic cells.
h. Why are photovoltaic cells an attractive way to produce electricity?
Conductivity
102 – 108 Ω-1 m–1 105 – 10–6 Ω-1 m–1 10–11 – 10–19 Ω-1 m–1
(σ)
Table 4.1 explains the classification of solids on the basis of conductivity and
resistivity. Relative values of the resistivity are not the only criteria for distinguishing
metals, insulators and semiconductors from each other.
Inside the crystal, no two electrons see exactly the same pattern of surrounding
charges. Hence each electron will have a different energy level. These different
energy levels with continuous energy variation form what are called energy bands.
The energy levels of the valence electrons combine together to form the valence
band. The energy band above the valence band is called the conduction band. The
gap between the valence band and conduction band is said to be energy gap. With
no external energy, all the valence electrons will reside in the valence band.
Normally the conduction band is empty and valence band is filled. When the valence
band overlaps with conduction band, electrons can move freely into it and is
responsible for current conduction. This is the case with metallic conductors (shown
in Fig 4.3).
Fig 4.3 Position of conduction band and valence band in a conductor
If there is some gap between the conduction band and the valence band, electrons
in the valence band all remain bound and no free electrons are available in the
conduction band. This makes the material an insulator (E g > 3 eV) (shown in Fig
4.4).
But some of the electrons from the valence band may gain external energy to cross
the gap between the conduction band and the valence band. Then these electrons
will move into the conduction band. At the same time they will create vacant energy
levels in the valence band where other valence electrons can move. Such materials
with less energy gap are called semiconductors (E g < 3 eV) (shown in Fig 4.5).
Table 4.2 given below explains the difference between conductor, semiconductor
and insulator.
A conductor is a A semiconductor is a
An insulator is a
material that allows material whose
material that does
Definition the flow of charge conductivity lies
not allow the flow
when applied with a between conductor
of current.
voltage. and insulator
The resistance of a
semiconductor
The resistance of a Insulator has very
decrease with
Temperature conductor increases high resistance but
Dependence increases in
with an increase in it still decreases
temperature. Thus it
temperature. with temperature.
acts as an insulator at
absolute zero.
Characteristics Conductor Semiconductor Insulator
They have
The conductors have
intermediate They have very low
very high conductivity
conductivity (10-7 to conductivity (10-13
(102 to 108 Ω-1 m-1),
Conductivity 10-13 Ω-1 m-1), thus they Ω-1 m-1), thus they
thus they can conduct
can acts as insulator do not allow current
electrical current
and conductor at flow.
easily.
different conditions.
The coefficient of
It has positive
resistivity of an
coefficient of resistivity It has negative
Coefficient of insulator is
i.e. its resistance coefficient of
Resistivity also negative but it
increase with resistivity.
has very huge
temperature
resistance.
Characteristics Conductor Semiconductor Insulator
Some special
conductors turn into The insulator’s
superconductors The semiconductors resistance
At Absolute Zero when cooled down turn into insulator at increase when
to absolute zero absolute zero. cooled down to
while others have absolute zero.
finite resistance.
Silicon, Germanium,
Selenium, Antimony, Rubber, Glass,
Gold, Copper, Silver,
Examples Gallium Arsenide Wood, Air, Mica,
Aluminum etc
(known as semi Plastic, Paper etc.
insulator), Boron etc.
The elemental semiconductor is made of single element from the fourth column of
the periodic table. They are also called as indirect band gap semiconductors.
Ex: Silicon and Germanium
4.3.1.2 COMPOUND SEMICONDUCTORS
However, an electron must also undergo a significant change in its momentum for a
photon of energy Eg to produce an electron-hole pair in an indirect band gap
semiconductor. This is possible, but it requires such an electron to interact not only
with the photon to gain energy, but also with a lattice vibration called a phonon in
order to either gain or lose momentum.
The indirect process proceeds at a much slower rate, as it requires three entities to
intersect in order to proceed: an electron, a photon and a phonon.
The band gap represents the minimum energy difference between the top of the
valence band and the bottom of the conduction band. In a direct band gap
semiconductor, the top of the valence band and the bottom of the conduction
band occur at the same value of momentum, as in the schematic below in Fig 4.7.
A photon of energy Eg, where Eg is the band gap energy, can produce an electron-
hole pair in a direct band gap semiconductor quite easily, because the electron does
not need to be given very much momentum.
The outermost shell of atom is capable to hold up to eight electrons. The atom which
has eight electrons in the outermost orbit is said to be completely filled and most
stable. But the outermost orbit of silicon and germanium has only four electrons.
Both categories of atom needs four more electrons to become most stable. Silicon
atom forms four covalent bonds with the four neighboring atoms.
