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Presentation outline
Surfactant
Surfactants are compounds that stabilize mixtures of oil and water by reducing the surface tension at the interface between the oil and water molecules. Surfactants are amphiphilic in nature i.e.; they contain 2 distinct structural units:
Tail or hydrophobic group which has little affinity for water this group is usually hydrocarbon (alkyl) chain Head or hydrophilic group which has strong affinity for water & can be neutral or charged.
Surfactants - behavior
Surfactants reduce the surface tension of water by adsorbing at the liquid-gas interface. They also reduce the interfacial tension between oil and water by adsorbing at the liquid-liquid interface. At higher concentrations surfactants have the tendency to assemble into aggregates. Examples of such aggregates are vesicles and micelles. The concentration at which surfactants begin to form micelles is known as the critical micelle concentration or CMC.
Surfactant- micelle
In a micelle : The lipophilic tails of the surfactant molecules remain on the inside of the micelle The polar heads of the micelle form a hydrophilic outer layer that in effect protects the hydrophobic core of the micelle.
The Cloud point of a fluid is the temperature at which dissolved solids are no longer completely soluble, precipitating as a second phase giving the fluid a cloudy appearance. The pour point of a liquid is the lowest temperature at which it will pour or flow under prescribed conditions.
HLB Value
10
11
12
13
14
15
16
17
18
Solubilizer
The Properties
Properties of Surfactants
Wetting Emulsification Dispersion / Solubilisation Foaming / De-foaming Detergency Conditioning Substantivity Thickening
Wetting
Emulsification
Surfactant Classification
Surfactant classes
Surfactants are broadly classified into the following four groups based on the ionic charges they carry: Anionic surfactants Nonionic surfactants Cationic surfactants Amphoteric surfactants
Surfactant grouping
Anionic
Fatty alcohol sulfates
Fatty alcohol ether sulfates Lauryl alcohol ethoxylates Sulfosuccinates Amides Betaines
Amphoteric
The Applications
The Applications
Oral Skin Sodium Lauryl Sulfate Ammonium Lauryl Sulfate Sodium Lauryl Ether Sulfate Ammonium Lauryl Ether Sulfate Alcohol ethoxylates Sulfosuccinate Ethanolamides Amine oxide Hair Soap Bath Sun Disinfectant/ protection Bleaching
The Applications
Oral Skin Hair Soap Bath Disinfectant/ Bleaching Benzalkonium chloride
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Edwin Powell Hubble