13

th
VXY (Date: 04-09-2011) Review Test-2
PAPER-2
Code-A
ANSWER KEY
MATHS
SECTION-2
PART-A
Q.1 D
Q.2 C
Q.3 D
Q.4 A
Q.5 D
Q.6 C,D
Q.7 A,B,D
Q.8 A,B,D
PART-B
Q.1 (A) P
(B) R
(C) R
Q.2 (A) S
(B) P
(C) T
(D) S
PART-C
Q.1 0004
Q.2 0000
Q.3 0001
Q.4 0005
Q.5 0013
PHYSICS
SECTION-1
PART-A
Q.1 B
Q.2 B
Q.3 A
Q.4 B
Q.5 C
Q.6 A,B
Q.7 A,B,C
Q.8 A,B,D
PART-B
Q.1 (A) P,R
(B) Q,R
(C) Q,S
Q.2 (A) T
(B) P
(C) Q, R
(D) Q
PART-C
Q.1 0002
Q.2 0010
Q.3 0025
Q.4 0030
Q.5 0003
CHEMISTRY
SECTION-3
PART-A
Q.1 C
Q.2 B
Q.3 A
Q.4 A
Q.5 A
Q.6 A
Q.7 A
Q.8 D
PART-B
Q.1 (A) Q
(B) P,S
(C) R,S
Q.2 (A) P,R
(B) Q,T
(C) P,T
(D) Q,R,S
PART-C
Q.1 1743
Q.2 0106
Q.3 0012
Q.4 0003
Q.5 0004
PHYSICS
Code-A Page # 1
PART-A
Q.1
[Sol. f = mg
car
van
f
f
=
car
van
m
m
= 3 ]
Q.3
[Sol. S
1
= v
1
t
1
; S
2
=
a 2
v
2
1
; a =
2
1
t
v
; S
2
=
2
t v
2 1
given t
2
= 20t
1
S
1
=
10
S
2
]
Paragraph for question nos. 4 to 5
[Sol.
o
|
o
|
u


0
x
(4) As o = (| o) + x, or x = 2o |, we have o = t 2x = t 4o + 2|.
(5) For minimum deflection, we require
|
o
d
d
= 4
|
o
d
d
+ 2 = 0, or
|
o
d
d
=
2
1
.
As o = sin
1

|
.
|

\
|
| sin
n
1
we have
|
o
d
d
=
n
1
o
|
cos
cos
and the above gives
1
2
n
1
sin
2
| =
2
n
4
cos
2
|,
or 1 =
2
n
1
+
2
n
3
cos
2
|,
giving cos
2
| =
3
1 n
2

]
Q.6
[Sol. Since collision is perfectly inelastic mechanical energy is not conserved during collision.
Since there is not net external impulsive force on the system, so linear momentum of system is conserved
during collision. ]
PHYSICS
Code-A Page # 2
Q.7
[Sol. Mechanical energy is conserved
p = mv ; a
n
=
r
v
2
v increases ]
Q.8
[Sol.
mg
T
V
mg
T
u
mg sin u
m
g

c
o
s

u
At starting point
T mg =
r
mv
2
T mg cos u = 0
T =
r
mv
2
+ mg T = mg cos u ]
PART-B
Q.1
[Sol.
1 2
x
2R
First surface
Refraction at
first surface
R

u

i r i r

=
) R (
3 / 4 1
) R 2 (
3 / 4
v
1

v
1
+
R 3
2
=
R 3
1
v = 3R (virtual)
m =
r
i

=
) R 2 (
) R 3 (
) 1 (
3 / 4

m = 2 (magnified)
Reflection from mirror & refraction from second surface
2
2R 2R
2R
6R
v
3 / 4

) R 4 (
1

=
R
1 3 / 4
v = 16R (Real)
PHYSICS
Code-A Page # 3
m =
u
v

r
i
=
3 / 4
1
) R 4 (
R 16

m = 3 (magnified)
Refraction a first surface after reflection from mirror and refraction at second surface.
2
16R
1
14R
R

u

i r i r

=
R 14
3 / 4
v
1

=
R
3 / 4 1

v =
3
R 7
(Real)
m =
u
v

r
i
m =
3
4

R 14
R 3 / 7
+
=
14 3
7
3
4

m =
9
2
(diminished) ]
Q.2
[Sol.(A) At the equilibrium position, F =
dx
dU
= 0, i.e.
2 2 2
2 2
) a x (
) x a ( c
dx
dU
+

