BI TP L THUYT DN XUT HALOGEN-ANCOL-PHENOL (GIO VIN- L LIN-TRNG THPT M C A) Cu 1. Hp cht CH3CH2CHClCH3 l dn xut halogen bc a.1 b.2 c.3 d.

4 Cu 2. Khi thc hin phn ng th clo vo isobutan,s sn phm iclo ti a c th thu c l bao nhiu? a.1 b.2 c.3 d.4 Cu 3. Khi tch hiroclrua t cc ng phn ca C 4H9Cl th thu c ti a bao nhiu ng phn cu to ca anken? a.2 b.3 c.4 d.5 Cu 4.Cho 3 cht CH3CH2CH2Cl (1); CH2=CHCH2Cl (2) v phenyl clorua (3). un tng cht vi dd NaOH d,sau gn ly lp nc v axit ho bng dd HNO3 ,ri nh vo dd AgNO3 th cc cht c xut hin kt ta trng l: a.1,2 b.2,3 c.1,3 d.1,2,3 Cu5.X l dn xut clo ca metan trong phn t X clo chim 83,52% khi lng. X c cng thc phn t l a.CH3Cl b.CH2Cl2 c.CHCl3 d.CCl4. Cu 6. ng vi cng thc phn t C4H10O2 c bao nhiu ng phn bn c th ho tan c Cu(OH)2 ? a.2 b.3 c.4 d.5 Cu 7. C bao nhiu ng phn ancol bc 2 c cng cng thc phn t C5H12O ? a.2 b.3 c.4 d.5 Cu 8 .Cht hu c X c CTPT C4H10O . S lng cc ng phn ca X khng tc dng vi Na l: a.2 b.3 c.4 d.5 Cu 9.Khi cho cht X c CTPT C3H5Br3 tc dng vi dd NaOH d thu c cht hu c Y c phn ng vi Na v phn ng trng gng.Cng thc cu to thu gn ca X l a.CH2Br-CHBr-CH2Br b.CH2Br-CH2-CHBr2 c.CH2Br-CBr2-CH3 d.CH3-CH2-CBr3. Cu 10. C bao nhiu ng phn c cng CTPT C5H10O khi oxi ho bng CuO (to) to sn phm c phn ng trng gng? a.2 b.3 c.4 d.5 Cu 11. Ch dng cc cht no sau y c th phn bit hai ancol ng phn c cng CTPT C 3H7OH? a.CuO, dd AgNO3/NH3 b.Na, H2SO4 c c.Na, dd AgNO3/NH3 d.Na v CuO. Cu 12. Cho cc thuc th sau: Na; CuO (to); AgNO3/NH3 v qu tm.S thuc th c th dng phn bit hai ng phn khc chc c CTPT C3H8O l a.1 b.2 c.3 d.4 Cu 13. phn bit ancol etylic nguyn cht v ancol etylic c ln nc ,ngi ta dng thuc th no sau y? a.CuSO4 khan b.Na kim loi c.Benzen d.CuO Cu 14 .CHt hu c X mch h ,bn c ng phn hnh hc ,c CTPT C4H8O. X lm mt mu dd Brom v tc dng vi Na gii phng kh H2.Cng thc cu to ca X l a.CH2=CH-CH2-CH2-OH b.CH3-CH=CH-CH2-OH c.CH2=C(CH3)-CH2-OH d.CH3-CH2-CH=CH-OH Cu 15.Chiu gim linh ng ca nguyn t H(t tri qua phi ) trong nhm -OH ca 3 hp cht phenol, ancol etylic v nc l a.HOH, C6H5OH,C2H5OH. b.C6H5OH, HOH, C2H5OH c.C2H5OH, C6H5OH, HOH d. C2H5OH, HOH, C6H5OH Cu 16. Khi un nng ancol sec-butylic vi axit sunfuric c 180 0C th s ng phn cu to thu c l a.1 b.2 c.3 d.4 Cu 17. Cho s phn ng sau:
+HCl +NaOH, t0 H2SO4 dc,180 C +Br2 +NaOH, to

