Ex.01 Basic Thermodynamic calculations Roll No.

:
24.07.2023 Name:

Component A B C
Benzene(1) 13.8858 2788.51 52.41
Ethyl Benzene(2) 14.0045 3279.47 60

Temperature 373 K

lnP1sat 5.187743292
sat
lnP2 3.526960064
sat
P1 179.0640015
sat
P2 34.02039045

X1 P=(P1sat-P2sat)x1+Psat Y1=(X1P1sat)/P
0 34.02039045 0
0.05 41.272571 0.216928576
0.1 48.52475155 0.369015803
0.15 55.7769321 0.481553919
0.2 63.02911265 0.568194582
0.25 70.2812932 0.636954705
0.3 77.53347375 0.692851717
0.35 84.78565431 0.739186376
0.4 92.03783486 0.778219095
0.45 99.29001541 0.811549886
0.5 106.542196 0.840343114
0.55 113.7943765 0.865466325
0.6 121.0465571 0.887579155
0.65 128.2987376 0.907192098
0.7 135.5509182 0.924706396
0.75 142.8030987 0.940441785
0.8 150.0552793 0.95465619
0.85 157.3074598 0.967559971
0.9 164.5596404 0.979326407
0.95 171.8118209 0.99009952
1 179.0640015 1

P-X-Y Diagram at 373 K

200
180 p Vs x1
160
P vs Y1
140
 140
120

P,KPa
100
80
60
40
20
0
0 0.2 0.4 0.6 0.8 1 1.2
X,Y
21CHR034
KAVIYA S
Ex.01 Basic Thermodynamic calculations
24.07.2023

Component A B C
Benzene(1) 13.8858 2788.51 52.41
Ethyl Benzene(2) 14.0045 3279.47 60

T1sat 353.29435
sat
T2 409.38478

T ln P1sat P1
sat
ln P2
sat
P2
sat

353.29435 4.6180863 101.29999 2.823002641 16.82730123

358.90335 4.7876907 120.02388 3.03282638 20.75581359
364.51235 4.9511989 141.34432 3.234920375 25.40434889
370.12135 5.1089338 165.49382 3.429704037 30.86750576
375.73035 5.261196 192.71183 3.617566973 37.24683494
381.33935 5.4082652 223.24398 3.798871589 44.65077162
386.94835 5.5504029 257.34121 3.97395542 53.19452195
392.55735 5.6878528 295.25897 4.143133231 62.9999058
398.16635 5.8208433 337.25633 4.306698903 74.19515882
403.77535 5.9495877 383.59516 4.464927137 86.9146964
409.38478 6.0742958 434.54338 4.618086545 101.3000135

420
T-X-Y Diagram at 101.325 Kpa
410 T Vs X1
T Vs y1
400

390
T,K

380

370

360

350
0 0.2 0.4 0.6 0.8 1 1.2
X1,Y1
 Roll No.: 21CHR034
Name: KAVIYA S

sat sat sat sat

X1=P-P2 /P1 -P2 Y1=(X1P1 )/P
1.000296037 1.000049164
0.811632504 0.961414057
0.654827239 0.913457792
0.523356052 0.854795857
0.412171024 0.783915432
0.317336982 0.69917167
0.235764185 0.598784517
0.16501011 0.480836078
0.103131301 0.343268536
0.048571798 0.183882622
7.49796E-05 0.000321558