Scribd Logo
Upload

Welcome to Scribd!

  • Equilibrio Liq-Liq Acetona (1) - Ndodecano

    Uploaded by

    Carlos GV
    9 views5 pages
    This document contains information about the liquid-liquid equilibrium of acetone and n-dodecane at 276.4K. It provides experimental data on the composition of each liquid phase at different overall compositions. It also contains calculations of the activity coefficients using a NRTL model with fitted parameters and compares the calculated results to literature data from Dechema.

    Original Description:

    Original Title

    p-8

    Copyright

    © Attribution Non-Commercial (BY-NC)

    Available Formats

    XLSX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document
    This document contains information about the liquid-liquid equilibrium of acetone and n-dodecane at 276.4K. It provides experimental data on the composition of each liquid phase at different overall compositions. It also contains calculations of the activity coefficients using a NRTL model with fitted parameters and compares the calculated results to literature data from Dechema.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as XLSX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    9 views5 pages

    Equilibrio Liq-Liq Acetona (1) - Ndodecano

    Uploaded by

    Carlos GV
    This document contains information about the liquid-liquid equilibrium of acetone and n-dodecane at 276.4K. It provides experimental data on the composition of each liquid phase at different overall compositions. It also contains calculations of the activity coefficients using a NRTL model with fitted parameters and compares the calculated results to literature data from Dechema.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as XLSX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 5

    EQUILIBRIO LIQ-LIQ

    Acetona(1)-nDodecano(2)
    a)
    T (K)
    276.4
    Composicion
    X1

    A12
    1.400454

    A21
    2.8623

    g/RT (ideal)

    gE/RT

    g/RT (real)

    PENDIENTE

    #NUM!
    -0.19851524
    -0.32508297
    -0.42270909
    -0.50040242
    -0.56233514
    -0.6108643
    -0.64744664
    -0.67301167
    -0.68813881
    -0.69314718
    -0.68813881
    -0.67301167
    -0.64744664
    -0.6108643
    -0.56233514
    -0.50040242
    -0.42270909
    -0.32508297
    -0.26638446
    -0.19851524
    -0.11690685
    #NUM!

    0
    0.06826479
    0.13282453
    0.19337184
    0.24956435
    0.30101963
    0.34730909
    0.38795085
    0.42240117
    0.45004418
    0.47017955
    0.48200746
    0.4846103
    0.47693015
    0.4577409
    0.42561346
    0.37887189
    0.31553774
    0.2332586
    0.18415498
    0.12921526
    0.06799419
    0

    0
    -0.13025045
    -0.19225844
    -0.22933725
    -0.25083807
    -0.26131551
    -0.26355521
    -0.25949579
    -0.2506105
    -0.23809464
    -0.22296763
    -0.20613136
    -0.18840137
    -0.17051649
    -0.1531234
    -0.13672169
    -0.12153054
    -0.10717134
    -0.09182437
    -0.08222949
    -0.06929998
    -0.04891266
    0

    -2.60500908
    -1.24015977
    -0.74157615
    -0.43001641
    -0.20954887
    -0.04479393
    0.08118846
    0.17770573
    0.25031728
    0.30254005
    0.33672553
    0.35459973
    0.35769759
    0.34786186
    0.32803425
    0.30382296
    0.28718389
    0.30693939
    0.38379548
    0.51718034
    0.81549281
    1.95650633

    X2
    0
    0.05
    0.1
    0.15
    0.2
    0.25
    0.3
    0.35
    0.4
    0.45
    0.5
    0.55
    0.6
    0.65
    0.7
    0.75
    0.8
    0.85
    0.9
    0.925
    0.95
    0.975
    1

    0.508075235
    0.89234426

    1
    0.95
    0.9
    0.85
    0.8
    0.75
    0.7
    0.65
    0.6
    0.55
    0.5
    0.45
    0.4
    0.35
    0.3
    0.25
    0.2
    0.15
    0.1
    0.075
    0.05
    0.025
    0

    0.491924765 -0.69301676
    0.10765574 -0.34158585

    0.47267484 -0.22034191
    0.2471915 -0.09439435

    b)

    X1
    0.89234426

    LIQUIDO 1
    g1
    X2
    0.10765574 1.05632303

    g2
    6.3088202

    X1
    0.50807524

    CALCULADO
    0.8923
    0.4919

    DECHEMA
    0.90
    0.48

    c)

    FASE RICA EN ACETONA


    FASE RICA EN n-DODECANO

    X1=
    X2=

    LIQUIDO 2
    X2
    0.49192476

    0.2

    0.4

    0.6

    -0.05

    -0.1

    g/RT -0.15

    -0.2

    -0.25

    -0.3

    LIQUIDO 2
    g1
    1.85524452

    X1

    E1
    g2
    1.38065972

    E2

    8.3314E-10 -5.1658E-10

    0.8

    1.2

    EQUILIBRIO LIQ-SOL
    Acetona(1)-nDodecano(2)
    Tfus (K)

    hfus (J/mol)
    R (J/mol K) A12
    A21
    263.6
    36619
    8.314
    1.496646

    3.0639

    a)
    Ec. 1
    T (K)

    x1

    259.486783

    ln( / )

    x2
    0.3

    0.7 -0.26486063

    s/L

    g2

    0.76731289 1.09616067

    b)
    A12
    A21
    1.57517775
    3.2284875

    T (K)

    x1

    253.15 0.97169412

    CALCULADO
    x2

    2.83058793

    ln( / )

    x2

    0.02830588 -0.68974635

    DECHEMA
    1.11

    Ec. 1
    s/L

    g2

    0.50170331 17.7243243

    Ec. 2
    g2x2
    0.76731247

    Ec. 2
    g2x2
    0.50170258

    E
    4.202E-07

    E
    7.2358E-07

    You might also like