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It should be kept in mind that refrigeration is not same as “cooling”, even though
both the terms imply a decrease in temperature.
Cooling is a heat transfer process down a temperature gradient, it can be a
natural, spontaneous process. However, refrigeration is not a spontaneous
process, as it requires expenditure of energy.
The reverse process, however, cannot occur by itself. The transfer of heat
from a low-temperature region to a high-temperature one requires special
devices called refrigerators
Another device that transfers heat from a low-temperature medium to a
high-temperature one is the heat pump. Refrigerators and heat pumps are
essentially the same devices; they differ in their objectives only
Artificial Refrigeration
Vapour Compression Refrigeration Systems:
Vapour Absorption Refrigeration Systems:
Gas Cycle Refrigeration:
Steam Jet Refrigeration System:
Thermoelectric Refrigeration Systems:
Application of Refrigeration and Air - conditioning
Where m is the mass of the substance providing cooling, cp is its specific heat and ΔT
is the temperature rise undergone by the substance.
2. Endothermic mixing of substances
Low temperatures can be obtained when certain salts are dissolved in water.
This is due to the fact that dissolving of these salts in water is an endothermic
process
3. Phase change processes
Refrigeration is produced when substances undergo endothermic phase change
processes such as sublimation, melting and evaporation.
For all phase change processes, the amount of refrigeration produced is
given by:
where Q is the refrigeration produced (heat transferred), m is the mass of the phase
change substance and Δhph is the latent heat of phase change.
4. Expansion of Liquids
When a battery is added in between the two conductors A and B whose junctions are
initially at same temperature, and a current is made to flow through the circuit, the
junction temperatures will change, one junction becoming hot (T1) and the other
becoming cold (T2). This effect is known as Peltier effect.
Refrigeration effect is obtained at the cold junction and heat is rejected to the
surroundings at the hot junction. This is the basis for thermoelectric
refrigeration systems.
Cont..
6. Adiabatic demagnetization
Similar to mechanical compression and expansion of gases, there are some
materials that raise their temperatures when adiabatically magnetised, and drop thei
temperature when adiabatically demagnetised.
Each atom of the paramagnetic salt may be considered to be a tiny magnet. If the sal
is not magnetized then all its atoms or the magnets are randomly oriented such that
the net magnetic force is zero.
If it is exposed to a strong magnetic field, the atoms will align themselves to the
direction of magnetic field. This requires work and the temperature increases
during this process.
Now if the magnetic field is suddenly removed, the atoms will come back to the
original random orientation. This requires work to be done by the atoms. If there i
no heat transfer from surroundings, the internal energy of the salt will decrease as
it does work. Consequently the salt will be cooled .