=
= 0
Thus there are two equilibrium positions, x
1
= a, x
2
= a. Consider
2
2
dx
U d
=
3 2 2
2 2
) a x (
) a 3 x ( cx 2
+

We have
0
dx
U d
1
x
2
2
<
,
0
dx
U d
2
x
2
2
>
It follows that x
1
is a position of unstable equilibrium and x
2
is a position of stable equilibrium.
The total energy of the particle is
E =
2
mv
2
+ U(a) =
2
mv
2

a 2
c
For the particle to be confined in a region, we require E < 0, i.e.
(B) v <
ma
c
As E =
2
mx
2
+ U(x), for the particle to reach x = , we require E > U() = 0, i.e.
(D) v >
ma
c
To escape to +, the particle must pass through the point x
2
= +a at which the potential energy is
maximum. Hence we require E > U(a) =
a 2
c
, i.e.,
(C) v >
ma
c 2
]
PART-C
Q.1
[Sol. sin 60 = sin 90
60
60
2
3
= 1
3
= 2 ]
Q.2
[Sol. Refraction plane surface h' = h
i
r

=
1
2 / 3 20
= 30 cm
Mirror
f
1
u
1
v
1
= +
10
1
45
1
v
1

+
v =
7
90
from pole of mirror..
distance of object from plane surface l = 15
7
90
=
7
90 105
=
7
15
Refraction at plane surface x = 10 l' = l
i
r

x = l' =
2 / 3
1
7
15

=
7
10
7x = 10 (location of final image from plane surface) ]
Q.3
[Sol. y = x tan u
2
1
g
u
2 2
2
cos v
x
x = 38 + 2 = 40
y = 18
u = 60 v = 25 m/s ]
PHYSICS
Code-A Page # 5
Q.4
[Sol. As << m, M, momentum conservation
MV = (M + m)V'
gives for the velocity of the two carts after collision,
V' =
m M
MV
+
Consider the circular motion of the ball atop the cart M if it were stationary. If at the lowest and highest
points the ball has speeds V
1
and V
2
respectively, we have
2
1
V
1
2
=
2
1
V
2
2
+ 2gR,
R
V
2
2
= T + g
where T is the tension in the string when the ball is at the highest point. The smallest V
2
is given by T = 0.
Hence the smallest V
1
is given by
2
1
V
1
2
=
2
1
gR + 2gR i.e. V
1
= gR 5
With the cart moving, V
1
is the velocity of the ball relative to the cart. As the ball has initial velocity V and
the cart has velocity V' after the collision, the velocity of the ball relative to the cart after the collision is V
V'. Hence the smallest V for the ball to go round in a circle after the collision is given by
V V' = V
m M
MV
+
= gR 5 i.e. V =
m
m M+
gR 5 ]
Q.5
[Sol. After collision velocity of A
V
A
= V
0
2
1
m 3
) m 2 )( m (
V
0
2
=
2
1
k x
0
2
k =
2
0
2
0
x 3
mV 2
n = 3 ]
MATHEMATICS
Code-A Page # 1
PART-A
Paragraph for questions nos. 1 to 3
[Sol. Given, f(x) =
( )
( )
( )

