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MDMW-Wollastonite04

MDMW-Wollastonite04

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Published by miningnova
This paper deals the study of use of wollastonite for the treatment of tailing wastes enriched in Mn(II) and Zn(II). The efficiency of wollastonite was tested at different concentrations and temperatures at suitable pH of the system.
This paper deals the study of use of wollastonite for the treatment of tailing wastes enriched in Mn(II) and Zn(II). The efficiency of wollastonite was tested at different concentrations and temperatures at suitable pH of the system.

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05/11/2014

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226 
 
Mineral Processing Technology (MPT 2007)
Use of Wollastonite for Tailing Waste ManagementEnriched in Mn (II) and Zn (II)
 A.K. Singh, S. Gupta, R.P. Singh
and
N.C. Karmakar 
Department of Mining Engineering, Institute of Technology,Banaras Hindu University, Varanasi-221005, India
ABSTRACT:
This paper deals the study of use of wollastonite for the treatment of tailing wastes enriched inMn(II) and Zn(II). The efficiency of wollastonite was tested at different concentrations and temperatures atsuitable pH of the system. It was found that low concentration favors the uptake of adsorbate species.However effect of temperature varies with the nature of adsorbate Species The process of uptake follows afirst order adsorption rate kinetics and obeys Langmuir model of adsorption isotherm. The removal processhas also been found to be partially diffusion controlled and mass transfer co-efficient have been determinedto explain the mechanism of adsorption. The effect of pH has been discussed incorporating various surfacesite reactions. A generalized empirical models is proposed for different initial concentrations andtemperatures
1. INTRODUCTION
Rapid industrialization is posing problems, suchas environmental pollution, which is threateningthe very existence of living beings. The presenceof heavy metals in the environment, released by polluting industries, is of major concern becauseof its toxicity and threat to the environment.Anthropogenic of heavy metals include wastesfrom the electroplating and metal finishingindustries, metallurgical industry, chemical and battery manufacturing industries, mining andmineral processing industry, acid mine drainageand leachates from land filled by mine wastes .”(Singh et al, 2004 & 2006).The present investigation is aimed to developa suitable and economic method for the treatmentof mine tailing wastes enriched in Mn(II) andZn(II) prior to their discharge in the environment.An environment friendly adsorption techniqueemployed in the present study is considered as anadvanced method for water treatment due to itssimplicity, ease in handling and economicviability (Qiming et al, 1999 and Inow et al. 2004).Some conventional adsorbents have beenutilized for the removal of heavy metals in past(Adams et al 2005, Melegy et al 2005 and Akar etal 2005). However many of these, such asactivated carbon, activated alumina and activatedsilica etc are very costly. Keeping the above factsthe utility of wollastonite a clay mineral has beentested as unconventional adsorbent for thetreatment of mine tailing waste enriched in Mn(II)and Zn(II).
2. MATERIAL AND METHODS2.1 Physico Chemical Analysis of Adsorbent
Wollastonite was obtained from m/s Wolkem,Udaipur, Rajsthan. It was used as such after grinding and sieving through 53, 75 and 125
µ
m pore size sieves. All the chemicals used were of analytical reagent grade, and were obtained fromB.D.H. Bombay. The average particle size wasmeasured by HiAC 320, Model- 8002917 (RoycoInstruments , Div. USA) and surface charge bylaser zee meter, model- 500 (Peutem, Ine N.Y.,USA) the surface area was measured by a triple point Nitrogen gas adsorption method usingquantasorb surface area analyser, model Qs - 7(Quantachrome corp. USA) and porosity bymercury porosimeter. The India standard method(1960) were applied to analyze the adsorbentchemically
2.2 Method
 
