13

th
VXY (Date: 22-01-2012) Review Test-6
PAPER-1
Code-A
ANSWER KEY
PHYSICS
SECTION-2
PART-A
Q.1 C
Q.2 D
Q.3 B
Q.4 A
Q.5 B
Q.6 D
Q.7 B
Q.8 D
Q.9 C
Q.10 C,D
Q.11 C
Q.12 A,D
Q.13 A,C
PART-C
Q.1 2000
Q.2 0002
Q.3 0012
Q.4 0002
Q.5 0001
Q.6 0060
Q.7 0008
Q.8 BONUS
MATHS
SECTION-1
PART-A
Q.1 D
Q.2 D
Q.3 C
Q.4 B
Q.5 B
Q.6 C
Q.7 B
Q.8 A
Q.9 A
Q.10 A,B,C,D
Q.11 A,B
Q.12 A,B,C
Q.13 A,C,D
PART-C
Q.1 0004
Q.2 0006
Q.3 0002
Q.4 0038
Q.5 0005
Q.6 0162
Q.7 0004
Q.8 0004
CHEMISTRY
SECTION-3
PART-A
Q.1 C
Q.2 C
[Only V-Group Batch]
Q.3 B
[Only XY Batch]
Q.3 B
Q.4 A
[Only V-Group Batch]
Q.5 B
[Only XY Batch]
Q.5 A
Q.6 B
Q.7 A
Q.8 C
Q.9 A
Q.10 A,B,C,D
[Only V-Group Batch]
Q.11 A,B
[Only XY Batch]
Q.11 A
[Only V-Group Batch]
Q.12 A,B
[Only XY Batch]
Q.12 A,C
[Only V-Group Batch]
Q.13 A,B,D
[Only XY Batch]
Q.13 A,B,C,D
PART-C
Q.1 0003
Q.2 0006
Q.3 1233
Q.4 4002
Q.5 0003
Q.6 0004
Q.7 0003
Q.8 2248
MATHEMATICS
Code-A Page # 1
PART-A
Q.1
[Sol. x y = 2 ..........(1)
cx + y = 3 ..........(2)
(1) + (2)
x (1 + c) = 5
x =
c 1
5
+
and y =
c 1
5
+
2

c 1
5
+
> 0 and
c 1
5
+
> 2

c 1
5
+
> 2
c 1
c 2 2 5
+

> 0
1 c
3 c 2
+

< 0
So, c e
|
.
|

\
|

2
3
, 1
. Ans.]
Q.2
[Sol. Given, sin u, 2 (sin u + 1), 6 (1 + sin u), .............. are in geometric progression.
So,
u
+ u
sin
) 1 (sin 2
=
) sin 1 ( 2
) sin 1 ( 6
u +
u +
1 + sin u = 3 sin u sin u =
2
1
(As, sinu = 1 is not possible)
So, terms of geometric progression are
2
1
,
2
3 2
,
2
3 6
,.......... .
So, fifth term of geometric progression =
4
2
6

2
1
|
.
|

\
|
|
.
|

\
|
=
4
1296
2
1

= 162. Ans.]
Q.3
[Sol. f (x) will be continuous where
3 sin x + a
2
10a + 30 = 4cos x or

5
2
30 a 10 a
>
+
=

5
x sin 3 x cos 4
s

or (a 5)
2
+ 5 = 4cos x 3sin x
a = 5 and 4 cos x 3 sin x = 5

1 x sin
5
3
x cos
5
4
=
or cos (x + u) = 1, where tan u =
4
3
x = 2nt u = 2nt
4
3
tan
1
, n e I.
Q.4
[Sol. Equation of director circle of ellipse
4
x
2
+ y
2
= 1 is x
2
+ y
2
= 5 or x
2
+ y
2
5 = 0 .....(1)
If above circle in equation (1) intersects orthogonally the circle x
2
+ y
2
2x 4y + k = 0, then
k 5 = 0 k = 5 (Using condition of orthogonality of two circle). Ans.]
MATHEMATICS
Code-A Page # 2
Q.5
[Sol. f (x) =

