Ngy son:. HIRO SUNFUA Tit : 69 (Ban nng cao) I- MC TIU - HS bit: Cu to phn t, tnh cht vt l c bn ca H2S.

Trng thi t nhin. ng dng v phng php iu ch H2S. - HS hiu: V sao H2S c tnh kh mnh, dd H2S c tnh axit yu. - HS vn dng: Vit phng trnh phn ng minh ho tnh cht ho hc ca H2S. Gii thch nguyn nhn nhim mi trng khng kh v bin php chng nhim mi trng khng kh. II- CHUN B - Hc sinh: c bi trc. III- T CHC CC HOT NG DY HC 1. n nh lp, kim tra s s: 2. Bi mi Hot ng ca GV v HS Ni dung Hot ng 1: I. CU TO PHN T -HS: Biu din s hnh thnh lin kt trong phn S t H2S v d on tnh cht ho hc ca H2S? H H - S-2 v lin kt H- S phn cc yu: Tnh kh v tnh axit yu. - HS tm hiu SGK v nu tnh cht vt l c bn II. TNH CHT VT L ca H2S? - Kh khng mu, mi trng thi. - dH2S/kk = 1,17 Hot ng 2: - H2S rt c v tan khng nhiu trong nc. - GV thng bo: H2S tan trong nc cho dung III. TNH CHT HO HC dch axit yu sunfuhiric. Do l axit yu nn khi 1. Tnh axit yu phn ng vi kim c thay th tng gc axit. - Khng i mu ch th. - HS vit phng trnh H2S + NaOH? - H2S + NaOH NaHS + H2O - GV hi: Vy t mui suafua c thu hi c hoc H2S + 2NaOH Na2S + 2H2O H2S khng? 2. Tnh kh mnh Hot ng 3: H2S + O2 (kk) S + H2O - GV lm th nghim: H2S + O2? trong trng 0 SO2 + H2O H2S + O2 (d) t hp thiu v d oxi? - HS quan st v vit phng trnh phn ng, H2S + Cl2+ H2O HCl + H2SO4 H2S + 2FeCl3 2FeCl2 + 2HCl + S nu vai tr ca cc cht trong phn ng? 3Na2S + 2FeCl3 2FeS + 6NaCl + S - GV gii thiu thm vi cht. IV. TRNG THI T NHIN. IU CH Hot ng 4: - SGK - HS t tm hiu v rt ra cc kt lun? - Trong CN khng iu ch, trong PTN th: FeS + 2HCl FeCl2 + H2S V. TNH CHT CA MUI SUNFUA - Na2S; K2S (tan)- IA; IIA (tr Be) v ZnS; FeS

..(ko tan) c tc dng vi axit HCl v H2SO4 long H2S. - PbS; CuS khng tan trong axit mnh. - CdS c mu vng; Ag2S; CuS; FeS .. mu en. IV- CNG C, DN D - Chng minh H2S va c tnh kh; va c tnh axit yu. V- RT KINH NGHIM