Diketahui :

ethanol
A = 16.6758
B = 3674.49
C = -46.7

1- propanol
A = 16.0692
B = 3448.66
C = -69.06

T = 320 K

ln⁡〖 (𝑃_1^𝑠𝑎𝑡)/𝑘𝑃𝑎 〗 =16,6758−3674,49/(𝑇−(−46,7))

= 𝑃_1^𝑠𝑎𝑡=exp16,6758−3674,49/(𝑇(−46,7)) =

ln⁡〖 (𝑃_2^𝑠𝑎𝑡)/𝑘𝑃𝑎 〗 =16,0692−3448,66/(𝑇−(−69,06)) =

𝑃_2^𝑠𝑎𝑡=exp16,0692−3448,66/(𝑇−(−69,06)) =

A. Bubl point 𝑥_1= 0.6

𝑃= 𝑃_2^𝑠𝑎𝑡+(𝑃_1^𝑠𝑎𝑡−𝑃_2^𝑠𝑎𝑡 ) 𝑥_1

𝑃_1^𝑠𝑎𝑡= 776.948901 and 𝑃_2^𝑠𝑎𝑡= 1346.3026539

P= 1346,30 + (776,94 - 1346,30)(0.6) = 1004.6904023 Kpa 1600

1400
Value y1 (Eq 10.1)
1200

y1= 〖𝑥 1P1 〗 ^𝑠𝑎𝑡/𝑃=((0,6)(1346,30))/1004,690= 0.4639930268 1000

800
x1 y1 P/kPa
600
0 0 1346.30265388665
0.2 0.12608387 1232.43190337185 400
0.4 0.27783869 1118.56115285705 200
0.6 0.46399303 1004.69040234225
0
0.8 0.69773845 890.819651827452 0 0.2 0.
1 1 776.948901312652

Dew P (Eq 10.3)

𝑦_( 0.6 T/t 320 K

𝑦_( 1
2 =)
=)
 𝑦_(
𝑦_( 1 0.4 46.85 ˚C
2 =)
P = 1/(𝑦_1/(𝑃_1^𝑠𝑎𝑡 ) + 𝑦_2/(𝑃_2^𝑠𝑎𝑡 ))
=)

P = 1/(0.6/776,94 +0.4/1346,30) 935.1373996 kPa

𝑥_1 = (𝑦_1 𝑃)/(𝑃_1^𝑠𝑎𝑡 )

0.722161314353479
P 70

1- propanol A 16.0692
B 3448.66
C -69.06
ln P 4.248495242

T 〖𝑁𝑖𝑡𝑟𝑜〗 ^𝑠𝑎𝑡= 𝐵/(𝐴−ln⁡𝑃 ) - C 222.68741021

T 〖𝐴𝑐𝑒𝑡𝑜𝑛〗 ^𝑠𝑎𝑡= 𝐵/(𝐴−ln⁡𝑃 ) - C 248.97875509

Goal seek

ethanol

A 16.6758
B 3674.49
C -46.7

T X1 X2 P1 sat P2 sat P P Goal seek

344.5144 0.1 0.9 1455.75008987877 2276.8089842 2194.7030947 2194.70309472
346.1126 0.2 0.8 1512.45936558825 2351.081721 2183.3572499 2183.35724995
347.7963 0.3 0.7 1574.0623244235 2431.2974976 2174.1269456 2174.12694564
349.5724 0.4 0.6 1641.16595613634 2518.1495809 2167.356131 2167.35613097
351.4501 0.5 0.5 1714.52783261664 2612.5047705 2163.5163016 2163.51630156
353.4387 0.6 0.4 1794.99631130421 2715.3202719 2163.1258956 2163.12589555
355.5487 0.7 0.3 1883.57980607713 2827.7264756 2166.8238069 2166.82380693
357.7921 0.8 0.2 1981.46857062752 2951.0460892 2175.3840743 2175.38407435
360.1822 0.9 0.1 2090.07269422966 3086.8317169 2189.7485965 2189.7485965
362.7336 1 0 2211.06847363906 3236.910957 2211.0684736 2211.06847364
Dew T dan P

