B TI NGUYN V

MI TRNG
------S: 47/2011/TT-BTNMT

CNG HA X HI CH NGHA VIT NAM

c lp - T do - Hnh phc
--------------H Ni, ngy 28 thng 12 nm 2011

THNG T
QUY NH QUY CHUN K THUT QUC GIA V MI TRNG
B TRNG B TI NGUYN V MI TRNG
Cn c Lut Tiu chun v Quy chun k thut ngy 29 thng 6 nm 2006;
Cn c Ngh nh s 127/2007/N-CP ngy 01 thng 8 nm 2007 ca Chnh ph quy nh chi
tit thi hnh mt s iu ca Lut Tiu chun v Quy chun k thut;
Cn c Ngh nh s 25/2008/N-CP ngy 04 thng 3 nm 2008 ca Chnh ph quy nh chc
nng, nhim v, quyn hn v c cu t chc ca B Ti nguyn v Mi trng, c sa
i, b sung ti Ngh nh s 19/2010/N-CP ngy 05 thng 3 nm 2010 ca Chnh ph v Ngh
nh s 89/2010/N-CP ngy 16 thng 8 nm 2010 ca Chnh ph;
Theo ngh ca Tng cc trng Tng cc Mi trng, V trng V Khoa hc v Cng ngh,
V trng V Php ch,
QUY NH:
iu 1. Ban hnh km theo Thng t ny quy chun k thut quc gia v mi trng: QCVN
40:2011/BTNMT - Quy chun k thut quc gia v nc thi cng nghip.
iu 2. Thng t ny c hiu lc thi hnh t ngy 15 thng 02 nm 2012.
iu 3. Tng cc trng Tng cc Mi trng, Th trng cc n v thuc B Ti nguyn v
Mi trng, Gim c S Ti nguyn v Mi trng cc tnh, thnh ph trc thuc Trung ng
v cc t chc, c nhn c lin quan c trch nhim thi hnh Thng t ny.

KT. B TRNG
TH TRNG
Ni nhn:
- Vn phng Trung ng v cc Ban ca ng;
- Vn phng Quc hi;
- Vn phng Ch tch nc;
- Vn phng Chnh ph;
- Ta n nhn dn ti cao;
- Vin Kim st nhn dn ti cao;

Bi Cch Tuyn

CNG HA X HI CH NGHA VIT NAM

QCVN 40:2011/BTNMT

QUY CHUN K THUT QUC GIA V

NC THI CNG NGHIP
National Technical Regulation on Indus trial Wastewater

H NI - 2011

Li ni u
QCVN 40:2011/BTNMT do Ban son tho quy chun k thut quc gia v cht l ng nc
bin son thay th QCVN 24:2009/BTNMT, Tng cc Mi trng, V Khoa hc v Cng ngh,
V Php ch trnh duyt v c ban hnh theo Thng t s 47/2011/TT-BTNMT ngy 28 thng
12 nm 2011 ca B trng B Ti nguyn v Mi trng.

QUY CHUN K THUT QUC GIA

V NC THI CNG NGHIP
National Technical Regulation on Industrial Wastewater
1. QUY NH CHUNG
1.1. Phm vi iu chnh
Quy chun ny quy nh gi tr ti a cho php ca cc thng s nhim trong nc thi cng
nghip khi x ra ngun tip nhn nc thi.
1.2. i tng p dng
1.2.1. Quy chun ny p dng i vi t chc, c nhn lin quan n hot ng x nc thi
cng nghip ra ngun tip nhn nc thi.
1.2.2. Nc thi cng nghip ca mt s ngnh c th c p dng theo quy chun k thut
quc gia ring.
1.2.3. Nc thi cng nghip x vo h thng thu gom ca nh my x l nc thi tp trung
tun th theo quy nh ca n v qun l v vn hnh nh my x l nc thi tp trung.
1.3. Gii thch thut ng
Trong Quy chun ny, cc thut ng di y c hiu nh sau:
1.3.1. Nc thi cng nghip l nc thi pht sinh t qu trnh cng ngh ca c s sn xut,
dch v cng nghip (sau y gi chung l c s cng nghip), t nh my x l nc thi tp
trung c u ni nc thi ca c s cng nghip.
1.3.2. Ngun tip nhn nc thi l: h thng thot nc th, khu dn c; sng, sui, khe,
rch; knh, mng; h, ao, m; vng nc bin ven b c mc ch s dng xc nh.
2. QUY NH K THUT