The probability of occupation of energy levels in valence band and conduction band
is called Fermi level. At absolute zero temperature intrinsic semiconductor acts as
perfect insulator. However as the temperature increases free electrons and holes get
generated.
Fig.4.11 Energy band diagram showing Fermi level of intrinsic semiconductor
The number of electrons per unit volume in the conduction band is given by
𝑛𝑒 = ∫ 𝑍 ( 𝐸 ) 𝐹 ( 𝐸 ) 𝑑𝐸
…(4.1)
𝐸𝐶
But, as you can see in Fig. 4.13, the conduction band energies varies from to . The
electron’s mass ‘m’ is replaced by its effective mass and is replaced by ().
( )
∗ 3/2 …(4.3)
𝜋 8𝑚𝑒 1/ 2
𝑍 ( 𝐸 ) 𝑑𝐸 = ( 𝐸 − 𝐸𝐶 ) 𝑑𝐸
2
We know that the Fermi function h
2
1 …(4.4)
𝐹 ( 𝐸 )=
1+ exp
(
𝐸 − 𝐸𝐹
𝑘𝐵 𝑇
is the energy of the Fermi level which is exactly at the centre of the forbidden
)
energy gap in the case of the intrinsic semiconductor and is the Boltzmann
constant.
But,
𝐸 − 𝐸 𝐹
Therefore, 𝑘 𝐵 𝑇
≫ 1
1 + exp ( 𝐸 − 𝐸𝐹
𝑘𝐵 𝑇 )
On substituting the above equation in (4.4) we get
≈ exp ( 𝐸 − 𝐸𝐹
𝑘𝐵 𝑇 )
1
𝐹 ( 𝐸 )=
( ) ( )
∞ ∗ 3 /2
𝜋 8 𝑚𝑒 𝐸𝐹 − 𝐸
𝑛𝑒 =∫
1 /2
( 𝐸 − 𝐸𝐶 ) 𝑑𝐸 exp …(4.6)
𝐸𝐶 2 h
2
𝑘𝐵 𝑇
To solve this integral, we take a substitution like,
( ) ( )
∞ ∗ 3 /2
𝜋 8 𝑚𝑒 𝐸 𝐹 −( 𝐸 𝐶 + 𝑥 𝑘𝐵 𝑇 )
𝑛𝑒=∫ ( 𝑥 𝑘 𝐵 𝑇 ) 1/ 2 ( 𝑘 𝐵 𝑇 𝑑𝑥 ) exp …(4.7)
0 2 h2 𝑘𝐵 𝑇
On simplification we get
( ) ( )
∗ 3/ 2 ∞
𝜋 8 𝑚 𝑒 𝑘𝐵 𝑇 𝐸𝐹 − 𝐸𝐶
𝑛𝑒 =
2 h2
exp
𝑘𝐵 𝑇
∫ 𝑥 1/ 2 exp (− 𝑥…(4.8)
) 𝑑𝑥
0
The integral in the above eqn. (4.8) will have the result as
∞
√𝜋
∫ 𝑥 1/ 2 exp ( − 𝑥 ) 𝑑𝑥 =
2
0
( ) ( )
∗ 3/ 2
𝑛𝑒 =
𝜋 8 𝑚 𝑒 𝑘𝐵 𝑇
exp
𝐸𝐹 − 𝐸𝐶 √𝜋
2 h
2
𝑘𝐵 𝑇 2
( ) ( )
∗ 3 /2
2 𝜋 𝑚 𝑒 𝑘𝐵 𝑇 𝐸 𝐹 − 𝐸𝐶
𝑛𝑒 = 2 exp
h
2
𝑘 𝐵 𝑇 …(4.9)
The above eqn. (4.9) gives the number of electrons in the conduction band per unit
volume of a given intrinsic semiconductor.
4.5.2 EXPRESSION FOR DENSITY OF HOLES IN VALENCE BAND
The desnsity of holes in the valence band can be calculated similar to that for
electrons in the conduction band.
The density of holes in the valence band between the energy interval and .
𝐸𝑉
𝑛h = ∫ 𝑍 ( 𝐸 ) [ 1 − 𝐹 ( 𝐸 ) ] 𝑑𝐸
…(4.10)
−∞
[ ]
1
1 − 𝐹 ( 𝐸 ) =1 −
1+ exp
( 𝐸 − 𝐸𝐹
𝑘𝐵 𝑇 )
¿
[ 1 + exp
( 𝐸 − 𝐸
𝑘𝐵 𝑇
𝐹
)] − 1
…(4.11)
1 + exp
( 𝐸 − 𝐸
𝑘𝐵 𝑇
𝐹
)
Since at ordinary temperatures, for a semiconductor we have
𝐸 − 𝐸 𝐹
≪ 1
𝑘𝐵 𝑇
1 + exp ( 𝐸 − 𝐸𝐹
𝑘𝐵 𝑇 ) ≈ 1
1 − 𝐹 ( 𝐸 ) =exp ( 𝐸 − 𝐸𝐹
𝑘𝐵 𝑇
…(4.12) )
We know that the density of holes in the valance band is
( )
3 /2
𝜋 8𝑚 1 /2
𝑍 ( 𝐸 ) 𝑑𝐸 = 2
𝐸 𝑑𝐸
…(4.13)
2 h
Electron mass is replaced by its effective mass ; is replaced by .