+ s s
< <
=
< <
s s
1 e x 2 , 1 x n 2
2 x 0 , 4 x
2
1
0 x , 0
0 x 2 , x 4
2
1
2 x 1 e ), 1 x ( n 2
2
2
l
l

y
x
2
O
1 2 1
2
e +1 e 1
2
1
1
Graph of f(x)
Clearly, g(x) =

+ s <
s s
< s
1 e x 2 ), 1 x ( n 2
2 x 2 , 0
2 x 1 e ), 1 x ( n 2
l
l

y
x
O
1 2 1 2 e +1 e 1
2
1
Graph of g(x)
(i) From above graph of g(x), range of g(x) is [0, 2] and g(x) = 0 in interval [2, 2].
Also g(x) is an even continuous function.
(ii) Clearly, g(x) is non-differentiable at x = 2, 2.
(iii) Clealry, g(x) = k has exactly two distinct solutions, then integral value of k is either 1 or 2.
So, sum of all possible integral values of k = 1 + 2 = 3. Ans.]
Paragraph for question nos. 4 to 5
[Sol. Given, x
3
+ y
3
= 2 .... (1) and y = kx + d .... (2)
Substituting y = kx + d in equation (1), we getfor 13th
x
3
+ (kx + d)
3
= 2 (1 + k
3
) x
3
+ 3k
2
d x
2
+ 3kd
2
x + (d
3
2) = 0 ..... (3)
For the above equation (3) to give no solution, we must have k = 1,
otherwise it will be a cubic and will always give atleast one real solution.
(i) Clearly, k = 1.
(ii) For k = 1, the equation (3) becomes 3d x
2
3d
2
x + d
3
2 = 0 ..... (4)
If d = 0, then equation (4) has no solution ..... (5)
Also, if d = 0 then equation (4) is a quadratic equation.
So for no solution, we must have discriminant < 0. So,
9d
4
12d (d
3
2) < 0 3d (3d
3
4 (d
3
2)) < 0 d (8 d
3
) < 0
d (2 d) ( )

positive Always
2
d 2 d 4 + + < 0 d (d 2) > 0 d e ( , 0) (2, ) .... (6)
Hence, from (5) (6) d e (, 0] (2, ). Ans.]
MATHEMATICS
Code-A Page # 2
Paragraph for question nos. 6 to 8
[Sol. Let degree of P(x) = n
degree of P ' (x) = n 1.
So, L.H.S. has a degree n
and R.H.S. has a degree 2
2 n =
(

(
Let P(x) = ax
2
+ bx + c.
Now, ax
2
+ bx + c (2ax + b) x
2
+ 2x + 1
a = 1; b = 4 and c = 5
Hence, P(x) = x
2
+ 4x + 5.
Given, F(x) =
( )

=
=
|
.
|

\
|
+

1 x , e
1 x ,
10
) x ( P
40 k 9 k
1
) 4 x 4 ( sin 3 sin
1
2
As, ) x ( F Lim
1 x
= e
L

( ) form 1

, where L =
( )
|
|
.
|

\
|

+ +

1
10
5 x 4 x
) 4 x 4 ( sin 3 sin
1
Lim
2
1 x
=
10
) 1 x ( ) 5 x (
) 1 x ( 12
1
Lim
1 x
+

=
120
6
=
20
1
.
(i) Hence, continuity at x = 1 ) x ( F Lim
1 x
= F(1). So,
20
1
e =
40 k 9 k
1
2
e
+
Hence, k
2
9k + 40 = 20 k
2
9k + 20 = 0 k = 4, 5.
(ii)
}
1
0
dx
) x ( P
1
=
( )
}
+ +
1
0
2
dx
1 2 x
1
= |
1
0
1
) 2 x ( tan +

= tan
1
3 tan
1
2=
7
1
tan
1
= cot
1
7
Now, use tan
1
1 + tan
1
2 + tan
1
3 = t , to get other options.
(iii)
O
1
5
y = 1
2
y
v ( 2, 1)
x
Graph of P(x) = x
2
+ 4x + 5 = (x + 2)
2
+ 1.
Now, verify alternatives. ]
MATHEMATICS
Code-A Page # 3
PART-B
Q.1
[Sol.
(A) As f (x) is continuous at x = 0, so
) x ( f Lim
0 x
= f (0)
|
|
.
|