ethanol 1- propanol

A 16.6758 A 16.0692
B 3674.49 B 3448.66
C -46.7 C -69.06

T Y1 Y2 P1 sat P2 sat P X1
344.5144 0.1 0.9 1455.75008987877 2276.8089842 2194.7030947 0.066330
346.1126 0.2 0.8 1512.45936558825 2351.081721 2183.3572499 0.138544
347.7963 0.3 0.7 1574.0623244235 2431.2974976 2174.1269456 0.217199
349.5724 0.4 0.6 1641.16595613634 2518.1495809 2167.356131 0.302888
351.4501 0.5 0.5 1714.52783261664 2612.5047705 2163.5163016 0.396236
353.4387 0.6 0.4 1794.99631130421 2715.3202719 2163.1258956 0.497890
355.5487 0.7 0.3 1883.57980607713 2827.7264756 2166.8238069 0.608497
357.7921 0.8 0.2 1981.46857062752 2951.0460892 2175.3840743 0.728687
360.1822 0.9 0.1 2090.07269422966 3086.8317169 2189.7485965 0.859033
362.7336 1 0 2211.06847363906 3236.910957 2211.0684736 1
 776.94890131

1346.3026539

1600

1400

1200

1000

800

600

400

200

0
0 0.2 0.4 0.6 0.8 1 1.2

X1 Y1

1600

1400

1200
y1 y2 P/kPa x1 x2
1000
0 1 1346.303 0 1
800

600

400
 1400

1200

1000

0.2 0.8 1174.209 0.3022616 0.5556774 800

0.4 0.6 1041.125 0.536007 0.416758 600
0.6 0.4 935.1374 0.7221613 0.2778387
400
0.8 0.2 848.7352 0.8739161 0.1389193
1 0 776.9489 1 0 200

0
0 0.2 0.4 0.6 0.8

ethanol A 16.6758
B 3674.49
C -46.7

X1 Y1 T/t(K/C) P1sat P2Sat

0.00 0.00 222.6874 2.08E+01 70
-0.13 -0.04 220.4874 1.86E+01 63.987053
-0.28 -0.07 218.2874 1.66E+01 58.410227
-0.44 -0.09 216.0874 1.48E+01 53.244479
-0.61 -0.11 213.8874 1.31E+01 48.465747
-0.80 -0.13 211.6874 1.16E+01 44.050941
-1.01 -0.15 209.4874 1.03E+01 39.977924
-1.25 -0.16 207.2874 9.10E+00 36.225502
-1.50 -0.17 205.0874 8.02E+00 32.773405
-1.79 -0.18 202.8874 7.05E+00 29.602271
-2.00 -1.80 -1.60 -1.40 -1.20 -1.00 -0.80 -0.60 -

x1 y1

1- propanol

A 16.0692
B 3448.66
C -69.06

Y1 Y2
0.06633 0.9336698393 Grafik T vs X1,X2
0.138544 0.8614556216
365
0.217199 0.7828007705
0.302888 0.6971118991 360
0.396236 0.6037635974 355
0.49789 0.5021104463 X1
350
0.608497 0.3915029639 Axis Title Y1
0.728687 0.2713126499 345
0.859033 0.1409674025 340
1 0
335
0 0.2 0.4 0.6 0.8 1 1.2
Axis Title
 335
0 0.2 0.4 0.6 0.8 1 1.2
Axis Title

Grafik T vs Y1,Y2
365
X2
360
0.93367
0.861456 355
0.782801 350 Y1
Axis Title X1
0.697112
345
0.603764
0.50211 340
0.391503 335
0.271313 0 0.2 0.4 0.6 0.8 1 1.2
0.140967 Axis Title
0
4 0.6 0.8 1 1.2