( )
∗ 3/2
𝜋 8𝑚h 1/2
𝑍 ( 𝐸 ) 𝑑𝐸 =
2 2 ( 𝐸𝑉 − 𝐸) 𝑑𝐸
…(4.14)
h
( )
𝐸𝑉
( )
3/ 2
𝜋 8 𝑚∗ 𝐸 − 𝐸𝐹
𝑛h =∫
h 1 /2
( 𝐸𝑉 − 𝐸 ) 𝑑𝐸 exp …(4.15)
−∞ 2 h
2
𝑘𝐵 𝑇
( ) ( )
0 ∗ 3/2
𝜋 8 𝑚h 𝐸 𝑉 − 𝑥 𝑘𝐵 𝑇 − 𝐸 𝐹
𝑛h =∫ ( 𝑥 𝑘𝐵 𝑇 ) 1/ 2 ( − 𝑘𝐵 𝑇 𝑑𝑥 ) exp
∞ 2 h
2
𝑘𝐵 𝑇 …(4.16)
On simplification,
( ) ( )
∗ 3 /2 ∞
𝜋 8𝑚 h 𝑘𝐵 𝑇 𝐸𝑉 − 𝐸𝐹
𝑛h =
2 h2
exp
𝑘𝐵 𝑇
∫ 𝑥1 /2 exp ( − 𝑥…(4.17)
) 𝑑𝑥
0
But,
∞
√𝜋
∫ 𝑥 1/ 2 exp ( − 𝑥 ) 𝑑𝑥 =
2
0
( ) ( )
∗ 3 /2
𝑛h =
𝜋 8 𝑚 h 𝑘𝐵 𝑇
exp
𝐸𝑉 − 𝐸𝐹 √𝜋
2 h
2
𝑘𝐵 𝑇 2
( ) ( )
∗ 3 /2
2 𝜋 𝑚h 𝑘 𝐵 𝑇 𝐸𝑉 − 𝐸𝐹
𝑛h =2 exp
h
2
𝑘 𝐵 𝑇 …(4.18)
The above eqn. (4.18) gives the number of holes in the valance band per unit
volume of a given intrinsic semiconductor.
4.5.3 INTRINSIC CARRIER CONCENTRATION ()
In intrinsic semiconductors,
where is called intrinsic carrier concentration.
Therefore,
𝑛2
𝑖 = 𝑛𝑒 𝑛 …(4.19)
h
[( ) ( )][ ( ) ( )]
∗ 3 /2 ∗ 3/2
2 2 𝜋 𝑚𝑒 𝑘𝐵 𝑇 𝐸 𝐹 − 𝐸𝐶 2 𝜋 𝑚h 𝑘 𝐵 𝑇 𝐸𝑉 − 𝐸𝐹
𝑛= 2
𝑖 exp 2 exp
h
2
𝑘𝐵 𝑇 h
2
𝑘 𝐵𝑇
( ) ( )
3
2 𝜋 𝑘𝐵 𝑇 3 /2 𝐸𝑉 − 𝐸𝐶
2
𝑛 =4
𝑖 2 ( 𝑚 ∗𝑒 𝑚∗h ) exp
𝑘𝐵 𝑇
h
( ) ( )
3 /2
2 𝜋 𝑘𝐵 𝑇 3/4 𝐸 𝑉 − 𝐸𝐶
𝑛𝑖 =2 2 ( 𝑚∗𝑒 𝑚∗h ) exp
2 𝑘𝐵 𝑇 …(4.20)
h
But, , which is the forbidden energy gap. On replacing with in eqn. (4.20) we get
…(4.21)
( ) ( )
3 /2
2 𝜋 𝑘𝐵 𝑇 ∗ 3/4 − 𝐸𝑔
𝑛𝑖 =2 2 (𝑚 ∗
𝑒 𝑚 h) exp
2 𝑘𝐵 𝑇
h
4.5.4 LAW OF MASS ACTION
The law of mass action states that the product of number of electrons in the
conduction band and the number of holes in the valence band is constant at a fixed
temperature and is independent of amount of donor and acceptor impurity added.
Mathematically it is represented as
constant
where is the intrinsic carrier concentration
is density of electrons in conduction band
is density of holes in valence band.