But-1-en X Y Z T K Bit X,Y,Z,T,K u l sn phm chnh ca tng giai on .Cng thc cu to thu gn ca K l a.CH3 CH(OH)CH(OH)CH3 B.CH3CH2CH(OH)CH3 c.CH3CH2CH(OH)CH2OH d.CH2(OH)CH2CH2CH2OH Cu 18.Cho dy chuyn ho sau:
H2SO4 c ,170 C H2O (H2SO4 long)

CH3CH2CH2OH X Y Bit X,Y u l sn phm chnh .Vy CTCT ca X ,Y ln lt l a. CH3CH=CH2 , CH3CH2CH2OH b.CH3CH=CH2,CH3CH2CH2OSO3H c. CH3CH=CH2,CH3CH(OH)CH3 d.C3H7OC3H7,CH3CH2CH2OSO3H Cu 19. Cho cc cht sau etylclorua, imetylete, ancol propylic,ancol etylic.cht c nhit si cao nht l: 1

a. etylclorua

b. imetylete

c. ancol propylic

d. ancol etylic

BI TP L THUYT DN XUT HALOGEN-ANCOL-PHENOL (GIO VIN- L LIN-TRNG THPT M C A) Cu 20.Phenol l nhng hp cht hu c m phn t ca chng c nhm hiroxyl a.lin kt vi nguyn t cacbon no ca gc hirocacbon. b.lin kt trc tip vi nguyn t cacbon ca vng benzen. c.gn trn nhnh ca hirocacbon thm. d.lin kt vi nguyn t cacbon no ca gc hirocacbon khng no. Cu 21.Trong cc cu sau cu no khng ng a.phenol cng c lin kt hiro lin phn t b.nhit si ca phenol thp hn nhit si ca toluen c.phenol c lin kt hiro vi nc c.phenol t tan trong nc lnh. Cu 22. Cu no sau y khng ng a.Phenol l cht rn ,tinh th khng mu c mi c trng b. lu ngoi khng kh ,phenol b oxi ho mt phn nn c mu hng c.phenol rt c ,gy bng nng i vi da d.phenol d tan trong nc lnh Cu 23. S ng phn thm c cng CTPT C7H8O va tc dng c vi Na va tc dng c vi NaOH a.1 b.2 c.3 d.4 Cu 24.Cho cht hu c X c CTPT C6H6O2. Bit X tc dng vi KOH theo t l mol 1:2 .S ng phn cu to ca X l a.1 b.2 c.3 d.4 Cu 25.Nguyn t H trong nhm OH ca phenol c th c thay th bng nguyn t Na khi cho a.Phenol tc dng vi Na b.phenol tc dng vi NaOH c.phenol tc dng vi NaHCO3 d.c A,B,C ng e.c A,B ng Cu 26. X l dn xut ca benzen khng phn ng vi NaOH c CTPT l C 7H8O.S ng phn ph hp ca X l a.2 b.3 c.4 d.5 Cu 27. Hp cht X tc dng vi Na nhng khng phn ng vi NaOH.X l cht no sau y? a.C6H5CH2OH b.HOCH2C6H4OH c.p-CH3C6H4OH d.C6H5OCH3 Cu 28.Cho s chuyn ho sau: Br2,Fe NaOH,t0cao,p cao HCl Toluen B C D .D l a.Benzylclorua b.m-metylphenol c.o-metylphenol v p-metylphenol d.o-metylphenol v p-clotoluen Cu 29.Trong s cc dn xut ca benzen c CTPT C8H10O c bao nhiu ng phn X tho mn X+NaOH Khng phn ng X -H2O Y xc tc Polime a.1 b.2 c.3 d.4 Cu 30.Pht biu no sau y ng (1).Phenol c tnh axit mnh hn etanol v nhn benzen ht electron ca nhm OH bng hiu ng lin hp ,trong khi nhm C2H5- y e vo nhm OH (2). Phenol c tnh axit mnh hn etanol v c minh ho bng phn ng phenol tc dng vi dung dch NaOH cn etanol th khng. (3).Tnh axit ca phenol yu hn H2CO3 v sc CO2 vo dd natriphenolat ta s thu c phenol (4).Phenol trong nc cho mi trng axit lm qu tm ho . a.1v 2 b.2 v 3 c.3 v 1 d.1,2 v 3 Cu 31.Cho 4 cht benzen,phenol, axitaxetic v ancol etylic. linh ng ca nguyn t H trong cc phn t trn gim theo th t a.Phenol>benzen>axit axetic>ancol etylic b.Axit axetic>phenol>ancol etylic>benzen c.Benzen> ancol etylic> phenol> axit axetic d.Axit axetic> ancol etylic> phenol> benzen Cu 32.Nhit si ca phenol,ancol etylic,nc,etyl clorua,ancol propylic c xp theo chiu gim dn t tri qua phi A. ancol propylic > ancol etylic> phenol> etyl clorua> nc B. nc >ancol propylic > ancol etylic> phenol> etyl clorua C. phenol> ancol propylic > ancol etylic> nc > etyl clorua D. phenol> nc >ancol propylic > ancol etylic> etyl clorua ANCOL Cu 33. Cc cng thc Ancol vit khng ng l a.CnH2n+1OH ,C3H6(OH)2 ,CnH2n+2O b.CnH2nOH ,CH3CH(OH)2 , CnH2n-3O c.CnH2nO ,CH2OH CH2OH , CnH2n+2On d.C3H5(OH)3 , CnH2n-1OH, CnH2n+2O 2

