12

th
ABCD (Date: 01-01-2012) Final Test
PAPER-1
Code-A
ANSWER KEY
MATHS
SECTION-1
PART-A
Q.1 C
Q.2 C
Q.3 C
Q.4 B
Q.5 D
Q.6 C
Q.7 B
Q.8 A
Q.9 D
Q.10 B,C,D
Q.11 A,C,D
Q.12 C,D
Q.13 A,C,D
PART-C
Q.1 0001
Q.2 0004
Q.3 0006
Q.4 0009
Q.5 0007
Q.6 0008
Q.7 0000
Q.8 0003
PHYSICS
SECTION-2
PART-A
Q.1 B
Q.2 C
Q.3 B
Q.4 B
Q.5 A
Q.6 D
Q.7 C
Q.8 D
Q.9 A
Q.10 B,D
Q.11 C,D
Q.12 B,D
Q.13 B,C
PART-C
Q.1 0800
Q.2 0001
Q.3 0200
Q.4 2200
Q.5 0003
Q.6 0015
Q.7 0009
Q.8 0080
CHEMISTRY
SECTION-3
PART-A
Q.1 B
Q.2 D
Q.3 A
Q.4 C
Q.5 B
Q.6 D
Q.7 A
Q.8 C
Q.9 A
Q.10 A,B,C
Q.11 A,B,C
Q.12 A,B
Q.13 B,C
PART-C
Q.1 0200
Q.2 0006
Q.3 0003
Q.4 0003
Q.5 0009
Q.6 0006
Q.7 4000
Q.8 0014
MATHEMATICS
Code-A Page # 1
PART-A
Q.1
Sol. Given, }
=
3
2
II I
7 dx ) x ( ' ' f ) x 3 (

|
3
2
) x ( ' f ) x 3 ( +
}
=
3
2
7 dx ) x ( ' f
0 (f '(2)) + f(3) f(2) + 7 f(3) = f '(2) + f(2) + 7 = 4 + (1) + 7 = 10. Ans.
Q.2
Sol. Given, tan
1
x + tan
1
y + tan
1
(xy) =
12
11t
...(1)
At x = 1;
4
t
+ 2 tan
1
y =
12
11t
2 tan
1
y =
3
2t
y =
3
Differentiate both sides of equation (1) with respect to x, we get
2
x 1
1
+
+
2
y 1
1
+
y ' +
2
) xy ( 1
1
+
(xy' + y) = 0

2
1
+
4
1
y' +
4
1
(y' +
3
) = 0
2
1
+
4
3
+
2
1
y' = 0 2 +
3
+ 2y' = 0
So, y' = 1
2
3
. Ans.
Q.3
[Sol. (a + be + ce
2
) (a + be
2
+ ce) = | a + be + ce
2
|
2
= (a
2
+ b
2
+ c
2
ab bc ca)
(a b)
2
+ (b c)
2
+ (c a)
2
= 2
(a = b, | b c | = 1) or (b = c, | a c | = 1) or (c = a, | a b | = 1)
| b c | = 1
(b, c) = {(2, 1), (1, 2), (3, 2), (2, 3), (4, 3), (3, 4), (5, 4), (4, 5), (6, 5), (5, 6)}
Required probability =
6 6 6
10 3

=
36
5
Ans.]
Q.4
Sol. As, f(0
+
) = f(0

) = f(0) = 0, so f(x) is continuous at x = 0.

Further, f(0 + h) > f(0) and f(0 h) > f(0) where h is sufficiently small positive quantity.
Hence, f(x) has local minimum at x = 0.
Q.5
[Sol. We have, dy
y
dx y dy x
2
=

|
|
.
|

\
|
y
x
d
= dy
y
x
= y + C
As, y(1) = 1 C = 2
y
x
= y + 2
Now, y(|) = 3
3
|
= 5 | = 15. Ans.]
MATHEMATICS
Code-A Page # 2
Q.6
[Sol. Given, f (x) =
x tan 1
9 x tan 4 x tan
2
2
+
+ +
=
x tan 1
) x tan 2 ( 2
2
+
+
|
|
.
|

