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- GASIFICATION
- PYROLYSIS
Table 1.
TT
facilities
Heating value
Moisture content and ash represent the non-combustible component of the
MSW. Moisture and ash are undesirable in MSW as they add weight to the
fuel without adding to the heating value. Furthermore, ash retains heat when
removed from the furnace; causing useful heat to be lost to the environment.
The volatile matter and the fixed carbon content are the preferred indicators of
the combustion capability of MSW.
Volatile matter: the portion of MSW converted into gas as the temperature
increases. Gasification occurs before the onset of combustion.
Fixed carbon: the solid carbon residue that has settled on the furnace grates.
Combustion occurs in the solid state, i.e., on the surface of this ‘char’ material. The
rate of combustion is affected by the temperature and surface area of the char. A
waste fuel with a high percentage of fixed carbon will require a longer retention
time in the combustion chamber to achieve complete combustion as compared with
a fuel low in fixed carbon.
HHV (MJ/kg) = 0.339 (C) + 1.44 (H) – 0.139 (O) + 0.105 (S)
Heating value
Low heating value (LHV): subtracting the heat of vaporization of water. This value
represents the net heat available during the incineration of MSW.
Calculate the gross heat value and net heat value of this waste as received
Difference between Pyrolysis, Gasification and
Incineration
Incineration usually involves the
combustion of unprepared (raw or
residual) MSW. To allow the
combustion to take place a sufficient
quantity of oxygen is required to
fully oxidise the fuel. Typically,
incineration plant combustion
(flame) temperatures are in
excess of 850ºC and the waste is
converted into carbon dioxide and
water. Any noncombustible materials
(e.g. metals, glass) remain as a solid,
known as Bottom Ash, that contains
a small amount of residual carbon
Difference between Pyrolysis, Gasification and
Incineration
The process is much more complex, however, since not all the hydrocarbons are
converted into carbon dioxide and water; and other components of the waste
such as sulfur and nitrogen are also oxidized, as follows:
Example 2
A carbonaceous waste given by the empirical formula C65.5H102.3O40.8N1.1 is to
be incinerated. Proximate and elemental analysis of the waste are as follows:
Proximate % Elemental %
analysis analysis
Moisture 4.8 Carbon 47.36
Noncombustibles 6.2 Hydrogen 6.25
Oxygen 39.25
Nitrogen 0.85
Sulfur 0.19
Ash 6.10
Calculate the volume of air needed for the complete combustion of 1000 kg
(1 metric ton) of the input material.
Incineration technology overview
Incinerator with energy recovery typically comprise the following key elements:
waste reception and handling
combustion chamber
energy recovery plant
emissions clean-up for combustion gases
bottom ash handling and air pollution
control residue handling
Combustio
Waste
n chamber
Funnel
Sec.
Air Stair type grate
Mo
vi ng
g ra
te
Slag
Prim.
Water
Air
basin
Rotary kiln
Rotary kiln installation
The control of CO, VOCs and dioxins in terms of their concentration is primarily
though correct combustion conditions being maintained.
The clean-up of the flue gases will produce solid residues comprising fly-ash,
lime/bicarbonate and carbon. These residues are usually combined (although some
systems may separate fly ash and other components) and are classified as hazardous
waste, therefore their disposal must be undertaken in accordance with relevant
regulations and guidance. Typically, their production will be around 2% - 6% of the
weight of the waste entering the incinerator.
Flue Gas Cleaning Method
Flue Gas Emission in
Step 3 :2:Dioxin
Step Treatment
Flue Gas
accordanceCleaning
to EU to
Step 1: Flue Gas Cooling
removeStandard
dust andprior
acidic
togases
discharge to
atmosphere
Dioxin Filter
Scrubber
Quencher
Continuous Emission Monitoring System
Incineration technology overview
Bottom Ash Handling
The main residual material from the incineration of MSW is referred to as “bottom
ash”. This is the residual material in the combustion chamber and consists of the
noncombustible constituents of the waste feed.
The bottom ash typically represents around 20% - 30% of the original waste feed by
weight, only about 10% by volume. The bottom ash is continually discharged from
the combustion chamber and is then cooled. The amount of ash will depend on the
level of waste pre-treatment prior to entering the incinerator and will also contain
metals that can be recovered for recycling.
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Summary: The three main issues of incineration
The three main issues: (i) air emissions (ii) residual incinerator ash (iii) dioxin
Air emissions
The combustion of any substance will generate byproduct emissions that could
be released to the air
air emissions are usually associated with metals, mercury, lead, cadmium,
organics such as dioxins and furans, acid gases, particulate matter such as dust
and grit
People can be exposed to emissions directly by inhaling contaminated air,
ingesting, having skin contact with contaminated soil and dust.
can also occur indirectly by eating foods that have been contaminated with
these substances
Residual incinerator ash
generates ash representing about 10% by volume and 25-35% by weight of
the waste incinerated.