227 
 
Mineral Processing Technology (MPT 2007)
Batch adsorption experiments were run byshaking 1.0 g of adsorbent with 50ml. aqueoussolution of laboratory prepared waste containingknown concentration of MnSO
4
and ZnCl
2
solutions in different glass bottles kept in atemperature controlled shaking water bath with aconstant speed of 125 rpm at the end of pre-selected time intervals the bottles were taken outfrom the shaker and reaction mixtures werecentrifuged at 1500 rpm, The progress of adsorption was assessed by determining theconcentration of adsorbate species e.g. Mn (II)and Zn(II) by spectrophotometric method usingspectrophotometer and also confirmed sometimes atomic absorption spectrophotometer.
3. RESULTS AND DISCUSSION3.1 Characterization of Adsorbent
The chemical analysis of wollastonite indicatesthe presence of mainly silica and calcium oxideand with trace amounts of other oxides in theform of impurities Table 1. It was thus expectedthat the adsorbate species will be removed mainly by SiO
2
and/or CaO . Infra red, x-ray diffractionand Scanning Electron Microscope (SEM) of wollastonite also support chemical and physicalanalysis results and prove its utility as anadsorbent for waste water treatments.
Table 1:
Chemical and physical characteri
zationof wollastonite
Constituents% by Weigh
SiO
2
48.42Al
2
O
3
0.24Fe
2
O
3
0.26CaO48.48Loss an ignition2.50Menu Particle diameter (m)48 x 10
-4
Surface area (m
2
g
-1
)1.18Porosity (Ep)0.23Density (P
p
) (g cm
-3
)2.60P
H
zpc2.60
3.2 Effect of Contact Time andAdsorbate Concentration
It has been found that the removal of Mn(II) andZn(II) increases with the lapse of time and attainsequilibrium in 100 and 130 min. respectively bywollastonite. It is inferred from Table 2 that the percentage removal of aforesaid pollutantsdecreases with increase of initial concentrations.The maximum removal at low concentration isdue to the fact that parking space at the surface of adsorbent is constant for all the initial adsorbentconcentration while the number of adsorbingspecies are less in low initial concentration rangein comparison to higher concentration range. Thefollowing correlations have been developed between percentage removal and initial adsorbateconcentration (Co) to predict successfully, the percentage removal of various pollutants bywollastonite at any initial concentration .
Table 2:
Experimental and Model values for Mn (II) and Zn (II) removal by wollastonite atdifferent initial concentrations
   A   d  s  o  r   b  a   t  e   S  p  e  c   i  e   C  o  n  c  n .  m  g   /   l   E  x  p  e  r  m .   V  a   l  u  e  s   M  o   d  e   l   V  a   l  u  e  s   %   e  r  r  o  r
Mn(II)1080.0081.241.552065.0063.302.623053.3354.702.57Zn(II)1062.0062.130.211553.3351.553.342045.0045.160.36
For Mn (II) - Wollastonite,% removal = 186.11 Co.
-0.32
...(1)for Zn (II) - Wollastonite ,% removal = 179.17 Co
-0.46
…(2)The experimental and model values(calculated by above relationships ) of percentageremoval of different initial concentrations arerecorded in Table 2 along with percentage error.Table 2 depicts that the model values are in goodagreement with those of experimental showingthe validity of the above model. These results will be helpful during the fabrication of a treatment plant for the treatment of tailing wastes enrichedin Mn(II) and Zn(II).
 
Use of Wollastonite for Tailing Waste Management Enriched in Mn (II) and Zn (II)
228
4. ADSORPTION DYNAMICS
The dynamics or adsorption is studied byconsidering the following steps:
4.1 Study of Rate Constant
The adsorption or Mn (II) and Zn(II) from liquid phase to solid phase can be considered asreversible reaction (Yadav et al., 1991) with anequilibrium being established between two phases. A simple first order reversible reactionkinetic model was therefore used to establish therates or reaction which can be expressed as: 
1 
S
 
A
2
 the rate equation for the above reaction may beexpressed as:ln [1-u(t)] =
/
t …(3)Where K 
/
is overall rate constant and u(t)= q/q
e
isthe fractional attainment of equilibrium. Further 
21
 K  K  K 
ae sec
==
… (4)
21/
 K  K  K 
+=
…(5)In which C
Ae
(mgl-
1
) and C
Se
(mgl-1) are theequilibrium concentration of Mn (II) and Zn(II)on the adsorbet and solution respectively, q and qe both in (mgg-1) are the amount of adsorbate attime t and at equilibrium respectively,
1
and K 
2
are the rate constants of adsorption and desorptionrespectively, and K 
c
is the equilibrium constant.The straight line plot of ln (1- u(t)) vs t prove thevalidity of this kinetic model. The values of K 
/
, K 
1
and K 
2
were calculated from the slopes of therespective plots and given in Table 3.
Table 3:
Kinetic parameters for theRemoval of Mn (II) and Zn (II) byadsorption on wollastonite
   A   d  s  o  r   b  a   t  e   K  x   1   0
   3
   K
   1
  x   1   0
   3
   K
   2
  x   1   0
  -   3
   K
   i   d
      β
   l
  x   1   0
  -   5
Mn (II)383010.0201.78.60Zn (II)271710.30.0161.33
Units of K
/
, K
1
& K
2
are (min
-1
)Units of Kid are (mg.g
-1
. min
0.5
)Unirts of 
β
l
are (cm . Sec
-1
)
4.2 Intra Particle Diffusion Study
Due to porous nature of the adsorbent porediffusion is also expected in addition to surfaceadsorption. This possibility was tested in terms of a graphical relationship between amount of adsorbate vs Square root or time (Singh et al,2004 & 2006 )The dual nature or these plots mayexplained on the basic of the fact that the initialcurved portion are due to surface adsorption whilethe linear portions are due to intra-particlediffusion effect. The rate constant of intra-particlediffusion kid was calculated from the slopes of linear portion of respective plots and values are presented in Table 3.
4.3 Mass Transfer Coefficient Study
The mass transfer analysis for the adsorption of these pollutants species follows three consecutivesteps: First adsorbates migrates from solution tothe exterior surface of the adsorbent particles(surface adsorption). Secondly, the adsorbatespecies move into the pores of adsorbent particlesand lastly they are adsorbed at sites on interior surface of the adsorbent particles. By the abovefacts Mckay and co-workers have proposed amodel for mass transfer study, (Singh et al, 2004& 2006).
mk mk mk mk mk 
 s
β 
     ++=      +
11ln11ln
0
…(6)

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