2.1. Gi tr ti a cho php ca cc thng s nhim trong nc thi cng nghip khi x vo
ngun tip nhn nc thi
2.1.1. Gi tr ti a cho php ca cc thng s nhim trong n c thi cng nghip khi x vo
ngun tip nhn nc thi c tnh ton nh sau:
Cmax = C x Kq x Kf
Trong :
- Cmax l gi tr ti a cho php ca thng s nhim trong n c thi cng nghip khi x vo
ngun tip nhn nc thi.
- C l gi tr ca thng s nhim trong nc thi cng nghip quy nh ti Bng 1 ;
- Kq l h s ngun tip nhn nc thi quy nh ti mc 2.3 ng vi lu lng dng chy ca
sng, sui, khe, rch; knh, mng; dung tch ca h, ao, m; mc ch s dng ca vng nc
bin ven b;
- Kf l h s lu lng ngun thi quy nh ti mc 2.4 ng vi tng lu lng nc thi ca cc
c s cng nghip khi x vo ngun tip nhn nc thi;
2.1.2. p dng gi tr ti a cho php Cmax = C (khng p dng h s Kq v Kf) i vi cc
thng s: nhit , mu, pH, coliform, Tng hot phng x , Tng hot phng x .
2.1.3. Nc thi cng nghip x vo h thng thot nc th, khu dn c cha c nh my x
l nc thi tp trung th p dng gi tr Cmax = C quy nh ti ct B Bng 1.
2.2. Gi tr C ca cc thng s nhim trong nc thi cng nghip c quy nh ti Bng 1
Bng 1: Gi tr C ca cc thng s nhim trong nc thi cng nghip
TT

Thng s

n v

Gi tr C
A

oC

40

40

Pt/Co

50

150

6 n 9

5,5 n 9

Nhit

Mu

pH

BOD5 (20oC)

mg/l

30

50

COD

mg/l

75

150

Cht rn l lng

mg/l

50

100

Asen

mg/l

0,05

0,1

Thu ngn

mg/l

0,005

0,01

Ch

mg/l

0,1

0,5

10

Cadimi

mg/l

0,05

0,1

11

Crom (VI)

mg/l

0,05

0,1

12

Crom (III)

mg/l

0,2

13

ng

mg/l

14

Km

mg/l

15

Niken

mg/l

0,2

0,5

16

Mangan

mg/l

0,5

17

St

mg/l

18

Tng xianua

mg/l

0,07

0,1

19

Tng phenol

mg/l

0,1

0,5

20

Tng du m khong

mg/l

10

21

Sunfua

mg/l

0,2

0,5

22

Florua

mg/l

10

23

Amoni (tnh theo N)

mg/l

10

24

Tng nit

mg/l

20

40

25

Tng pht pho (tnh theo P )

mg/l

26

Clorua

mg/l

500

1000

(khng p dng khi x vo

ngun nc mn, nc l)
27

Clo d

mg/l

28

Tng ho cht bo v thc vt

clo hu c

mg/l

0,05

0,1

29

Tng ho cht bo v thc vt

pht pho hu c

mg/l

0,3

30

Tng PCB

mg/l

0,003

0,01

31

Coliform

vi khun/100ml

3000

5000

32

Tng hot phng x

Bq/l

0,1

0,1

33

Tng hot phng x

Bq/l

1,0

1,0

Ct A Bng 1 quy nh gi tr C ca cc thng s nhim trong nc thi cng nghip khi x

vo ngun nc c dng cho mc ch cp nc sinh hot;

Ct B Bng 1 quy nh gi tr C ca cc thng s nhim trong nc thi cng nghip khi x

vo ngun nc khng dng cho mc ch cp nc sinh hot;
Mc ch s dng ca ngun tip nhn nc thi c xc nh ti khu vc tip nhn nc thi.
2.3. H s ngun tip nhn n c thi Kq
2.3.1.H s Kq ng vi l u lng dng chy ca sng, sui, khe, rch; knh, mng c quy
nh ti Bng 2 di y:
Bng 2: H s Kq ng vi l u lng dng chy ca ngun tip nhn n c thi
Lu lng dng chy ca ngun tip nhn n c thi (Q)

H s Kq

n v tnh: mt khi/giy (m3/s)

Q 50

0,9

50 < Q 200

200 < Q 500

1,1

Q > 500

1,2

Q c tnh theo gi tr trung bnh lu lng dng chy ca ngun tip nhn nc thi 03 thng
kh kit nht trong 03 nm lin tip (s liu ca c quan Kh tng Thu vn).
2.3.2. H s Kq ng vi dung tch ca ngun tip nhn nc thi l h, ao, m c quy nh
ti Bng 3 di y:
Bng 3: H s Kq ng vidung tch ca ngun tip nhn nc thi
Dung tch ngun tip nhn nc thi (V)