225

220

215

210

205

200

195

190
-1.20 -1.00 -0.80 -0.60 -0.40 -0.20 0.00

x1 y1

X1
Y1

1.2
1.2
 A B C
Diketahui : Metanol = 16.5938 3644.3 -33.39
Etanol = 16.6758 3674.49 -46.7
Propanol = 16.0692 3448.66 -69.06
Air = 16.262 3799.89 -46.8

Ditanya : Neraca mol,L,V jika diketahui T = 330 dan P = 101,3 kPa

Menggunakan persamaan raoults dan tanki flash isobaric

Jawab :

v/f xi p sat xi*psat

Metanol 0.35
Etanol 0.3
Propanol 0.2
Air 0.15

ln⁡〖 (𝑃_1^𝑠𝑎𝑡)/𝑘𝑃𝑎 〗 709.94011 ln⁡〖 (𝑃_

=A−𝐵/(𝑇−𝐶) = =A−𝐵/(

ln⁡〖 (𝑃_1^𝑠𝑎𝑡)/𝑘𝑃𝑎 〗 1013.71800

=A−𝐵/(𝑇−𝐶) =

ln⁡〖 (𝑃_1^𝑠𝑎𝑡)/𝑘𝑃𝑎 〗 1681.16351

=A−𝐵/(𝑇−𝐶) =

Bubble P

Bubble P
V/F 1360.41
Z P T psat K
Metanol 0.35 101.3 57.85 709.94011 2.151334
Ehanol 0.3 101.3 57.85 1013.717998 3.071873
Propanol 0.2 101.3 57.85 1681.163509 5.094435
Air 0.15 101.3 57.85 481.7215462 1.459762

L= -1359.41
 T = 330 K = 56.85
P = 101.3 kPa
Z1 = 0.35
Z2 = 0.3
Z3 = 0.2
Z4 = 0.15

ln⁡〖 (𝑃_1^𝑠𝑎𝑡)/𝑘𝑃𝑎 〗 481.7215461531

=A−𝐵/(𝑇−𝐶) =

- Feed
X1 Y1 Komponen mol frac mol
0.000223316 7.81606E-05 Metanol 0.35 35
0.0001063982 -2.348288E-08 Ethanol 0.3 30
3.5899488E-05 -5.2818175E-09 1-Propanol 0.2 20
0.0002394387 -2.6426473E-08 Air 0.15 15
0.0006050524 7.8105409E-05 1 100
0
c

Dew P
Vapor Liquid
mol frac mol mol frac mol
7.81606E-05 10.63305 0.000223316 -30.3578 54.7248
-2.3483E-08 -0.00319 0.000106398208 -14.4639 44.4671
-5.2818E-09 -0.00072 3.58994877E-05 -4.88021 24.8809
-2.6426E-08 -0.0036 0.000239438688 -32.5495 47.5531
7.81054E-05 136041 0.000605052383 -135941 0
F1=y1*P Methanol = P1 Sat
F2=y2*P Air = P2 sat

gamma1= (𝑌1∗𝑃)/ 𝐺𝐸/𝑅𝑇

(𝑋1∗𝑃1 = 𝑋_1−
𝑠𝑎𝑡)

gamma2= (𝑦2∗𝑃)/ A12 A21

(𝑋2∗𝑃2
𝑠𝑎𝑡) -0.7566 -1.1791

P x1 y1 x2 y2 Gamma 1 Gamma 2
15.79 0 0 1 1 1
17.51 0.0932 0.1794 0.9068 0.8206 0.48594105024 1.003515343783
18.15 0.1248 0.2383 0.8752 0.7617 0.49966278225 1.000394155813
19.3 0.1757 0.3302 0.8243 0.6698 0.52294201018 0.993196138478
19.89 0.2 0.3691 0.8 0.6309 0.52922426471 0.99339779924
21.37 0.2626 0.4628 0.7374 0.5372 0.54299279409 0.985950843497
24.95 0.3615 0.6184 0.6385 0.3816 0.6153506232 0.944356305325
29.82 0.475 0.7552 0.525 0.2448 0.68354470952 0.880597846738
34.8 0.5555 0.8378 0.4445 0.1622 0.75670473622 0.804222461426
42.1 0.6718 0.9137 0.3282 0.0863 0.8255371786 0.701087436838
60.38 0.878 0.986 0.122 0.014 0.97761177364 0.438812695315
65.39 0.9398 0.9945 0.0602 0.0055 0.99763482218 0.378351452515
69.36 1 1 0 0 1