\
|
o

2
2
0 x
x
x sin
Lim
=
|
.
|

\
|
o
+
4
1
4
3
o =
o
+
4
1
4
3
4o
2
= 3o + 1
4o
2
3o 1 = 0 4o(o 1) + 1(o 1) = 0 (4o + 1)(o 1) = 0
So, o = 1,
4
1
Ans.
(B) If triangle ABC is obtuse angled, then tanA tanB tanC < 0
tanA + tanB + tanC = (x 1) (x 5) < 0 x e (1, 5) Ans.]
As, in triangle ABC,
tanA + tanB + tanC = tanA tanB tanC
(C) As, f(x) = [cos
1
(cos x) sin
1
(sin x) ] =

t
s s
< s
t

2
x 0 , 0
0 x
2
], x 2 [
=

t
s s
< <

s <
s <

s s
t
2
x 0 , 0
0 x
2
1
, 0
2
1
x 1 , 1
1 x
2
3
, 2
2
3
x
2
, 3
1
t
2
3
2
1
2
O
t
2
y
x
y=3
y=2
y=1
Graph of f(x) = [cos (cos x) sin (sin x)] in
1 1
(

t t
e
2
,
2
x
y=0
Clearly, f(x) is discontinuous at 3 points in x e
(

t t

2
,
2
viz. x =
2
3
, 1,
2
1
.
Note : f(x) is continuous at x = 0.
MATHEMATICS
Code-A Page # 4
Q.2
[Sol.
(A) If A + B = 225 then (1 + tanA) (1 + tanB) = 2 tan A (cot A + 1) tan B (cot B + 1) = 2

|
.
|

\
| +
|
.
|

\
| +
B cot
B cot 1
A cot
A cot 1
= 2.
So, f(72) f (153) = 2 and f(78) f (147) = 2.
Hence, f(72) f(78) f(147) f(153) = 4 Ans.
(B) Let f(x) = 2x
2
mx 1 = 2
(

2
1
x
2
m
x
2
= 2
(
(

|
.
|

\
|
+
|
.
|

\
|

2
1
16
m
4
m
x
2
2
As, graph of f(x) is symmetrical about x =
2
1
,
So,
4
m
=
2
1
m = 2.
x
y
O
V
|
.
|

\
|
2
3
,
2
1
|
.
|

\
|

0 ,
2
3 1
2
1
x =
|
.
|

\
|
+
0 ,
2
3 1
Graph of f(x) = 2x 2x 1
2
So, the quadratic eqution becomes 2x 2x 1 = 0
2

| o
.
Hence, sum of roots = o + | =
2
) 2 (
= 1. Ans.
(C) Given, cot
2
x (k 4) cot x + (4 2k) = 0, which is quadratic equation in cot x.
So, cot x =
2
) k 2 4 ( 4 ) 4 k ( ) 4 k (
2

=
2
k ) 4 k (
So, cot x = k 2 or 2.
As, cot x = 2, for any x e
(

t t
2
,
4
So, cot x = k 2.
As, x e
(

t t
2
,
4
0 s cot x s 1.
0 s k 2 s 1 2 s k s 3.
Hence, the sum of all possible integral values of k = 2 + 3 = 5. Ans.
(D) Given, ( ) form 1 x e Lim
x cos 1
1
2 x
0 x
2

|
.
|

\
|
+ = e
l
, where
l =
( ) x cos 1 x
x 1 x e
Lim
2
2 2 x
0 x
2

|
.
|

\
|
+

= 2
4 1
x
1 e
Lim
2
x
0 x
2
=
|
|
.
|

\
|
+

So, k = e
4
ln k = 4 A. Ans.]
MATHEMATICS
Code-A Page # 5
PART-C
Q.1
[Sol. Given, f(x) =

< <
s s +
< < +
x 3 ,
x
b
c
3 x 0 , 2 x
0 x , e a
2
x 2
Now, continuity at x = 0 a
2
+ 1 = 2 a
2
= 1 a = 1 ..... (1)
and continuity at x = 3 5 = c
3
b
2
.......(2)
Also, derivability at x = 3, we get f '(3

) = f '(3
+
) 1 =
9
b
2
b
2
= 9 b = 3 .....(3)
From (2) and (3), we get c = 8.
Hence, number of ordered triplets (a, b, c) of real numbers = 2 2 1 = 4. Ans.]
Q.2
[Sol. As,