4.5.5 FERMI LEVEL IN INTRINSIC SEMICONDUTOR
( ) ( ) ( ) ( )
3/2 3 /2
2 𝜋 𝑚∗𝑒 𝑘 𝐵 𝑇 𝐸 𝐹 − 𝐸𝐶 2 𝜋 𝑚∗h 𝑘𝐵 𝑇 𝐸𝑉 − 𝐸𝐹
2 exp =2 exp
h
2
𝑘𝐵 𝑇 h
2
𝑘𝐵 𝑇
( 𝑚∗
𝑒 )
3 /2
exp ( 𝐸 𝐹 − 𝐸𝐶
𝑘𝐵 𝑇 ) (
∗ 3 /2
= 𝑚h ) exp ( 𝐸𝑉 − 𝐸 𝐹
𝑘𝐵 𝑇 )
( ) ( )
3/ 2
𝐸 𝐹 − 𝐸𝐶 − 𝐸𝑉 + 𝐸𝐹 𝑚∗
h
exp =
𝑘𝐵 𝑇 𝑚∗
𝑒
( )( ) ( )
3/ 2
2 𝐸𝐹 𝑚∗h 𝐸𝑉 + 𝐸 𝐶
exp = exp
𝑘𝐵 𝑇 𝑚∗𝑒 𝑘𝐵 𝑇
( )
∗
2 𝐸𝐹 3 𝑚h 𝐸 𝑉 + 𝐸𝐶
= log +
𝑘𝐵 𝑇 2 𝑚∗
𝑒
𝑘𝐵 𝑇
𝐸𝐹=
3 𝑘𝐵 𝑇
4
log
( 𝑚∗
𝑚
h
∗
𝑒
) +
𝐸 𝑉 + 𝐸𝐶
2 …(4.22)
𝜎 =𝑛𝑒 𝑒 𝜇 𝑒 + 𝑛h 𝑒 𝜇 h
…(4.25)
𝜎 =𝑒 ( 𝑛 unit 𝜇
where is the number of electrons in𝑒 volume𝑒
+ 𝑛hband,
in the conduction
𝜇 h)
is the number of holes per unit volume in the valence band
is the mobility of electrons in the conduction band
is the mobility of holes in the valance band and
is the charge of an electron or hole (1.6 x 10 -19 C)
We know that in the case of intrinsic semiconductors, . So, eqn. (4.25) for the case
of intrinsic semiconductor becomes
…(4.26)
𝜎 =𝑛 𝑒 (𝜇
𝑖the expression for 𝑖from eqn. (4.21) in the
Substituting 𝑒 +𝜇 hwe get
above eqn. (4.26),
)
the expression for the electrical conductivity of an intrinsic semiconductor as
…(4.27)
( ) ( )
3/ 2
2 𝜋 𝑘𝐵 𝑇 ∗ 3/4 − 𝐸𝑔
𝜎 𝑖 =2 𝑒 2 (𝑚
∗
𝑒 𝑚 h ) exp
2 𝑘𝐵 𝑇
(𝜇𝑒 +𝜇 h)
h
…(4.28)
𝜎 = 𝐶 exp
𝑖
where is a constant. ( − 𝐸𝑔
2𝑘𝐵 𝑇 )
Fig 4.15 log i verses 1/T
𝐸 𝑔 …(4.29)
log (𝜎 ¿ ¿ 𝑖 )= log ( 𝐶 ) − ¿
2 𝑘𝐵 𝑇
A typical graph drawn between 1/T and log is shown in Fig. 4.15. From the graph,
we understand that conductivity increases with increase in temperature.
𝜌𝑖 =
1
𝐶
exp
( 𝐸𝑔
2 𝑘𝐵 𝑇 )
𝑅𝑖 𝐴
𝐿
=
1
𝐶
exp ( 𝐸𝑔
2 𝑘𝐵 𝑇 )
𝑅𝑖 =
𝐿
𝐴𝐶
exp ( 𝐸𝑔
2𝑘 𝐵 𝑇 )
𝑅𝑖 =𝐶 1 exp
where .
( 𝐸𝑔
2 𝑘𝐵 𝑇
…(4.30)
)
On taking logarithm on both sides we get
𝐸 𝑔 …(4.31)
log ( 𝑅 ¿ ¿ 𝑖 )= log ( 𝐶 1 ) + ¿
2 𝑘𝐵 𝑇
Fig 4.16 log Ri verses 1/T
Fig. 4.16 shows the plot of a curve between and . The slope of the curve gives the
value of .
𝑑𝑦 𝐸 𝑔
=
𝑑𝑥
Therefore,
2 𝑘𝐵
𝐸
𝐸𝑔𝑔=2
=2𝑘𝑘 × Slope
𝐵𝐵 ( 𝑑𝑦
𝑑𝑥 ) …(4.32)
A semiconductor specimen is immersed in an oil bath. The two ends of specimen are
connected in series with a battery, rheostat and an ammeter as shown in
Fig 4.17. A voltmeter is connected in parallel. Now, the initial temperature is noted
by using thermometer.