H s Kq

n v tnh: mt khi (m3)

V 10 x 106

0,6

10 x 106 < V 100 x 106

0,8

V > 100 x 106

1,0

V c tnh theo gi tr trung bnh dung tch ca h, ao, m tip nhn nc thi 03 thng kh
kit nht trong 03 nm lin tip (s liu ca c quan Kh tng Thu vn).
2.3.3. Khi ngun tipnhn nc thi khng c s liu v lu lng dng chy ca sng, sui,
khe, rch, knh, mng th p dng Kq = 0,9; h, ao, m khng c s liu v dung tch th p
dng Kt qu = 0,6.

2.3.4. H s Kq i vi ngun tip nhn nc thi l vng nc bin ven b, m ph nc mn

v nc l ven bin.
Vng nc bin ven b dng cho mc ch bo v thu sinh, th thao v gii tr di nc, m
ph nc mn v nc l ven bin p dng Kq = 1.
Vng nc bin ven b khng dng cho mc ch bo v thu sinh, th thao hoc gii tr di
nc p dng Kq = 1,3.
2.4. H s lu lng ngun thi Kf
H s lu lng ngun thi Kf c quy nh ti Bng 4 di y:
Bng 4: H s lu lng ngun thi Kf
Lu lng ngun thi (F )

H s Kf

n v tnh: mt khi/ng y m (m3/24h)

F 50

1,2

50 < F 500

1,1

500 < F 5.000

1,0

F > 5.000

0,9

Lu lng ngun thi F c tnh theo lu lng thi ln nht nu trong Bo co nh gi tc

ng mi trng, Cam kt bo v mi trng hoc n bo v mi trng.
3. PHNG PHP XC NH
3.1. Ly mu xc nh cht lng nc thi p dng theo hng dn ca cc tiu chun quc
gia sau y :
- TCVN 6663-1:2011 (ISO 5667-1:2006) Cht lng nc Phn 1: Hng dn lp chng
trnh ly mu v k thut ly mu;
- TCVN 6663-3:2008 (ISO 5667-3: 2003) - Cht lng nc - Ly mu. Hng dn bo qun v
x l mu;
- TCVN 5999:1995 (ISO 5667 -10: 1992) - Cht lng nc - Ly mu. Hng dn ly mu
nc thi.
3.2. Phng php xc nh gi tr cc thng s kim sot nhim trong nc thi cng nghip
thc hin theo cc tiu chun quc gia v quc t sau y:
- TCVN 4557:1988 Cht lng nc - Phng php xc nh nhit ;

- TCVN 6492:2011 (ISO 10523:2008) Cht lng nc - Xc nh pH ;

- TCVN 6185:2008 - Cht lng nc - Kim tra v xc nh mu sc;
- TCVN 6001-1:2008 (ISO 5815-1:2003), Cht lng nc Xc nh nhu cu oxy sinh ha sau
n ngy (BODn) Phn 1: Phng php pha long v cy c b sung allylthiourea ;
- TCVN 6001-2:2008 (ISO 5815-2:2003), Cht lng nc Xc nh nhu cu oxy sinh ha sau
n ngy (BODn) Phn 2: Phng php dng cho m u khng pha long;
- TCVN 6491:1999 (ISO 6060:1989) Cht lng nc - Xc nh nhu cu oxy ho hc (COD) ;
- TCVN 6625:2000 (ISO 11923:1997) Cht lng nc - Xc nh cht rn l lng bng cch
lc qua ci lc si thu tinh;
- TCVN 6626:2000 Cht lng nc - Xc nh asen - Phng php o ph hp th nguyn t
(k thut hydro);
- TCVN 7877:2008 (ISO 5666:1999) Cht lng nc - Xc nh thu ngn;
- TCVN 6193:1996 Cht lng nc - Xc nh coban, niken, ng, km, cadimi v ch. Phng
php trc ph hp th nguyn t ngn la;
- TCVN 6222:2008 Cht lng nc - Xc nh crom - Phng php o ph hp th nguyn t;
- TCVN 6658:2000 Cht lng nc Xc nh crom ha tr su Phng php trc quang
dng 1,5 diphenylcacbazid ;
- TCVN 6002:1995 Cht lng nc Xc nh mangan Phng php trc quang dng
formaldoxim;
- TCVN 6177:1996 Cht lng nc Xc nh st bng phng php trc ph dng thuc th
1,10- phenantrolin;
- TCVN 6665:2011 (ISO 11885:2007) Cht lng nc- Xc nh nguyn t chn lc bng ph
pht x quang Plasma cp cm ng ( ICP-OES) ;
- TCVN 6181:1996 (ISO 6703 -1:1984) Cht lng nc - Xc nh xianua tng;
- TCVN 6494-1:2011 (ISO 10304 -1:2007) Cht lng nc Xc nh cc anion ha tan bng
phng php sc k lng ion Phn 1: Xc nh bromua, clorua, florua, nitrat, nitr it, phosphat
v sunphat ha tan;
- TCVN 6216:1996 (ISO 6439:1990) Cht lng nc - Xc nh ch s phenol - Phng php
trc ph dng 4-aminoantipyrin sau khi chng ct;