=

5
1 r
2 1
) r 2 ( cot
=
=

|
.
|

\
|
5
1 r
2
1
r 4
2
tan
=

|
|
.
|

\
|
+ +
+
5
1 r
1
) 1 r 2 ( ) 1 r 2 ( 1
) 1 r 2 ( ) 1 r 2 (
tan
=
( )

=

+
5
1 r
1 1
) 1 r 2 ( tan ) 1 r 2 ( tan
= tan
1
11 tan
1
1 = tan
1

|
.
|

\
|
+

1 11 1
1 11
= tan
1

|
.
|

\
|
12
10
= tan
1

|
.
|

\
|
6
5
tan
|
.
|

\
|

5
1 r
2 1
) r 2 ( cot
= tan
|
.
|

\
|

6
5
tan
1
=
6
5
Now,tan
5 x 6
6 x 5
) r 2 ( cot
5
1 r
2 1
+
+
= |
.
|

\
|

5 x 6
6 x 5
6
5
+
+
=
The given equation has no real solution. Ans. ]
Q.3
[Sol. We have, x
2
+ x (5 a) + a = 0
o
|
So, o + | = a 5 and o| = a
Now, o
3
| + o|
3
= 14 (2 a) (Given)
o|
( ) | | o| | + o 2
2
= 14 (2 a)
a
( ) | | a 2 5 a
2

= 14 (2 a)
a
3
12a
2
+ 39a 28 = 0 (a 1) (a 4) (a 7) = 0.
So, a
1
= 1, a
2
= 4, a
3
= 7 (As, a
3
> a
2
> a
1
)
MATHEMATICS
Code-A Page # 6
Given, 4a
1
(x
2
+ 1) + pa
2
(x + 1) a
3
> 0 x e R
4x
2
+ 4 + 4px + 4p 7 > 0 (Putting the value of a
1
, a
2
and a
3
)
4x
2
+ 4px + 4p 7 > 0
Discriminant < 0. So, (4p)
2
4 4 (4p 3) < 0 p
2
4p + 3 < 0
(p 1) (p 3) < 0 p e (1, 3).
Hence, number of integral values of p is 1 ie. p = 2. Ans.]
Q.4
[Sol. As, [a] + [ a] =

e
e
I a if , 1
I a if , 0
] a [ ] a [ + is defined only for integral values of a.
( ) 0 ] a [ ] a [ sin
1
= +

Also, 0 a 3 > 3 a s 3 s a s 3.
So, a = 1, 2, 3 (Given, a e R
+
)
Now, the given quadratic equation becomes
3x
2
2ax + a 3 = 0
Clearly, discriminant = D = 4a
2
4 3 a 3 = 4 ( ) a 3 3 a
2

for o, | e R, D > 0 a = 2 and 3.
Hence, the sum of all values of a = 2 + 3 = 5 Ans.]
Q.5
[Sol. L :
) x (sin e
) 1 x ( e ) x 1 (
Lim
1
x
1
0 x

+ +
=
x e
) 1 x ( e e
Lim
) x 1 ( n
x
1
0 x
+
+

l
=
x
) 1 x ( e
Lim
1 ) x 1 ( n
x
1
0 x
+
+

l
= 1+
x
1 e
Lim
1 ) x 1 ( n
x
1
0 x

l
= 1 +
x
1 ) x 1 ( n
x
1
Lim
0 x
+

l
= 1 +
2
0 x
x
x ) x 1 ( n
Lim
+

l
= 1
2
1
=
2
1
.
M : f(x) =
2 2 2
2
) 3 x tan 2 ( x tan
x tan 2
+ +
=
2
) x cot 3 x tan 2 ( 1
2
+ +
=

12 value . min
2 2
x cot 9 x tan 4 13
2
=
+ +
[As, 4 tan
2
x + 9 cot
2
x = (2 tan x 3 cot x)
2
+ 12 4 tan
2
x + 9 cot
2
x > 12]
Greatest value of f(x) =
12 13
2
+
=
25
2
Hence, (L + M
1
) =
2
25
2
1
+
=
2
6 2
= 13. Ans. ]
CHEMISTRY
Code-A Page # 1
PART-A
Paragraph for question nos. 1 to 3
[Sol.
S Q R P
HOC o
alkene of stability
1
]
Paragraph for question nos. 4 to 5
Q.4
[Sol.
) K 300 400 ( r , P K 300 K 400
C H H

