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13 Amines 2
13 Amines 2
UNIT 13
ORGANIC COMPOUNDS CONTAINING NITROGEN
PART II
DIAZONIUM SALTS
Prepared by
Mr, Sunil Urade, PGT Chemistry JNV
Chandrapur
Mr. G.T. Hirve, PGT Chemistry JNV Latur
Mr.Ajit Sharma, PGT Chemistry JNV
Gandhinagar
REGIONAL OFFICE, PUNE
OUTLINE
Review of previous session
Introduction:What are the diazonium salts?
Structure
Method of Preparation of benzenediazonium
chloride
Physical Properties of benzenediazonium chloride
Chemical properties of benzenediazonium chloride
Importance
DIAZONIUM SALTS
The diazonium salt have the general formula RN2+X-
where R stands for an aryl group and X- may be Cl- ,Br-,
HSO4- BF4- etc.
They are named by suffixing diazonium to the name of
the parent hydrocarbon from which they are formed
The N2+ group is called diazonium group.
For example, C6H5N2+Cl- benzenediazoniumchloride
Stability of benzene diazonium salt
The stability of benzenediazonium ion is
due to the resonance effect
Preparation (Diazotization)
Gatterman reaction :
2. Replacement by iodide ion: