Cementitious capillary crystalline waterproofing building

material

Abstract

The invention belongs to the technical field of building materials and particularly relates to a
cementitious capillary crystalline waterproofing building material. The cementitious capillary
crystalline waterproofing building material comprises the following components in parts by
weight: 100 parts of cement, 65-110 parts of silica sand, 50-90 parts of a mineral admixture, 3-6
parts of an activator, 0.6-1.2 parts of a chelating agent, 3-5 parts of a calcium ion compensator,
3-6 parts of a capillary crystalline, 0.08-0.2 part of a retarder, and 0.5-1.0 part of other additives,
wherein the other additives are the mixture of a defoamer and a dispersant, and the weight ratio
of the defoamer to the dispersant in the mixture is 1:(1-3). The cementitious capillary crystalline
waterproofing building material uses superfine slag powder as a mineral admixture, the silica
fume is completely replaced, part of the cement is replaced, and the manufacturing cost is
lowered; the waterproof material is relatively high in activity, the painted waterproof material
further has a dense structure, and the cementitious capillary crystalline waterproofing building
material has the characteristics of high wear-resisting property, high anti-permeability pressure,
strong self-healing ability and the like.

Classifications

Y02W30/91 Use of waste materials as fillers for mortars or concrete

Description

A kind of cement-base infiltration crystallization type architectural waterproof material Technical

field
The invention belongs to building materials technology field, particularly a kind of cement-base
infiltration crystallization type architectural waterproof material. Background technology
Along with the continuous improvement of the developing rapidly of economy, day by day the
reducing of land resources, living condition, the high stratification of building, high quality are
inexorable trends; On the other hand, subway, Tunnel Engineering increase increasingly, and a
lot of tier 2 cities is also at the ranks of subway construction.So the construction quality of quality
to these construction works of architectural waterproof material plays vital effect, be related to
the use value of buildings, working conditions and sanitary condition, have influence on the
activity in production of people, the quality of working life.
Architectural waterproof material is divided into rigid waterproofing and flexible water according
to the difference of principle and mode of appearance.What rigid waterproofing mainly adopted
is mortar, concrete or be mixed with the mortar of admixture or the rigid material of coagulation
great soil group, but this kind of water-proof material fragility is large, has the feature of splitting
resistance difference; What flexible water adopted is flexible waterproof material, mainly
comprise various waterproof roll, waterproof paint and sealing material etc., but the weather
resistance of this kind of flexible water is poor, and easy and basal plane peels off the
phenomenon producing two-layer skin, and cost is high.