Two types of impurities are added to the semiconductor. They are pentavalent and
trivalent impurities. Pentavalent impurity atoms have 5 valence electrons. When the
pentavalent impurity is added to an intrinsic or pure semiconductor (silicon or
germanium), then it is said to be a n-type semiconductor The various examples of
pentavalent impurity atoms include phosphorus (P), arsenic (As), antimony (Sb), etc.
The atomic structure of pentavalent atom (phosphorus) is shown in the Fig. 4.18.
Fig 4.18 Atomic structure of pentavalent atom (Phosphorus)
As can be seen in the Fig.4.19, when a pentavalent atom takes the place of a Si
atom, four of its electrons bond with four neighbouring Si atoms. However, the fifth
electron remains loosely bound to the parent atom. Hence, the ionization energy
required to set this electron free is very small. Thereby, this electron can move in
the lattice even at room temperature.
To give you a better perspective, the ionization energy required for silicon at room
temperature is around 1.1 eV. On the other hand, by adding a pentavalent impurity,
this energy drops to around 0.05 eV.
( ) ( )
∗ 𝟑/ 𝟒
𝟏/ 𝟐 𝟐 𝝅 𝒎𝒆 𝒌𝑩 𝑻 𝑬 𝒅− 𝑬 𝑪
𝒏= ( 𝟐 𝑵 𝒅 ) 𝒆𝒙𝒑
𝒉𝟐 𝟐 𝒌𝑩 𝑻
where is the donor concentration,
is the donor energy level.
Trivalent impurity atoms have 3 valence electrons. When the trivalent impurity is
added to an intrinsic or pure semiconductor (silicon or germanium), then it is said to
be a p-type semiconductor. The various examples of trivalent impurities include
boron (B), gallium (Ga), indium (In), aluminium (Al).
Boron atom has 5 electrons (2 electrons in first orbit and 3 electrons in the
outermost orbit). The atomic structure of trivalent atom (boron) is shown in below
Fig. 4.20.
In the fourth covalent bond, only silicon atom contributes one valence electron,
while the boron atom has no valence electron to contribute. Thus, the fourth
covalent bond is incomplete with shortage of one electron. This missing electron is
called hole. This shows each boron atom accept one electron to fill the hole.
Therefore, all the trivalent impurities are called acceptors. A small addition of
impurity (boron) provides millions of holes.
In a nutshell, when a semiconductor is doped with a trivalent atom, holes are the
majority charge carriers. On the other hand, the free electrons are the minority
charge carriers. Therefore, such extrinsic semiconductors are called p-type
semiconductors.
( ) ( )
∗ 𝟑/ 𝟒
𝟏/ 𝟐 𝟐 𝝅 𝒎𝒉 𝒌 𝑩 𝑻 𝑬 𝑽 − 𝑬𝒂
𝒑 =( 𝟐 𝑵 𝒂 ) 𝒆𝒙𝒑
𝒉
𝟐
𝟐 𝒌𝑩 𝑻
where is the donor concentration,
is the donor energy level.
Fig 4.22 Variation of Fermi level with respect to temperature in n-type
semiconductor
In case of Intrinsic, Fermi level is located half way between the valence and
conduction bands and its position is independent of temperature. In case of N-type
semiconductor, Initially with increase in temperature, E F increases slightly. As
temperature increases, more number of donors are ionized. Further increase in
temperature results in generation of electron- hole pairs due to breaking of covalent
bonds and the Fermi level moves gradually towards the intrinsic Fermi level E Fi.
Under equilibrium condition, the force on the electrons due to magnetic field is
balanced by the electric field due to the Hall voltage, i.e.,
− 𝑒 𝐸 𝐻 =− 𝑒𝑣𝐵
…(4.33)
𝐸 𝐻 = 𝑣𝐵
In a uniform sample, the electric current density () is related to the velocity as
𝐽 = − 𝑛𝑒𝑣
where is the concentration of electrons.
𝐽 …(4.34)
𝑣 =−
𝑛𝑒
Substitute eqn. (4.34) in (4.33)
𝐽𝐵
𝐸 𝐻 = −
𝑛𝑒
This can be written as
…(4.35)
𝐸 𝐻 = 𝐵𝐽 𝑅𝐻
where is called the Hall coefficient.
The negative sign indicates that the developed field is in the negative y direction.
4.7.2 HALL COEFFICIENT FOR P-TYPE SEMICONDUCTOR
Under equilibrium condition, the force on the holes due to magnetic field is balanced
by the electric field due to the Hall voltage, i.e.,
The Hall field per unit current density per unit magnetic induction is defined as the
Hall coefficient.
The Hall coefficient is determined by measuring the Hall voltage that generates the
Hall field. Let ‘’ be the thickness of the sample and be the Hall voltage, then
𝑉 𝐻 = 𝐸 𝐻 𝑡
…(4.39)
where is the Hall field.
We already have derived the expression for in eqn. (4.35) and (4.38). Using eqn.
(4.35) or (4.38) in eqn. (4.39) we get
𝑉 𝐻 = 𝐵𝐽 𝑅𝐻 𝑡
…(4.40)
For a current flowing through a area of cross section , the current density, can be
written as
𝐼 𝐼
𝐽 = =
𝐴 𝑏𝑡
where is the breadth and is the thickness.
The experimental set up for the measurement of Hall voltage is shown in the Fig.
4.26. ‘’ is the thickness and ‘’ is the breadth of the sample. A suitable current is
allowed to pass through this sample along the X axis by connecting it to a battery.
The sample is placed between the pole pieces of an electromagnet such that the
applied magnetic field coincides with the z-axis.
Hall voltage () developed in the sample is measured by fixing two probes at the
centres of the bottom and top faces of the sample.
3. Determination of mobility
The mobility of charge carriers can be obtained if conductivity is known.
By measuring the conductivity and Hall coefficient, the mobility can be found out.
Solution:
Given:
( ) ( )
3 /2
2 𝜋 𝑘𝐵 𝑇 3/4 − 𝐸𝑔
𝑛𝑖 =2 2 ( 𝑚∗𝑒 𝑚∗h ) exp
2 𝑘𝐵 𝑇
h
( ) ( )
3 /2 3/2
2 𝜋 𝑘𝐵 𝑇 2 𝜋 × 1.38 ×10
− 23
× 300
2 2
=2 2
h ( 6.626 ×10 −34 )
3/ 2
¿ 2 ( 5.925 ×10 )
46 70
= 2× 1.442×10
¿ 2 . 884 ×10 70
3/4
( 𝑚∗𝑒 𝑚 ∗h ) =( 1.092 10 −31 2.548 10 −31 )
3/4
¿ ( 2.782 10 − 62 ) 3/ 4
¿ 6 . 813 10 − 47
exp ( − 𝐸𝑔
2 𝑘𝐵 𝑇 )
=exp − (
0.67 × 1.6 ×10 −19
−23
2 ×1.38 × 10 × 300 )
¿ exp ( −1 2 . 947 )
¿ 2 .284 × 10− 6
Solution:
Given
ni = 2.37 1019 m3
4. The Hall coefficient of certain silicon specimen was found to be -7.35 10-5
m3 C-1 from 100 to 400 K. Determine the nature of the semiconductor. If the
conductivity was found to be 200 -1 m1. Calculate the density and mobility of
the charge carrier.
Solution
¿ 8.455 × 10 22 m − 3
b) Mobility
𝜎
𝜇=
𝑛𝑒
200
¿ 22 − 19
8.455 × 10 × 1.609 ×10
5. For an intrinsic semiconductor with a band gap of 0.7 eV. Determine the
position of EF at T = 300 K if = 6.
Solution
Bandgap Eg = 0.7 eV
Temperature, T = 300 K
Fermi energy for an intrinsic semiconductor
𝐸𝐹=
3 𝑘𝐵 𝑇
4
log
( 𝑚∗
h
𝑚𝑒
∗ )
+
𝐸𝑔
2
(
6 𝑚∗
)
− 23
3 × 1.38 × 10 × 300 𝑒 0.7
¿ × log +
4 × 1.6 × 10
19
𝑚𝑒
∗
2
Solution
Given
Hall voltage, VH = 37 µV = 37 10-6 V
Breath of the sample, t = 1 mm = 1 10-3 m
Current, IH = 20 mA = 20 10-3 A
Solution
Given:
Length of Ge rod l = 1 mm = 1 10-3 m
Breadth b = 1 mm = 1 10-3 m
Thickness t = 1 mm = 1 10-3 m
Intrinsic carrier concentration ni = 2.5 1019 m-3
Since the Hall coefficient, RH is positive, the doped silicon must be a p-type
semiconductor.
Solution
Given data
= ni e (µe + µh)
10. The electron mobility and hole mobility is Si are 0.135 m2 V-1 s-1 and 0.04 m2
V-1 s-1 respectively at room temperature. If the carrier concentration is 1.5
1016 m-3. Calculated the resistivity of Si at room temperature.