Cu 34. Xc nh tn IUPAC ca ancol sau CH3 CHOH - CH2 - CH(CH3) - CH3 a.1,3-imetylbutan-1-ol b.2-metylpentan-4-ol c.4,4-imetylbutan- 2-ol d.4-metylpentan-2-ol Cu 35. S ng phn c cng cng thc phn t C4H10O l a.4 b.6 c.7 d.8 Cu 36.Ancol no di y thuc dy ng ng c cng thc chung l CnH2nO a.CH3CH2OH b.C6H5CH2OH c.CH2=CH-CH2OH d.CH2OH-CH2OH Cu 37.S ng phn ancol tng ng vi cng thc phn t C3H8O, C4H10O, C5H12O ln lt l a.2,4,8 b.0,3,7 c.2,3,6 d.1,2,3 Cu 40.Tn gi no sau y khng ng vi hp cht (CH3)2CHCH2CH2OH a.3-Metylbutan-1-ol b.ancol iso pentylic c.Acol iso amylic d.2-metylbutan-4-ol Cu 41.Tn chnh xc theo danh php IUPAC ca CH3CHOHCH(CH3)CH3 a.2-metylbutan-3-ol b.1,1-imetylpropan-2-ol c.3-metylbutan-2-ol d.1,2-imetylpropan-1-ol Cu 42.Tn ancol no sau y c sai a.CH3CH2CH2CH2CH(CH3)CH2OH, 2-metylhexan-1-ol b.CH3C(CH3)2CH2CHOHCH3 ; 4,4-imetylpentan-2-ol c.CH3CHC2H5CHOHCH3 ; 3-etylbutan-2-ol d.CH3CH2CH(CH3)CHOHCH3 ; 3-metylpentan-2-ol Cu 43.Etilen glicol v glixerol l a.ancol bc 2 v ancol bc 3 b.Hai ancol a chc c.2 ancol ng ng d.hai ancol tp chc. Cu 44.Cho cc hp cht CH2OH-CH2OH HOCH2CH2CH2OH CH3CHOHCH2OH CH2OHCHOHCH2OH .C bao nhiucht l ng phn ca nhau? a.1 b.2 c.3 d.4 Cu 45.Sn phm chnh ca phn ng cng nc vo propilen(xc tc Axit sufuric long) a.Ancol isopropylic b.Ancol etylic c.ancol n- propylic d.ancol sec-propylic. Cu 46. X l hn hp 2 ru ng phn c cng cng thc phn t C4H10O . un X vi H2SO4 c nhit 1700C ch to ra mt ancol duy nht. X l a.Butan-1-ol v butan-2-ol b.2-metylpropan-1-ol v 2-metylpropan-2-ol c.2-metylpropan-1-ol v butan-1-ol d. 2-metylpropan-2-ol v butan-2-ol Cu 47. X b oxi ho bi CuO cho sn phm c kh nng trng gng.CHt l: a.Ancol sec propylic b.ancol tert butylic c.ancol n-butylic d.ancol sec butylic Cu 48.Ancol no di y khi b oxi ho khng hon ton to ra xetn a. Ancol n-butylic b. ancol