Summary of the invention

The object of the invention is to improve a kind of cement-base infiltration crystallization type
architectural waterproof material, the ultimate compression strength of this kind of architectural
waterproof material is high, impermeability pressure is high and self-regeneration strong, and
cost is low.
Object of the present invention can be achieved through the following technical solutions: The
invention has the beneficial effects as follows:
A kind of cement-base infiltration crystallization type architectural waterproof material, is
characterized in that: its moiety according to parts by weight is:
Other additives described are the mixture of defoamer and dispersion agent, and in mixture, the
weight proportion of defoamer and dispersion agent is 1:1-3.
Described cement is strength grade higher than the silicate cement of 42.5 grades or ordinary
Portland cement.
Described mineral additive is superfine graining blast-furnace cinder micro-powder, the specific
surface area>=600m of this superfine graining blast-furnace cinder micro-powder 2/ kg.
The mixture of described quartz sand is particle diameter to be 50-100 object coarse sand and
particle diameter be 100-200 object fine sand, the proportioning that adds of coarse sand and
fine sand is 2:1-3:1.
Described exciting agent is potassium aluminium sulfate. Described sequestrant is tartrate or
maleic acid.
Described calcium ion compensator is calcium hydroxide or Calcium Chloride Powder
Anhydrous.
Described penetrant crystalline agent is sodium carbonate or water glass. Described retardant is
citric acid.
Described defoamer is polyethers defoamer, and described dispersion agent is polycarboxylic
acid dispersant.
The reaction mechanism that the present invention utilizes has penetrant crystalline mechanism,
chelating hyperplasia mechanism, excites catalytic mechanism and migration reinforcement
mechanism.
Penetrant crystalline mechanism: utilize the CO that crystalline deposit agent discharges 3 2-,
and the Ca that cement discharges in hydration process 2+reaction, generates CaCO 3crystal,
reaches the object of crackle filling and pore filling, realizes blocking water and density effect.
Chelating hyperplasia mechanism: the unique texture utilizing sequestrant, the Ca of hole
solution in chelating concrete 2+, reduce the potential barrier of its crystallization nucleation, the
formation of acceleration of hydration product, thus realize crystallization effect.
Excite catalytic mechanism: utilize the Al that crystalline deposit agent discharges 3+and SO4 2-,
accelerate the formation of needle-like crystal ettringite, realize the shutoff effect to crackle.
Migration reinforcement mechanism: the slow setting effect utilizing retardant, component in
capillary crystalline waterproof coating material is moved in the crackle and hole of concrete
substrate, and generate crystallized product by follow-up reaction, realize the filling of hole and
crackle, thus reach the effect of enhancing.
The preparation method of cement-base infiltration crystallization type architectural waterproof
material of the present invention is: take each component by each weight ratio in above-
mentioned formula, then quartz sand, cement, mineral additive, retardant, exciting agent,
sequestrant, calcium ion compensator, penetrant crystalline agent and admixture is fully mixed
in stirrer.
During slurry preparation, accurately take water conduction fracture and water, material is
slowly poured in appropriate clean water, ceaselessly stir with agitator simultaneously; For
ensureing that material effective constituent is fully dissolved, should continue when material
stirs into pasty state to stir after 2-3 minute and can use.Amount of water is the 40%-45% of
water conduction fracture weight.
The using method of cementitious capillary waterproofing material provided by the present
invention is:
1, basement bottom board adopts the dry phase method that spreads to construct.Spreading the
dry powder time is casting concrete before 30 minutes, in 6 hours.
2, metope and basement roof brushing construction point complete for twice, and first pass uses
scrub-brush, and back and forth firmly brushing more than three times; Second time can blade
coating or roller coating, often all over being spaced apart 4-6 hour, the concrete time
determines because of construction environment.When first pass not yet parches, but hand is
touched and can not be come off, and brushes second section, will be best combination
between now two-layer.
Compared to the prior art, beneficial effect is in the present invention:
1, the present invention is with the obtained ultrafine slag micro mist of metallurgical solid waste
granulated blast-furnace slag for mineral additive, replacing whole silicon ash, and Some
substitute cement, the specific surface area>=600m of this ultrafine slag micro mist 2/ kg, raw
material sources are easy to get, cheap, reduce the manufacturing cost of water-proof material.
2, described water-proof material not only has higher activity, also makes the water-proof
material after brushing have closely knit structure.
3, described water-proof material has the features such as high compressive strength, high
impermeability pressure, self-regeneration be strong.
Embodiment
Below in conjunction with embodiment, the invention will be further described: Embodiment 1:
Proportioning raw materials (weight part)
Cement: 100
Quartz sand: 70, the weight ratio of its medium coarse sand and fine sand is 2:1 Superfine
graining blast-furnace cinder micro-powder: 60
Potassium aluminium sulfate: 3.2 Tartrate: 0.8
Calcium hydroxide: 3.5
Sodium carbonate: 3.4
Citric acid: 0.1
Other additives: 0.6, the weight ratio of defoamer and dispersion agent is 1:3. Embodiment 2
Proportioning raw materials (weight part)
Cement: 100
Quartz sand: 90, the weight ratio of its medium coarse sand and fine sand is 2.5:1 Superfine
graining blast-furnace cinder micro-powder: 78
Potassium aluminium sulfate: 4.5
Maleic acid: 0.9
Calcium hydroxide: 3.9
Water glass: 4.0
Retardant: 0.15
Other additives: 0.8, the weight ratio of defoamer and dispersion agent is 1:2. Embodiment 3
Proportioning raw materials (weight part)
Cement: 100
Quartz sand: 100, the weight ratio of its medium coarse sand and fine sand is 3:1 Superfine
graining blast-furnace cinder micro-powder: 85
Potassium aluminium sulfate: 5.4 Maleic acid: 1.1
Calcium chloride: 4.4
Sodium carbonate: 5.2
Citric acid: 0.18
Other additive: 1.0, the weight ratio of defoamer and dispersion agent is 1:1.
The test result of above-mentioned three embodiments, contrast GB18445-2012 requirement, as
shown in table 1:
Table 1 test result contrast table
Can find out from test result contrast table, ultimate compression strength of the present
invention, impermeability pressure exceed standard-required far away, are very excellent water-
proof materials.
The above is preferred embodiment of the present invention, but the present invention should
not be confined to the content disclosed in this embodiment.The equivalence completed under
not departing from spirit disclosed in this invention so every or amendment, all fall into the scope
of protection of the invention.