Solution
Given data
= ni e (µe + µh)
Electrical resistivity, is just the inverse of the electrical conductivity and can be calculated
as follows
= 1/
= 1/ 0.4392 10-3
= 2.2768 m
OTHER LEARNING MATERIALS
YOUTUBE LINK
1. Density of electron-Intrinsic
4. Hall effect
5. AT&T Archives: Dr. Walter Brattain (Nobel Prize winner Walter Brattai
n, co-inventor of the transistor) on Semiconductor Physics
MIT Courseware
Semiconductors
NanoHUB
https://nanohub.org/resources/5221
Lecture Notes
Semiconductor Physics
E-books
Fundamental Principles of Semiconductors – Edward F. Gurnee
Semiconductor device fundamentals – Robert F. Pierret
COMPREHENSIVE QUIZ
After completing the course, students are instructed to take the following quiz to
quantify their understanding of the concepts on the semiconducting materials.
1. https://forms.gle/zWVQL99mVjjWFwKp9
2. https://forms.gle/jvftuDcCA5FT8PLi6
RESULTS
54
ASSIGNMENT PROBLEMS
1. Find the resistance of an intrinsic germanium rod 1 cm long, 1 mm wide and 1 mm
thick at 300 K. the intrinsic carrier density is 2.5 × 10 19 m–3 at 300 K and the mobility
of electron and hole are 0.39 and 0.19 m 2 V–1 s–1. (Ans: 4.31 × 103
Ω)
2. Calculate the position of Fermi level E F and the conductivity at 300 K for germanium
crystal containing 5 × 10 22 arsenic atoms / m3. Also calculate the conductivity if the
mobility of the electron is 0.39 m 2 V–1 S–1 .
(Ans : EF is 0.16 eV below Ec, σ = 3210 𝝮-1 m-1)
5. For silicon semiconductor with band gap 1.12 eV, determine the position of the Fermi
level at 300 K, if me*=0.12m0 and mh*=0.28m0 (Ans : 0.576 eV)
PART A – QUESTIONS WITH ANSWERS
5. What are compound semiconductors? (or) What are direct band gap
S.
Intrinsic Semiconductor Extrinsic Semiconductor
No.
1. Pure semiconductors are Semiconductors doped with impurity
called intrinsic are called extrinsic semiconductors.
semiconductors.
2. Charge carriers are produced Charge carriers are produced due to
due to thermal agitation. impurities as well as thermal agitation.
3. They have low electrical They have high electrical conductivity.
conductivity.
4. They have low operating They have high operating temperature.
temperature.
5. At 0K, Fermi level lies exactly At 0K, Fermi level lies closer to
between conduction and conduction band in the n type
valence bands. semiconductor and closer to the
valence band in the p type
semiconductor.
Examples: Ge and Si.
Examples: Ge or Si doped with As, Sb,
P, Al, B, etc.
The process of adding suitable impurities to a pure semiconductor is called doping. The
maximum extent up to which impurity can be added is called doping level.
Semiconductor added with pentavalent impurity is called n-type semiconductor.
Semiconductor added with trivalent impurity is called p-type semiconductor.
A trivalent impurity when doped with an intrinsic semiconductor accepts one electron
which produces an energy level called acceptor energy level.
10. How the Fermi level changes its position with the impurity
concentration in p-type semiconductors? (K2, CO4)
With increase of temperature more and more charge carriers are created and hence
the conductivity of semiconductors increases. In the case of metals with increase of
temperature the concentration of charge carriers remain the same. But due to
increase of thermal energy, the electrons make frequent collisions with lattice ions
and hence the resistivity increases and conductivity decreases.
13. What do you understand by the term electron-hole pair? (K1, CO4)
They are
i. Gauss Meter
ii. Electronic Multiplier
iii. Electronic Wattmeter
20. Compare elemental and compound semiconductors. (or) What are the
differences between direct and indirect band gap semiconductors?
(K2 CO4)
22. Why do we prefer Silicon for transistors and GaAs for laser diodes?
(K2, CO4)
Silicon
a. Silicon is abundant and cheap to process. Si is highly abundant in the Earth's
crust, in the form of silicate minerals.
b. The existence of silicon dioxide—one of the best insulators. Silicon dioxide can
easily be incorporated onto silicon circuits, and such layers are adherent to the
underlying Si.
c. Silicon possesses a much higher hole mobility. This high mobility allows the
fabrication of higher-speed P-channel field effect transistors, which are required
for CMOS logic.
d. Silicon is an indirect band gap semiconductor for which the lifetime of the charge
carriers is more and the current amplification is very high, hence it is preferable
for using it in transistors.
Gallium (III) Arsenide
e. GaAs is a direct band gap semiconductor in which electrons and holes recombine
directly to produce photons and hence used in laser diodes.
f. GaAs cells are relatively insensitive to heat and have high switching speed.
g. GaAs has high absorptivity so it requires a cell only a few microns thick to absorb
sunlight.
h. It has a higher saturated electron velocity and higher electron mobility, allowing
transistors made from it to function at frequencies in excess of 250 GHz.
i. GaAs devices generate less noise than silicon devices when operated at high
frequencies.
j. They can also be operated at higher power levels than the equivalent silicon
device because they have higher breakdown voltages.