P x1 y1 x2 y2 ganma1 ganma2
15.79 0 0 1 1 1 1
17.51 0.0932 0.1794 0.9068 0.8206 0.88449188205 0.997371860022
18.15 0.1248 0.2383 0.8752 0.7617 0.85804147124 0.995456145704
19.3 0.1757 0.3302 0.8243 0.6698 0.82596427509 0.991534346521
19.89 0.2 0.3691 0.8 0.6309 0.81464340611 0.989365747751
21.37 0.2626 0.4628 0.7374 0.5372 0.7955718249 0.983154451736
24.95 0.3615 0.6184 0.6385 0.3816 0.78974970186 0.972507481933
29.82 0.475 0.7552 0.525 0.2448 0.81084004592 0.961197679721
34.8 0.5555 0.8378 0.4445 0.1622 0.83879835967 0.955207708778
42.1 0.6718 0.9137 0.3282 0.0863 0.89056718018 0.951717104779
60.38 0.878 0.986 0.122 0.014 0.97928755906 0.969067135687
65.39 0.9398 0.9945 0.0602 0.0055 0.99456000479 0.9823927258
69.36 1 1 0 0 1 1
 in gamma 1 in gamma 2 GE/RT GE/RT.X1.X2
0 0
-0.72166795824 0.0035091794 -0.0640773298237 -0.75818813201
-0.69382184359 0.0003940782 -0.0862440688796 -0.78960037046
-0.64828470027 -0.006827113 -0.1195312113434 -0.82532359147
-0.63634299612 -0.006624092 -0.132567872578 -0.82854920361
-0.61065922969 -0.01414878 -0.1707924241532 -0.882004392
-0.4855630546 -0.057251742 -0.2120862814849 -0.91884736544
-0.38046321234 -0.127154231 -0.2474759970754 -0.99238495068
-0.27878214626 -0.217879355 -0.2517108554374 -1.01940349218
-0.19172097896 -0.355122668 -0.2453494133492 -1.11277266215
-0.02264264723 -0.823682619 -0.1203695237955 -1.12373057055
-0.00236797927 -0.971931747 -0.0607357180771 -1.07352518768
0 0

y1 y2 Pmargules Error
0 1 15.79 0
0.326537228254 0.6734627717 19.9984081808538 2.488408180854
0.409218556714 0.5907814433 21.1839314279628 3.033931427963
0.521536610804 0.4784633892 22.9711672079309 3.671167207931
0.568161555033 0.431838445 23.7984014552051 3.908401455205
0.678076476467 0.3219235235 25.9378983859861 4.567898385986
0.793663315211 0.2063366848 29.6066374842309 4.656637484231
0.895839575882 0.1041604241 34.6820246182796 4.86202461828
0.928691512151 0.0713084878 39.022737984111 4.222737984111
0.985674847388 0.0143251526 46.4289736893712 4.328973689371
0.987690164208 0.0123098358 61.5035236637141 1.123523663714
0.991434844473 0.0085651555 65.7637457447656 0.373745744766
1 0 69.36 0
37.23744984241
 Chart Title
0.2
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
-0.2
Column H
-0.4 Column I
Axis Title Column J
-0.6 Column K
-0.8
-1
-1.2
Axis Title

Chart Title
70
60
50
40 Column A
Axis Title Column A
30
20
10
0
0 0.2 0.4 0.6 0.8 1 1.2
Axis Title