\
|
+

x tan 1
x tan 1
4
2
2
+ 5 = 2 sin 2x + 4 cos 2x + 5
R
f
=
| | 20 5 , 20 5 +
Hence, (M + m) = 10 Ans.
Aliter : f(x) =
x tan 1
x tan
2
2
+
+
x tan 1
x tan 4
2
2
+
+
x tan 1
9
2
+
= sin
2
x + 2 sin 2x + 9 cos
2
x
= 1 + 4(1 + cos 2x) + 2 sin 2x = 5 + 2 sin 2x + 4 cos 2x. ]
Paragraph for question nos. 7 to 9
[Sol.
mb
Given, f(x) = x
2
e
x
f '(x) = x e
x
(2 x)
+
0 2

Sign scheme of f '(x) O
x
y
4
1
y =
|
.
|

\
|
= =
2
e
4
y , 2 x
x = 2
Graph of f(x) = x e
2 x
As, g(x) =
}
+
x
e 2
0
2
dt
t 1
) t ( ' f
g'(x) =
) e 4 1 (
e 2 ) e 2 ( ' f
x 2
x x
+
=
) e 4 1 (
) e 1 ( e e 8
x 2
x e 2 x 2
x
+

.
Now, verify alternatives. ]
Q.10
Sol. S = {1, 2, 3, ... n}
E
1
= No. is divisible by 2.
E
2
= No. is divisible by 3.
If n = 6k say n = 6
S = {1, 2, 3, 4, 5, 6}
P(E
1
) =
6
3
=
2
1
; P(E
2
) =
6
2
=
3
1
P(E
1
E
2
) =
6
1
= P(E
1
).P(E
2
) (B) is correct.
If n = 6k + 2 say n = 8
S = {1, 2, 3, 4, 5, 6, 7, 8}
P(E
1
) =
8
4
=
2
1
; P(E
2
) =
8
2
=
4
1
Here, P(E
1
E
2
) =
8
1
= P(E
1
) P(E
2
) (C) is correct.
Note that : P(E
1
E
2
) =
10
1
= P(E
1
) P(E
2
)
Not independent dependent. ]
MATHEMATICS
Code-A Page # 3
Q.11
[Sol. Given, u = 2| tan u = tan 2|
tan u =
|
|
2
tan 1
tan 2

2 x
y
0
0

=
( )
( )
2
0
2
0
0 0
y 1 x
1 x y 2
+
+
2
0
2
0
0
0
y ) 1 x (
) 1 x ( 2
2 x
1
+
+
=

3x
0
2
y
0
2
= 3
(1,0) (2,0)
x
y
M(x , y )
0 0
(0,0) A
B
| u
Locus of M is hyperbola 3x
2
y
2
= 3
Now, verify alternatives. Ans.]
Q.12
[Sol. Given, f(x) =
( ) ( )

=
s < t
o
0 x , 0
1 x 0 , ) x 2 ( cos 1 x x 1
Note: f (x) is not defined at x = 1 for o s 0 ......(1)
f(x) is continuous at x = 0 but for continuous at x = 1.
f (1

) = f(1)
2 h sin h Lim
2
0 h
t
o

= 0
2
0 h
h Lim
+ o

= 0
o + 2 > 0 o > 2 ......(2)
Hence, (1) (2) o > 0
Note: f (x) is differentiable in (0, 1). Ans.]
Q.13
[Sol. Now, slope of LM =
0 t
2

o
= t (given)
o 2 = t
2
o = 2 + t
2
Let mid point of LM is (h, k)
(h, k)
y
x
slope = m = t
(given)
(0, 0)
M
(0, ) o
L (t, 2)
Now, 2h = t and 2k = o + 2 = t
2
+ 4
On eliminating t, we get
k = 2(h
2
+ 1)
Locus of (h, k) is y = 2(x
2
+ 1) x
2
=
2
1
(y 2)
Now, verify alternative. Ans.]
MATHEMATICS
Code-A Page # 4
PART-C
Q.1
[Sol. Clearly, the given curves intersect at x = 0,
1 k
k
2
+
Required area = ( ) dx
k
x
kx x
1 k
k
0
2
2
2
}
+
|
|
.
|