- TCVN 6199-1:1995 (ISO 8165/1:1992) Cht lng nc- Xc nh cc phenol n ho tr la

chn. Phn 1: Phng php sc k kh sau khi lm giu bng chit;
- TCVN 5070:1995 Cht lng nc - Phng php khi lng xc nh du m v sn phm
du m;
- TCVN 7875:2008 Nc Xc nh du v m Phng php chiu hng ngoi;
- TCVN 6637:2000 (ISO 10530:1992) Cht lng nc-Xc nh sunfua ho tan- Phng php
o quang dng metylen xanh ;
- TCVN 5988:1995 (ISO 5664:1984) Cht lng nc - Xc nh amoni - Phng php chng
ct v chun ;
- TCVN 6620:2000 Cht lng nc - Xc nh amoni - Phng php in th;
- TCVN 6638:2000 Cht lng nc - Xc nh nit - V c ha xc tc sau khi kh bng hp
kim Devarda;
- TCVN 6202:2008 (ISO 6878:2004) Cht lng nc - Xc nh pht pho - Phng php o ph
dng amoni molipdat ;
- TCVN 8775:2011 Cht lng nc - Xc nh coliform tng s - K thut mng lc;
- TCVN 6187-1:2009 (ISO 9308-1: 2000) Cht lng nc - Pht hin v m escherichia coli
v vi khun coliform. Phn 1: Phng php lc mng;
- TCVN 6187-2:1996 (ISO 9308 -2:1990(E)) Cht lng nc - Pht hin v m vi khun
coliform, vi khun coliform chu nhit v escherichia coli gi nh. Phn 2: Phng php nhiu
ng (s c xc sut cao nht);
- TCVN 6225-3:2011 (ISO 7393-3:1990) Cht lng nc - Xc nh clo t do v clo tng s.
Phn 3 Phng php chun iot xc nh clo tng s ;
- TCVN 7876:2008 Nc Xc nh hm lng thuc tr su clo hu c - Phng php sc k
kh chit lng-lng;
- TCVN 8062:2009 Xc nh hp cht phospho hu c bng sc k kh - K thut ct mao qun;
- TCVN 6053:2011 Cht lng nc - o tng hot phng x anpha trong nc khng mn Phng php ngun dy;
- TCVN 6219:2011 Cht lng nc - o tng hot phng x beta trong nc khng mn.

3.3. Chp nhn cc phng php phn tch hng dn trong cc tiu chun quc gia v quc t
c chnh xc tng ng hoc cao hn cc tiu chun vin dn mc 3.2. v cc tiu chun
quc gia, quc t mi ban hnh nhng cha c vin dn trong quy chun ny.
4. T CHC THC HIN
4.1. Quy chun ny p dng thay th QCVN 24:2009/BTNMT - Quy chun k thut quc gia v
nc thi cng nghip ban hnh km theo Thng t s 25/2009/TT-BTNMT ngy 16 thng 11
nm 2009 ca B trng B Ti nguyn v Mi trng quy nh Quy chun k thut quc gia v
mi trng.
4.2. UBND cc tnh, thnh ph trc thuc trung ng cng b mc ch s dng ngun nc v
H s Kq trong quy hoch s dng ngun nc v phn vng tip nhn nc thi.
4.3. C quan qun l nh nc v mi trng cn c vo c im, tnh cht ca nc thi cng
nghip v mc ch s dng ca ngun tip nhn la chn cc thng s nhim c trng v
gi tr c bn (gi tr C) quy nh ti Bng 1 trong vic kim sot nhim mi trng.
4.4. Trng hp cc tiu chun quc gia vin dn trong Quy chun ny sa i, b sung hoc
thay th th p dng theo tiu chun mi.