sec butylic c. ancol tert butylic d. ancol iso butylic Cu 49.Khi t chy mt ru thy n(H2O) > nCO2,ru l a.No n chc mch h b.no,mch vng c.no mch h d.khng no mch vng. Cu 50.Khi t chy mt ancol thy n(H2O) = nCO2,ru l a.khng no mch h b.khng no mch h,c mt lin kt i,dn chc c.no,mch vng d.Khng no mch h c mt lin kt i,hoc mch mt vng no Cu 51.Khi t chy cc ancol no mch h n chc l ng ng lin tip .Khi s nguyn t C tng dn th t l n(H2O) / nCO2 c gi tr a.Khng i b.tng dn c.gim dn t 2 n 1 d.Gim dn t 1 n 0 Cu 52.Cng thc tng qut no sau y khng ng a.ru no n chc mch h CnH2n+1OH b.Ru no 2 chc mch h C nH2n(OH)2 c.ru no a chc mch h CnH2n+1(OH)x d.ru no a chc mch h CnH2n+2-x(OH)x Cu53. Ancol etylic tan v hn trong nc do a.cng c nhm OH b.Cng c lin kt phn cc c.cng c tnh cht ha hc tng t nhau d. Ancol etylic to lin kt hiro vi nc Cu 54.Khi cho mt ancol tc dng vi kim loi hot ng mnh ( hoc d),nu VH2 sinh ra=1/2V ca hi ru o cng iu kin th l ancol no sau y? a. a chc b. n chc c.hai chc d.ba chc. Cu 55. Hp cht CH3CH(CH3)CH=CH2 l sn phm tch nc ca ancol no sau y? a.2-metylbutan-1-ol b.2,2-imetylpropan-1-ol c.2-metylbutanol-1-ol d.3-metylbutan-1-ol Cu 56.Dung dch ancol etylic 25 0 c ngha l a.100g dd c 25ml ancol etylic nguyn cht b. 100ml dd c 25g ancol etylic nguyn cht c. 100g dd c 25g ancol etylic nguyn cht d. 100ml dd c 25ml ancol etylic nguyn cht Cu 57.Trong dy ng ng ca ancol n chc no mch h ni chung khi s nguyn t C tng th a. si tng,kh nng tan trong nc tng b. si tng,kh nng tan trong nc gim c. si gim, kh nng tan trong nc tng d. si gim, kh nng tan trong nc gim Cu 58.Cht X c CTPt l C4H8O.X lm mt mu dd nc brm v tc dng vi Na gii phng H2.CTPT ca X l a.CH2=CH-CH2-CH2OH v CH3CH2CH2CHO b.CH3CH=CH-CH2OH v CH3CH2CH=CH-OH c.CH2=CH-CH2-CH2OH v CH3CH=CHCH2OH d.tt c u sai 3

(vn cn bi tp ton v dx hal- ancol- phenol)