\
|
=
2
k
1
k 6
1
|
.
|

\
|
+
Now, for maximum area,
2
k
1
k
|
.
|

\
|
+
will be minimum k +
k
1
= 2 k = 1. Ans.]
Q.2
[Sol. Let c = 14 x, a = 14, b = 14 + x
Now, cos B =
13
5
(14 + x)
2
= (14 x)
2
+ 14
2
2(14 x) 14
13
5
x = 1.
So, a = 14, b = 15, c = 13.
Hence, r =
s
A
=
21
84
= 4. Ans.]
Q.3
Sol. S
n
= C
0
C
1
+ C
1
C
2
+ ... + C
n1
C
n
S
n
=
n
C
0
.
n
C
n1
+
n
C
1
.
n
C
n2
+ ... +
n
C
n1
.
n
C
0
=
2n
C
n1
S
n
=
2n
C
n1
Now,
n
1 n
S
S
+
=
4
15

1 n
n 2
n
2 n 2
C
C

+
=
4
15

4
15
! n 2
)! 1 n ( )! 1 n (
)! 2 n ( ! n
)! 2 n 2 (
=
+
+
+

n ) 2 n (
) 1 n 2 )( 1 n (
+
+ +
=
8
15
8(2n
2
+ 3n + 1) = 15n
2
+ 30n
16n
2
+ 24n + 8 = 15n
2
+ 30n n
2
6n + 8 = 0 (n 4) (n 2) = 0 n = 2 or 4
Sum of all values of n = 6 ]
Q.4
[Sol. P(HHH) =
3
3
6
1
3
1
1
18
5
2
1
18
13
|
|
.
|

\
|
|
.
|

\
|
+ + |
.
|

\
|
=
8
1

18
5
8
1

18
13
+
=
8
1
p + q = 9 Ans.]
Q.5
[Sol Given, A = (I + B) (I B)
1
Now, A
T
=
( ) ( )
T 1
) B I ( B I

+
=
( )
T 1
) B I (

(I + B)
T
=
( )
1 T
) B I (

(I + B
T
)

= (I + B)
1
(I B)
Also, AA
T
= (I + B) (I B)
1
(I + B)
1
(I B)
MATHEMATICS
Code-A Page # 5
= (I + B) ((I + B) (I B))
1
(I B) = (I + B) ((I B) (I + B))
1
(I B)
= (I + B) (I + B)
1
(I B)
1
(I B) = I I = I
2
= I.
| AA
T
| = | I | = 1 | A |
2
= 1
As, | A | > 0 | A | = 1.
Hence, det.(2A) det. (adj A) = 8 det.( A) (det.( A))
2
= 8(1) (1)
2
= 7 Ans.
Q.6
[Sol. Given,
dx
dy x
2y = x
4
y
2
or y
x
2
dx
dy
= x
3
y
2
. Now dividing by y
2
, we get
x
1
y
2
dx
dy
y
1
2
= x
3
........(i)
This is a Bernouli's differential equation, substituting t
y
2
=

, we get

dx
dt
dx
dy
y
2
2
=
. So, equation (i) becomes

x
t
dx
dt
2
1
+
= x
3
t
x
2
dx
dt
+ = 2x
3
IF =
2 x n x n 2
dx
x
2
x e e e
2
= = =
}
l l
So, general solution is given by
x
2
t =
6
x 2
6
+ C
y
2 x
2

=
3
x
6
+ C
y
2
=
3
x
4
+
2
x
C
If x = 1, y = 6 C = 0

3
x
y
2
4
=

y =
4
x
6
i.e. f(x) =
4
x
6
Now,
dx
dy
= 24x
5
=
5
x
24
. Hence,
5
1
3 x
dx
dy
=
(

(
=
3
24
= 8. Ans.]
Q.7
Sol. Given equation of planes are
P
1
: x + y + 1 = 1 ... (1)
P
2
: x + 2ay + z = 2 ... (2)
P
3
: ax + a
2
y + z = 3 ... (3)
If 3 planes intersect in a line, then
0
1 a a
1 a 2 1
1 1 1
2
=
Applying C
1
C
1
C
2
and C
2
C
2
C
3
MATHEMATICS
Code-A Page # 6