23. Why is a semiconductor damaged by strong current? (K2, CO4)
A strong current when passed through a semiconductor, heats up the semiconductor
and covalent bonds break up. Large number of free electrons are released with the
material behaving as a conductor. The material loses its semiconducting nature and
is said to be damaged.
25. Why are there an equal number of electrons and holes in an intrinsic
semiconductor? (K2, CO4)
There are an equal number of electrons and holes in an intrinsic semiconductor
because for each electron promoted from the valence band to the conduction band,
there is one hole created in the valence band.
PART B – QUESTIONS
1. (i) Obtain an expression for density of electrons in the conduction band and holes
in the valence band of an intrinsic semiconductor. (12)
(ii) How does intrinsic carrier concentration vary with temperature for an intrinsic
semiconductor? (4)
3. (i) Obtain an expression for density of electrons in the conduction band and holes
in the valence band of an intrinsic semiconductor. (12)
(ii) The energy gap of Si is 1.1 eV. Its electron and hole mobilities at room
temperature are 0.48 and 0.013 m 2 V-1 s-1. Calculate its conductivity. (4)
4. (i) Show that for a p-type semiconductor the Hall coefficient R H is given by 1/pe.
How do you determine the mobility of charge carriers for an n-type
semiconductor using Hall Effect? (10)
(ii) Derive the expression for the Fermi level of intrinsic semiconductor. Explain
with a neat sketch, the variation of Fermi level with temperature.
6. (i) What are semiconductors? What are its types? Explain it with suitable
necessary diagrams. (8)
(ii) Compare the variation of Fermi level with temperature and impurity
concentration in N-type and P- type semiconductors (8)
SUPPORTIVE ONLINE CERTIFICATION
COURSES
NPTEL COURSES
2. Physics of Materials
Coursera
4. Semiconductor Physics
5. Intrinsic semiconductor -1
6. Intrinsic semiconductor -2
7. Intrinsic semiconductor - 3
8. Carrier concentration
9. Intrinsic Vs Extrinsic
10.Hall Effect
edX
12.Semiconductor Fundamentals
Udemy
So many digital consumer products in daily life use semiconductors to keep them
functioning better longer including smartphones, digital cameras, televisions,
washing machines and dryers, ovens and refrigerators, and even LEDs.
65
The number of car-mounted semiconductor devices is rising. This relates
especially to Advanced Driver Assistance Systems where the need is growing for
semiconductors
66
The technologies of the future includes artificial intelligence, quantum computing,
and 5G and 6G wireless networks. Semiconductor innovation is the engine that
drives all these promising technologies.
DIY applications for everyday use
Semiconductor Device
67
CONTENT BEYOND THE SYLLABUS
1. Tunnel Diode
2. Varactor Diode
4. Organic Semiconductors
5. Zener Diode
PRESCRIBED TEXTBOOKS AND
REFERENCE BOOKS
TEXTBOOKS
2. R.K. Gaur and S.L. Gupta, “Engineering Physics”, Dhanpat Rai Publications (P)
Ltd., Eighth Ed., New Delhi, 2001.
4. R.A. Serway and J.W. Jewett, “Physics for Scientists and Engineers”, Ninth Ed.,
Cengage Learning, 2014.
5. C. Kittel, “Introduction to Solid State Physics”, 8 th Ed., John Wiley & Sons, NJ,
USA, 2005.
REFERENCE BOOKS
6. D. Halliday, R. Resnick and J. Walker, “Fundamentals of Physics”, 9 th Ed., John
Wiley & sons, 2011.
7. R.P. Feynman, “The Feynman Lectures on Physics - Vol. I, II and III”, The New
Millennium Edition, 2012.
8. N.W. Aschroft and N.D. Mermin, “Solid State Physics”, Harcourt College
Publishers, 1976.
10. M.A. Wahab, “Solid State Physics”, 3 rd Edition, Narosa Publishing House Pvt. Ltd.,
2015
11. N. Garcia and A. Damask, “Physics for Computer Science Students”, Springer-
Verlag, 2012.
MINI PROJECT SUGGESTIONS
Disclaimer:
This document is confidential and intended solely for the educational purpose of RMK Group of Educational
Institutions. If you have received this document through email in error, please notify the system manager. This
document contains proprietary information and is intended only to the respective group / learning community as
intended. If you are not the addressee you should not disseminate, distribute or copy through e-mail. Please notify
the sender immediately by e-mail if you have received this document by mistake and delete this document from
your system. If you are not the intended recipient you are notified that disclosing, copying, distributing or taking
any action in reliance on the contents of this information is strictly prohibited.