A + A = A

A = A
K 300 K 400
H H
Similarly,
|
.
|

\
|
A + A = A

300
400
ln C S S
r , P K 300 K 400

A = A
K 300 K 400
S S
) 0 C (
r , P
= A
At 400K (Equilibrium Temp.)
0 S T H G = A A = A

T
H
S
A
= A
=
K 400
mol / J 2000
= 5 J/mole-K Ans.]
Q.5
[Sol. A A = A

S T H G
K 300
= 2000 300 (5)
= 500 J/mole Ans. ]
Paragraph for question nos. 6 to 8
Q.6
[Sol. CCl
3
CHO (Chloral) doesn't shows intramolecular hydrogen bond.
Following compounds shows intramolecular hydrogen bonding.
]
CHEMISTRY
Code-A Page # 2
Q.7
[Sol. 0C to 4C density of H
2
O increases
At 4C density of H
2
O maximum.
Q.8
[Sol. (A) extent of H-bonding in H
2
O
2
is more than H
2
O between H
2
O
2
has 2 OH group.
(B) ;
Due to the present of more number of OH group in glycerol ; glycerol having more effective hydrogen
bonding than glycol, so it is more viscous.
(C) Boiling point of O-nitrophenol is less than meta & paranitrophenal, so they are separate by using
steam volatile property.
(D) In a ice, 2 oxygen atoms are covalently bonded and other 2 H are bonded with H-bond, so all the
4 Hydrogen atoms are not equidistant with oxygen atom. ]
PART-B
Q.1
[Sol. (A) For reversible isothermal expansion :
AT = 0, AH = 0, AU = 0, q
=
0,
AS
Total
= 0, AS
sys
> 0, AS
surr
< 0
Hence Q
(B) For reversible adiabatic compression of a real gas :
q = 0, AS
Total
= 0, AS
syst
= 0, AS
surr
= 0,
0 U , 0 H , 0 T = A = A = A
Hence P,S
(C) For Free expansion :
q = 0, w = 0, AU = 0
AH = 0 (for Ideal gas)

0 =
(for other cases)
AS
sys
> 0 , AS
surr
= 0, AS
Total
> 0
Hence R,S ]
Q.2
[Sol. (P) Keto > enol (Stability)
(Q) Complete teh octet more stable the resonating structure
(R) Aromatic enol > Keto (Stability)
(S) More number of o H more well the stability of alkene
(T) Complete octet more stable resonating structure ]
CHEMISTRY
Code-A Page # 3
PART-C
Q.1
[Sol. 2A (g) B(g) + C(g)
1 2 1 atm
Q =
2
1
1 2
= 2
AG = Q ln RT G + A
= (60 + 20 2 40) + 8.3 300 ln 2
= 1743 kJ Ans. ]
Q.2
[Sol. (i) P = (Ne)
Ptdt bond
(ii) (Due to the absence of vacant d-orbital in N & O; ptdt bond is not present.)
(iii) (Total 6ptdt bonds present) ]
Q.3
[Sol. Criteria for spontaneously is :
( ) 0 dG
T , P
< ; ( ) 0 dS
univ
> ; ( ) 0 dU
V , S
< ; ( ) 0 dH
P , S
< ;
( ) 0 dS
V , U
> ; ( ) 0 dS
P , H
>
So, option 2, 4 and 6 are correct
2 + 4 + 6 = 12 Ans. ]
CHEMISTRY
Code-A Page # 4
Q.4
[Sol. ; (sp
3
, non-planar, non-polar)
(sp
3
, non planar) ; (sp
3
, non-planar, non-polar, = 0)
(sp
3
d
2
, square planar, = 0, non-polar); (sp
2
, Triagonal planar, = 0, non-polar)]
Q.5
[Sol. Number of geometrical isomers in unsymmetrical compound = 2
n
n G.I. units Ans. 4 ]