0
1 1 a a a
1 1 a 2 a 2 1
1 0 0
2 2
=


On expanding along C
1
, we get
(1 2a) (a
2
1) (a a
2
)(2a 1) = 0 1 + 3a 2a
2
= 0 a =
2
1
, 1.
But, for a = 1, planes P
1
and P
3
are parallel and for a =
2
1
, planes P
1
and P
2
are parallel.
Hence, we conclude that 3 planes will never intersect in a line for any real value of a.
Q.8
[Sol. Clearly, d =
2 2
4
3
2
1
2
1
4
3
|
.
|

\
|
+
|
.
|

\
|

=
16
1
16
1
+
=
8
1
=
2 2
1
So, | sin u | =
d 2 2
| sin u | = 1
y
x
|
.
|

\
|
0 ,
2
1
|
.
|

\
|
2
1
, 0
|
.
|

\
|
4
3
,
2
1
|
.
|

\
|
2
1
,
4
3
y

=

x
O
u =
2
t
,
2
t
,
2
3t
.
Hence, the number of values of u are 3.]
PHYSICS
Code-A Page # 1
PART-A
Q.1
[Sol. F 2f
max
= 0
F = 2f
max
= 2mg
f
max
f
max
F
F' f '
max
= 0
F' = f '
max
= 2 mg = F
f '
max
F'
m
m
]
Q.2
[Sol. Pressure is atmospheric
]
Q.3
[Sol. P =
....
P
V
P
V
P
V
V
3
2
2
2
1
2
2
+ + +
]
Q.4
[Sol. R =
g
2 sin u
2
u
=
10
1 100
2

= 1000 m
R
R A
=
u
u 2A
+
u
u
2 sin
2 cos
Au x
2

1000
R A
=
100
1 2
AR = 20 m
980 m < R < 1020 m ]
Q.5
[Sol. Ie = I'e (angular momentum conservation)
e' =
' I
I
e
=
2
q
e
' T
1
=
2
T
1
q
T' = Tq
2
= 24q
2
]
Q.6
[Sol.
m(satellite)
v
1
v
||
v
Earth
mv

r = constant ]
PHYSICS
Code-A Page # 2
Q.7
[Sol.
p
h
=
=
mqV 2
h
KE m 2
h
=
]
Q.8
[Sol. Fring width ;
d
D
= |
If V decreases, then increases & hence | increases. ]
Q.10
[Sol. During discharging ; initial current
I
in
=
R
V
in
equal & not zero.
(B) correct
When
2
V
V
in
=

2
V
in
=
RC / t
in
e V

t = RC ln (2)
R same so lesser time for lesser capacitance.
(D) correct ]
Q.11
[Sol.
V A
2
1
P
2 2
e =
Also

=
T
V
=
Area
T

=
2
d
4
T
t

When T 4 times
V 2 times P 2 times (C) correct
Also
d
d
4
T
A d
4 2
1
P
2
2 2 2

t

e
|
.
|

\
| t
=
(D) correct ]
Q.12
[Sol. Stationary magnet generates magnetic field only which does not affect piece of paper. When it moves, it
generates electric field also which affects pieces of paper.
Torque due to magnetic force
t = MB sin u
Here
B

is to plane parallel to
M

t = 0 ]
PHYSICS
Code-A Page # 3
Q.13
[Sol. For adiabatic process, PV

= constant.
ln P = ln V + constant.
|slope| =

1
>
2
f
1
< f
2
and
1
V
C Z
2
V
C
[

f =
1
2
=
and C
v
=
1
R

]
PART-C
Q.1
[Sol. In both cases, Weight = Bouyant force
Initially,
b
Vg =
w

g V
3
2
|
.
|

\
|

b
=
3
2

w
After wards,
b
Vg =
oil

g
6
V 5
|
.
|

\
|

w
3
2

=
oil

6
5

oil
=
5
4

w
=
5
4
100 = 800 kg/m
3
. ]
Q.2
[Sol. K.E
loss
= P.E.
gain
mgh
R
v
I
2
1
mv
2
1
2
2
=
|
.
|

\
|
+
2
2
R
v
I
2
1
= mg
|
|
.
|

\
|
g 4
v 3
2

2
mv
2
1

2
mR
2
1
I =
=
2
) 5 . 0 ( 8
2
1
= 1 kg m
2
]
Q.3.
[Sol. oeA (T
4
T
0
4
) = mS
|
.
|

