Professional Documents
Culture Documents
OSHA
PA Training for Health & Safety
(PATHS)
29 CFR 1910.1200
(HCS-2012)
&
United Nations Globally
Harmonized System of
Classification and Labeling of
Chemicals (GHS, Rev 3)
PPT-016-04 1
Hazard Communication Standard (1910.1200)
PPT-016-04 2
Standard Requirements
• Change in process
• As deemed necessary by
supervision/management
PPT-016-04 4
“Right to Know” Law
PPT-016-04 5
Why is a Standard Necessary?
o Heart ailments
o Burns/rashes
o Kidney/lung damage
o Sterility
o Cancer
o Central nervous system damage
PPT-016-04 6
Globally Harmonized System
Rationale:
“To provide a single, harmonized system to classify
chemicals, labels and SDS with the primary benefit
of increasing the quality and consistency of
information provided to workers, employers and
chemical users”*
PPT-016-04 8
Updating GHS/HCS
• Mixtures (GHS)
o Health hazards can be based on data for mixture
o If no data, extrapolate from ingredient data or other similar mixtures
to classify
PPT-016-04 11
HNOC: Hazards Not Otherwise Classified
• Under new GHS standard, the following are not classified under
HNOC but addressed individually:
o Pyrophoric gases
o Simple asphyxiants
o Combustible dusts
PPT-016-04 12
Other Label Elements
Pyrophoric Gases:
-Signal Word: Danger
-Hazard Statement: “Catches fire spontaneously if
exposed to air”
Simple Asphyxiants:
-Signal Word: Warning
-Hazard Statement: “May displace oxygen and cause
rapid suffocation”
Combustible Dusts:
-Signal Word: Warning
-Hazard Statement: “May form combustible dust
concentrations in the air”
PPT-016-04 13
OSHA will Also Revise
• Most substance-specific
health standards
PPT-016-04 14
Effective Dates for GHS
Effective
Completion Date Requirements Who
PPT-016-04 15
Effective Dates
Effective
Completion Date Requirements Who
PPT-016-04 16
OSHA
PPT-016-04 17
Hazard Classification
PPT-016-04 18
Hazard Classification
PPT-016-04 19
Hazard Communication & Chemical Safety
PPT-016-04 20
Chemical Safety
PPT-016-04 21
Routes of Occupational Exposure
PPT-016-04 22
Hazards
PPT-016-04 23
Physical Hazards
PPT-016-04 24
Physical Hazards
or below
• Unstable materials
PPT-016-04 26
Acute Health Effects
• Happen quickly
• Examples:
o Carbon monoxide
poisoning
o Cyanide inhalation
o Hydrogen sulfide
inhalation
PPT-016-04 27
Chronic Health Effects
PPT-016-04 28
Keeping It Safe
PPT-016-04 29
Labeling
PPT-016-04 30
Chemical Labels
PPT-016-04 31
Label Information
PPT-016-04 32
Reading Chemical Labels
PPT-016-04 33
Labels/Other Warnings
PPT-016-04 34
Labeling
PPT-016-04 35
GHS Comparison
GHS
5 = Least Hazardous
1 = Most Hazardous
PPT-016-04 36
Pictograms
Different symbol on
white background with
red square frame set on
point
PPT-016-04 37
Health Hazard
Used to describe:
o Carcinogen
o Mutagenicity
o Reproductive toxicity
o Respiratory sensitizer
o Target organ toxicity
o Aspiration toxicity
o Germ cell mutagens
PPT-016-04 38
Flame
Describes:
o Flammables
o Pyrophorics
o Self-heating
o Emits flammable gas
o Self-reactives
o Organic peroxides
PPT-016-04 39
Exclamation Mark
Describes:
o Irritant (skin and eye)
o Skin sensitizer
o Acute toxicity (harmful)
o Narcotic effects
o Respiratory tract irritant
o Hazardous to ozone layer
(non-mandatory)
PPT-016-04 40
Gas Cylinder
Describes:
PPT-016-04 41
Corrosion
Describes:
o Skin corrosion/burns
o Eye damage
o Corrosive to metals
PPT-016-04 42
Exploding Bomb
Describes:
o Explosives
o Self-reactives
o Organic peroxide
PPT-016-04 43
Flame Over Circle
Describes:
o Oxidizers
Anything wrong
with this picture?
Yes!
Unsafe storage –
cylinders falling over!