Ash can divided into two categories:
Summary: The three main issues of incineration
Energy Recovery
Incineration processes are designed to recover energy from the waste processed
by generating electricity and / or heat for use on site and export off site. The
useful energy that can be generated from an incineration plant using a boiler to
generate steam is presented in Table 5.
Markets and outlets for the outputs
5
PYROLYSIS AND
GASIFICATOIN
Advantages of Pyrolysis Disadvantages of Pyrolysis
and Gasification over and Gasification over
Incineration Incineration
Less oxygen, thus fewer air emissions Unless they only deal with truly
Plants are modular; made up of small residual waste, the processes will
units which can be added to or taken undermine recycling and composting.
away as waste streams or volumes Any fuel produced will not make up for
change and are therefore more flexible the energy spent in manufacturing new
and can operate at a smaller scale than products
mass-burn incinerators. Disposal of ash and other by-products
They are quicker to build. may be required, though some
Produce more useful products – gases, companies claim that their process
oils and solid char useful as a fuel, or makes this easier than for incineration
purified and used as a feedstock for ash.
petro-chemicals and other applications.
The syngas may be used to generate
energy more efficiently, if a gas engine
(and potentially a fuel cell) is used
Thermal treatment (TT) technology overview
The choices of these variables, heating rate and temperature, determine the
products obtained from the pyrolysis system.
At very high temperatures and slow heating, the product is mostly gas, while
at very slow heating rates and low temperature, mostly solid product results
How it works
Waste reception, handling and pre-treatment
The pyrolysis and gasification process treats the biodegradable materials
present in MSW (e.g. paper,card, putrescible waste, green waste, wood), as
well as plastics. Non combustible materials and recyclables (typically metals
and glass) are removed prior to the primary treatment reactor stage.
The feed material might require processing to remove excess moisture and
shredding to reduce the size.
TT processes may be used in conjunction with other waste treatment
technologies such as Mechanical Biological Treatment (MBT) and
Mechanical Heat Treatment (MHT). Many MBT/MHT plant are designed to
produce a fuel stream (primarily composed of paper, card and plastics) as one
of the outputs from the process. This is commonly referred to as Refuse
Derived Fuel or RDF. This may be more amenable to processing in a TT plant
rather than raw MSW.
How it works
Thermal Treatment Reactor
The thermal treatment process, whether pyrolysis or gasification, will
produce syngas and solid residue. The composition of the syngas and solid
residue will depend on the process conditions employed, which include
operating temperature, oxygen level, heating rate and residence time in the
reactor. The main types of thermal treatment units available, their
application and operating conditions are summarised in Table 2. There are
also other factors influencing the process such as direction of gas flow
(e.g. horizontally or vertically).
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Table 2. Treatment icon
reactors to add picture
How it works
Gas and Residue Treatment Stages
Solids will be discharged from the process which include metals together with carbon.
The level of carbon is small for gasification; but significant in pyrolysis
Larger particles of solids in the thermal treatment reactor are usually discharged as
bottom ash and slag. Lighter ash is usually collected when the gas is separated with the
use of cyclones and ultimately filters. In addition, volatile metals such as lead, tin,
cadmium and mercury will be carried in the gas until such point that the gas is cooled
for them to be sufficiently condensed.
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Markets and outlets for the outputs
TT processes will all produce a gas (usually for energy recovery) and a solid
residue (slag, ash or char). Some facilities are also designed with mechanical
preparation and sorting equipment to extract recyclables. Table 3 summarises
the key outputs from ATT processes.
Materials Recycling
Recyclables derived from either the front end preparation stage of a TT plant
or metals extracted from the back end of the process (i.e. out of the ash) are
typically of a lower quality than those derived from a separate household
recyclate collection system, and generally have a lower value accordingly.
The types of materials recovered from TT processes almost always include
metals (ferrous and non-ferrous), usually from the front end of the process.
Metal removal can help enhance overall recycling levels and enable recovery
of certain constituent parts that would not otherwise be collected in
household systems (e.g. steel coat hangers, scrap metal etc.).
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Table 3:
Examples of outputs
from gasification and
pyrolysis
processes
Markets and outlets for the outputs
Pyrolysis plants produce a bottom residue that contains significant amounts of
carbon. This will need to be disposed of to landfill, or treated further to reduce the
carbon content for example by gasification or combustion. If treated further the final
bottom residue could then be recycled as a secondary aggregate.
Gasification tends to produce a bottom residue which has a lower carbon content and
has usually been melted or fused, and this could therefore be recycled as aggregate.