\
|
dt
dT

dt
dT
=
( )
mS
T T eA
4
0
4
o
=
S
2
d
3
4
) T T (
4
d
e
4
0
4
2
|
.
|

\
|
t

|
|
.
|

\
|
t o
PHYSICS
Code-A Page # 4
On putting values and solving, we get
dt
dT
= 200 10
3
C/s ]
Q.4
[Sol. Train to wall :
f
1
=
(

u v
v
f v speed of sound, u speed of train
Wall to train / passenger :
f
2
=
(

+
v
u v
f
1
=
(

+
u v
u v
f = 1800 (

+
34 340
34 340
= 2200 Hz ]
Q.5
[Sol.
m
Nuetron
m
H-atom

2m
u/2
Maximum possible loss of energy is
2
. E . K
in
when collision is perfectly inelastic as shown.
(K.E.
loss
)
max
=
2
5 . 25
= 12.75 eV
This is sufficient to raise the electron upto 3
rd
shell. While returning first shell three photons are possible.]
Q.6
[Sol. Initially,
) 1 ( 2
R
f

=
= 10 R = 10 cm
In water
=
~
+
1
st
refraction u
1
= ; R = + 10 cm
v
1

) 3 / 4 (
=
10
) 3 / 4 ( 1
v
1
= 30 cm
refraction at lens u
2
= v
1
= 30 cm
v
2
=
f u
f u
2
2
+
=
10 30
) 10 ( ) 30 (
+

= 15 cm ]
PHYSICS
Code-A Page # 5
Q.7
[Sol.
30 30
q
Q Q
2
kqQ 2

cos 30 = ma
2
8 9
) 2 . 0 (
10 10 9 2



2
3
= 3 10
6
a
a = 9 m/s
2
]
Q.8
[Sol. V
1
+ V
2
+ V
3
= 120 20 (0.5)
V
1
+ V
2
+ V
3
= 110 V .... (1)
Also V
1
+ V
2
= 60 V
3
= 110 60 = 50V
Now V
2
+ V
3
= 90 V
2
= 40V
R
3
R
2
R
1
120V, 20O
V
1
V
2
V
3
I=0.5A
R
2
=
5 . 0
40
= 80O ]
CHEMISTRY
Code-A Page # 1
PART-A
Q.1
[Sol. Radius of 4
th
orbit = x 4
2
16x
2tr = n
2t 16 x = 4
= 8t x ]
Q.2
[Sol. ZnS + 2HCl ZnCl
2
+ H
2
S | ]
Q.3
[Sol. Presence of electron withdrawing group increases the rate of BAC
2
reaction while rate electron
releasing group decrease the rate of BAC
2
reaction. ]
Q.4
[Sol. Normal boiling point = 100C at 1 atm
Standard boiling point at 1 bar 1 bar < 1 atm
as P + Boiling point +
less than 100C ]
Q.5
[Sol. Only Mn & Mg metals liberates H
2
gas with dil. HNO
3
M(Mg, Mn) + dil. 2HNO
3
M(NO
3
)
2
+ H
2
|
3Cu + 8HNO
3
3Cu(NO
3
)
2
+ 2NO + 4H
2
O
4Zn + 10HNO
3
4Zn(NO
3
)
2
+ NH
4
NO
3
+ 3H
2
O
or
Fe ]
Q.6
[Sol.
Br
2
CF
3
Cl
FeBr
3
CF
3
Cl
Br
Nitration
CF
3
Cl
O N
2
Br
NH
2
NH
2
CF
3
NHNH
2
O N
2
Br
]
CHEMISTRY
Code-A Page # 2
Q.7,8,9
[Sol.
Gas colourless (A)=
KMnO + H
4
+
Exposure/A
F
e
C
l 3
A
g
N
O
3
(X) = SO
3
2
(Y)=S O
2 3
2
Violet/Purple
(C)= [Fe(S O ) ]
2 3 2
White ppt. (E) = Ag S O
2 2 3

