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DIFFUSION

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Contents
◎ Introduction
◎ Types of Diffusion
◎ Diffusion System
◎ Characterization equipment's and techniques
◎ Diffusion Models
◎ Diffusion Process
Introduction
◎ Diffusion is the process of transferring the particle (impurities – in
view of the semiconductor ) from high concentration to low
concentration.
Mechanism of Diffusion in silicon
 Substitutional Diffusion : Impurities present in the vacancy.

 Interstitial Diffusion : Impurity atoms presents in between Si atom lattices.

 Interstitialcy Diffusion : occurs both substitutional and interstation diffusion


Diffusion System
Characterization equipment's and
techniques
 1. SIMS: Used for measurement of dopant concentration

 2. Spreading resistance: Used for measurement dopant profile concentration, by measuring the resistivity

 3. Sheet resistance: Used for the dopant profile.

 4. Capacitive- Voltage: Used mostly for lightly doped region doping profile.

 5. TEM Cross Sectional: Very thin cross section of diffused silicon is made by etching of silicon and

observed through TEM. Different doped areas have different contrast (colours).
Diffusion Models

• Macroscopy (Classical): Microscopy deals with concentration gradient


of dopant (physical basis)

• Microscopy (Atomic): Interaction between dopant and crystal defects


(atomic scale)
Diffusion Processes

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