CBSE TEST PAPER-04 CLASS - XI CHEMISTRY [ANSWERS]

Topic: - Mole concept, percentage composition 1mole = 6.022 1023 atoms/ ions / entities

Ans1:

Ans2:

22.4 Litres.

Ans3:

The

number

of

molecules

present

in

0.5

moles

of

C02

is

6.022 1023 0.5 = 3.011 1023.

Ans4:

(i)

Same molecular formula and empirical formula. Carbon dioxide, both is CO2.

(ii) When molecular formula and empirical formula are different Hydrogen peroxide: molecular formula is H2O2 and empirical formula is HO

Ans5:

22.4 L of the gas at STP will weigh

= 1.97 22.4 = 44.1g

i.e. molecular mass = 44.1

Ans6: Molecular formula CO Na2CO3 KCl C6H12 H2O2 H3PO4 Fe2O3 N2O4 Empirical formula CO Na2CO3 KCl CH6 HO H3PO4 Fe2O3 NO2

Material downloaded from http://myCBSEguide.com and http://onlineteachers.co.in Portal for CBSE Notes, Test Papers, Sample Papers, Tips and Tricks

Ans7

(i) 7.85g of Fe 56g of Fe contains 6.022 1023 atoms = 1mole 56g of Fe = 1mole 7.85g of Fe =
1 7.85 = 0.14moles 56

(ii) 40g of Ca = 40 103 mg of Ca 40g of Ca = 1mole Or 4 102 mg of Ca = 1mole 7.9mg of Ca =

1 7.9moles 4 102

= 1.97 10 2 moles

Ans8:

Percentage of carbon =

12 100 0.02998 = 47.69 44 0.2 2 100 0.0819 = 4.55 18 0.2

Percentage of Hydrogen =

Percentage of oxygen = 100 ( 47.69 + 4.55) = 47.76

Element

Atomic Mass

Relative no. of atoms

Simplest Ratio
3.97 = 1.33 2.98 4.55 = 1.5 2.98 2.98 =1 2.98

C H O

47.69 4.55 47.76

12 1 16

47.69 = 3.97 12 4.55 = 4.55 1 47.76 = 2.98 15

Empirical formula = C1.33 H1.5 O, = C8H9O6

Material downloaded from http://myCBSEguide.com and http://onlineteachers.co.in Portal for CBSE Notes, Test Papers, Sample Papers, Tips and Tricks