(D)= Fe
2+
+ S O
4 6
2

Green
Black (F)= Ag S + H SO
2 4 2
[B + X Y]
X
Zn+HCl
(A) (i)
(ii)
H S
2
(B) = S
Fe
3+
H
2
S + Na
2
[Fe(CN)
5
NO] No reaction colourless solution
H
2
S + OH S
2
; Na
2
S + Na
2
[Fe(CN)
5
NO] Na
4
[Fe(CN)
5
NOS] (Violet colour) ]
Q.10
[Sol. (i) Water is more acidic than EtOH
(ii) Bond length is not equal since R.S. are not equivalent.
(iii) Ph
2
NH
- -
is weaker base than MeNH
2
, due to involvement of lone pair of electron in resonance.
(iv) If key atom is lone pair bearing it will show +M effect. ]
Q.12
[Sol. Due to high ionisation energy of Be and Mg ]
Q.13
[Sol. (B)
O
O
(C)
OH
OH
(D)
O
(E)
OH
OH
and can be changed in by using conc. H
2
SO
4
and H
3
PO
4
]
CHEMISTRY
Code-A Page # 3
PART-C
Q.1
[Sol. Edge length =
B
A
r 2 r 2 +
+
= 2 60 + 2 100 320 pm
Molecular mass of AB = 320
=
3
A
O
a
N
M
z
3 10
A
) 10 320 (
N
320
4
2 . 3
x

=
; x =
50
10
4
= 200 ]
Q.2
[Sol. NH
4
NO
3


A
N
2
O + 2H
2
O
NH
4
NO
2


A
N
2
+ 2H
2
O
Except Na
+
, K
+
, Rb
+
, Cs
+
all metal nitrate give NO
2
on heating
M(NO
3
)
y

A
M
2
O
y
+ NO
2
+ O
2
]
Q.3
[Sol. Lassaigne method
Sodium Extract + FeSO
4
+ NaOH, boil and cool + FeCl
3
+ conc. HCl
Blue and green colour and how the presence of nitrogen.]
Q.4
[Sol. S =
|
|
.
|

\
|
+
+
a
sp
K
] H [
1 K
S =
|
|
.
|

\
|
+

5 . 3
10
10
1 10 5 . 2
5
4
13
=
36 10 5 . 2
13


=30 10
6
]
Q.5
[Sol. CH
3
CH
2
CHO
CH CH=CH
2 2
OH
O
H CH =CH/G.I.
3
C
OH
C CH
3
H C
3
O
C =CH
2
H C
3
O
CH
2
= CH O CH
3
O
]
CHEMISTRY
Code-A Page # 4
Q.6
[Sol. (a) PH
4
Cl + NaOH PH
3
| + H
2
O + NaCl
(b) P
4
+ 3 NaOH + 3H
2
O
A
PH
3
| +3NaH
2
PO
2
(c) Ca
3
P
2
+ 6H
2
O 2PH
3
| + 3Ca(OH)
2
(d) 4H
3
PO
3

A
PH
3
| + 3H
3
PO
4
(e) PCl
5
+ H
2
SO
4
SO
2
Cl
2
+ 2POCl
3
+ 2HCl
(f) 2H
3
PO
2

A
2PH
3
| + H
3
PO
4
(g) P
2
Cl
4
+ 4H
2
O H
4
P
2
O
4
+ 4HCl
(h) 2AlP + 3H
2
SO
4
Al
2
(SO
4
)
3
+ 2PH
3
|
(i) P
4
O
10
+ 6H
2
O 4H
3
PO
4
]
Q.7
[Sol. 2CH
4
+ 4O
2
2CO
2
+ 4H
2
O
AH = 900 2 = 1800 kJ
AG =
o
Reactant f
o
Products f
G G
= ( 400) 2 + 4 (120) [2( 40) + 0]
= 800 480 + 80
= 1200 kJ / mole
AG = AH TAS
T
G H
S
o
system
A A
= A
=
300
kJ ) 1200 ( ) 1800 (
=
kJ
300
600
= 2 kJ = 2000 J / K
Final answer 4000 Ans. ]
Q.8
[Sol. (a)
Cl
= 1
Cl
= 4
Cl
= 2
Cl
= 4
Cl
= 1
Cl
= 2
x = 14 Ans. ]