The recycling of bottom ash would need to be undertaken in accordance with
relevant legislation but is likely to be of equivalent or potentially better quality than
incinerator bottom ash, which is currently recycled in aggregate applications.
Energy
TT processes are designed to recover energy from the waste processed either in the
form of fuel production (liquid or gas) or combusting the syngas to generate
electricity and/or heat for use on site and export off site. There is also potential for
the syngas to be utilised in vehicles, after reforming to produce hydrogen. It is
envisaged that the initial market for the hydrogen would be public transport fleets
using fuel cell vehicles.
PLANNING ISSUES
Key Issues
The key issues that will need to be considered when planning a TT facility
are:
Plant/Facility Siting;
Traffic;
Air Emissions / Health Effects;
Dust / Odour;
Flies, Vermin and Birds;
Noise;
Litter;
Water Resources;
Visual Intrusion; and
Public Concern
Planningissues
Plant Siting
TT processes can be similar in appearance and characteristics to various
process industries. It would often be suitable to locate facilities on land
previously used for general industrial activities
Facilities are likely to require good transport infrastructure. Such sites should
either be located close to the primary road network or alternatively have the
potential to be accessed by rail or barge
The location of such plants together with facilities producing RDF (such as
MBT and MHT facilities) could be advantageous.
The potential for export of energy to host users or the national grid should
also be a key consideration in the siting of TT facilities. Consideration should
always be given to utilising not only the electricity from the plant but also the
waste heat in order to maximise energy and carbon benefits.
Planningissues
Traffic
TT facilities may be served by large numbers of heavy goods vehicle with a
potential impact on local roads and the amenity of local residents. It is likely
that the site layout/road configuration will need to be suitable to accept a
range of light and heavy vehicles.
Emissions/Health Effects
The major emission from a plant with energy recovery is the release of flue
gases from the combustion of the syngas or residual solid. The clean-up
required for the flue gases is dependent on the process from which they have
been generated. One of the main benefits claimed by manufacturers for
pyrolysis and gasification plant is that emissions of pollutants are lower than
those from conventional incineration.
Entrained (fine) particles in the syngas can either be removed before or after
combustion depending on the treatment process and combustion technology
employed.
Planning issues
A further solid residue that is produced is from abatement plant used to
clean-up the flue gases from the combustion process. Both of these solid
streams are hazardous and must be disposed of appropriately. Often they are
combined as they are removed during the same stage of the flue gas clean-up.
Dust / Odour
Any waste management operations can give rise to dust and odours. These
can be minimised by good building design, performing all operations under
controlled conditions indoors, good working practices and effective
management undertaken for dust suppression from vehicle movements.
Flies, Vermin and Birds
A TT processing is unlikely to attract vermin and birds due to majority of
waste throughput and operations being completely enclosed in buildings.
However, it is possible that flies could accumulate, especially if they have
been brought in during delivery of the waste. Effective housekeeping and on
site management of tipping and storage areas is essential to minimise the risk
from vermin and
Planning issues
other pests. In some operations waste heat from the process may be used to
bring temperatures in fresh input waste to levels above which flies can live.
The use of RDF as a feedstock would reduce this issue relative to raw waste.
Noise
The main contributors to noise associated with TT are likely to be:
vehicle movements / manoeuvring; steam turbine units; and
traffic noise on the local road networks;
air cooled condenser
units.
mechanical processing such as waste preparation;
air extraction fans and ventilation systems;
Litter
Any waste which contains plastics and paper is more likely to lead to litter
problems. With TT litter problems can be minimised as long as good working
practices are adhered to and vehicles use covers and reception and processing
are undertaken indoors.
Planning issues
Visual Intrusion
Visual intrusion issues should be dealt with on a site specific basis and the
following items should be considered:
Effect on landscape; removal of items such as trees or undertaking major earthworks
Site setting; is the site close to heritage buildings, conservation areas or sensitive
viewpoints
Existing large buildings and structures in the area
The potential of a stack associated with some air clean up systems for mixed waste
processing operations may impact on visual intrusion
Use of screening features (trees, hedges, banks etc); and
The number of vehicles accessing the site and their frequency
Public Concern
Public concerns about waste facilities relate to amenity issues (odour, dust,
noise, traffic, litter etc). With thermal based facilities health concerns can also be
a perceived issue.
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Table 4.
Land requirement
Size and Land take
Table 4 shows the land area required for the building footprint and also
for the entire site (including supporting site infrastructure) for examples
of thermal processes.
References
Vesilind, P. A., Worrell, W., and Reinhart, D. (2002). Solid waste engineering.
Brooks/Cole Thomson Learning, California, United States
Pichtel, J. (2005). Waste management practices. Municipal, hazardous and
industrial. Taylor & Francis Group, Boca Raton, United States