PPT-016-04 44
Skull and Crossbones
Describes:
o Acute toxicity (fatal or toxic)
PPT-016-04 45
Signal Word
A single word
indicating relative
hazard severity
PPT-016-04 46
Hazard Statement
PPT-016-04 47
Precautionary Statement
Information required on a
GHS label:
1-Product identifier
2-Pictograms
3-Signal word
4-Hazard statement
5-Precautionary statement
6-Supplier information
PPT-016-04 49
GHS: Annex 2
PPT-016-04 50
GHS: Annex 2
PPT-016-04 51
Table A3.1.2 Hazard Statement Codes
PPT-016-04 52
Table A3.2.3 Precautionary Statements
PPT-016-04 53
Labels
Chemical manufacturer,
importer or distributor:
ensure each container
of hazardous chemicals
leaving workplace is
labeled, tagged or
marked with:
o Identity of chemical,
o Hazard warnings, and
o Name and address of
manufacturer, distributor
or importer
PPT-016-04 54
Transporting
For transportation:
Use pictograms, referred
to as labels in transport
regulations, prescribed by
UN Model Regulations on
the Transport of
Dangerous Goods
PPT-016-04 55
Dangerous Good Label
UN regulations:
This symbol affixed to
packaging on a
background of
contrasting color
Only UN transport
markings and labels are
required for outer
packaging
PPT-016-04 56
Label Examples
PPT-016-04 57
Intermodal Container Markings
“Hazard Identification
Numbers” may be used
with intermodal
containers
Highly flammable
Top panel: 2 or 3 digits liquid
coded to group of
hazards; Gasoline
PPT-016-04 59
SDS
• Developed by chemical
manufacturers and
importers
PPT-016-04 60
Information on a SDS
• Chemical names
PPT-016-04 62
Information on a SDS
• Physical appearance
• Date of preparation
• Plus:
o How to put out a fire caused by a
chemical
o How to handle spills
o How to prevent dangerous exposures
PPT-016-04 63
Where are your SDSs?
SDSs:
PPT-016-04 64
SDS Categories
Section 1: Identification
Section 2: Hazard identification
Section 3: Ingredients
Section 4: First-aid measures
Section 5: Fire fighting measure
Section 6: Accidental release measures
Section 7: Handling and storage
PPT-016-04 65
SDS Categories
*OSHA indicated that since other agencies regulate sections 12-15, OSHA will
not be enforcing them
PPT-016-04 66
Section 1: Identification
PPT-016-04 67
Section 2: Hazard Identification
PPT-016-04 68
Section 2
• Classification of chemical
• Signal word, hazard statement(s), symbol(s) and
precautionary statement(s) in accordance with
paragraph (f) of this section (hazard symbols may be
provided as graphical reproductions or the name of
the symbol, e.g. flame, skull and crossbones)
• Unclassified hazards (e.g., combustible dust or dust
explosion hazard)
• Where an ingredient with unknown acute toxicity is
used in a mixture at a concentration > 1 percent, a
statement that x percent of mixture consists of
ingredient(s) of unknown toxicity is required
PPT-016-04 69
Section 3: Composition
• Format
SAFETY
• A separate SDS will be required DATA
for each mixture rather than SHEETS
PPT-016-04 70
Section 3
PPT-016-04 71
Section 3
PPT-016-04 72
Section 4: First Aid
PPT-016-04 73
Section 5: Fire-fighting
PPT-016-04 74
Section 6: Accidental Release
PPT-016-04 75
Section 7: Handling & Storage
Cylinders
unchained;
Drum not labeled
properly; Is this safe storage?
No spill
containment for
drum; NO!
Materials may be
incompatible
PPT-016-04 76
Section 8: Exposure Controls/PPE
PPT-016-04 77
Section 9: Physical, Chemical Properties
No new requirements
other than format: • Evaporation rate
• Flammability (solid,
• Appearance (physical liquid, gas)
state, color, etc)
• Upper/lower
• Odor flammability or
• pH explosive limits
• Melting point/freezing • Vapor pressure
point
• Vapor density
• Initial boiling point and
boiling range • Relative density
• Flash point • Solubility
PPT-016-04 78
Section 9: Physical, Chemical Properties
• Partition coefficient:
n-octanol/water
• Auto-ignition
temperature
• Decomposition
temperature
• Viscosity
PPT-016-04 79
Section 10: Stability and Reactivity
PPT-016-04 80
Section 11: Toxicological Information
Non-mandatory
• To be GHS-compliant, the requirements for
this section would be:
o Ecotoxicity (aquatic and terrestrial,
where available)
o Persistence and degradability
o Bioaccumulative potential
o Mobility in soil
o Other adverse effects
PPT-016-04 82
Section 13: Disposal Considerations
PPT-016-04 83
Section 14: Transportation Information
PPT-016-04 85
Section 16: Other Information
PPT-016-04 86
Written Hazard Communication Plan
PPT-016-04 88
Special Hazards
PPT-016-04 89
Contractor Requirements
PPT-016-04 90
Contractor Requirements
PPT-016-04 93
Summary
PPT-016-04 94
Now that You’ve Been Through the Presentation:
Large If chemical,
containers coffee can is
balanced not proper
on edge of type of
shelf- not storage
safe container
PPT-016-04 95
Questions
PPT-016-04 96