}
t +
1
0
) P . B . I (
II I
dt ) t x sin( t

f(x) =
1
0
) t x cos(
t
(

(
t +
t

+
t
1
}
t +
1
0
dt ) t x cos(
=
|
.
|

\
|

t
0 x cos
1
+
1
0
2
) t x sin(
1
(

(
t +
t
f(x) =
t
1
cos x
2
2
t
sin x
f(x) |
max
=
2
2
4 2
4 4 1
t
+ t
=
t
+
t
Ans.
Q.6
[Sol. Given,
2
1
b
c
c
b
2
1
2
A
cos |
.
|

\
|
+ = 4 cos
2

2
A
=
|
.
|

\
|
+
b
c
c
b
4bc cos
2

2
A
= b
2
+ c
2
2bc (1 + cos A) = b
2
+ c
2
2bc + 2bc cos A = b
2
+ c
2
2bc + (b
2
+ c
2
a
2
) = b
2
+ c
2
2bc = a
2
. Ans.
Aliter cos
b
c
c
b
2
1
2
A
+ =
bc
) a s ( s
=
bc
c b
2
1
2 2
+
On squaring both sides,
b
2
+ c
2
= 2s(2s 2a) b
2
+ c
2
= (b + c)
2
a
2
2bc = a
2
. Ans. ]
Q.7, 8, 9
[Sol.
(i) L
1
:
1
4 z
2
1
2 y
2
1
2 x
=

and L
2
:
1
3 z
1
1 y
2
1
0 x

=
+
=

.
shorest distance =
n
n AB

where
AB
=
k

3 i

2 + +
and
k

0 i

2 n + + =

=
5
5
=
5
. Ans.
(ii) Now,
5u = 6 3 + 2
5v = 3 + 6 4 2
(u, v, w)
M
(2


,
+
2, 2
+
4
)

P
2
3
Q
( , 2 1, 3 2 )
5w = 6 + 12 + 6 4
5u = 2 3 + 6 .......(1)
5v = 4 + 3 + 4 .......(2)
5w = 4 + 6 + 18 .......(3)
(2) + (3)
5(v + w) = 9 + 22 .......(4)
MATHEMATICS
Code-A Page # 3
Also, 10u 5v = 9 + 8 .......(5)
(4) + (5)
5w + 10u = 30 w + 2u = 6
Hence locus is 2x + z = 6 Ans.
(iii) As,
OA
,
OB
,
OC
are coplanar so volume of tetrahedron OABC = 0. Ans.]]
Q.10
Sol. To find locus of the middle point of all focal chords
T = S
1
yk 2(x + h) = k
2
4h passes through (1, 0)
y
x=1/2
V
(1,0)
|
.
|

\
|
0 ,
2
3
S
x
O
Directrix
2(1 + h) = k
2
4h
Hence, locus is y
2
= 2x 2 = 2(x 1).
Now, verify alternatives. Ans.
Q.11
Sol. Note that A is symmetric matrix.
Also, | A | =
|
.
|

\
|
+ + +
c
1
b
1
a
1
1
abc
As,
c
1
b
1
a
1
+ +
= 0
So, | A | = abc = 0 (As a = 0, b = 0, c = 0) given
A is also non-singular. ]
Q.12
[Sol. f(x) = sgn {sin x} =

=
= < <
1 , 0 x sin , 0
0 x sin , 1 x sin 1 , 1
t/2 t 3t/2 2t
y-axis
x
y=1 y=1
O
t/2 t 3t/2 2t
Graph of f(x) = sgn {sin x}
f(x) is a periodic function.
As, f( x) = f(x) f(x) is an even function.
f(x) e {0, 1} f(x) is an into function.
Note that 1 ) x ( f Lim
2
x
=
t

and
}
t
t
t = 2 dx ) x ( f . Ans.]
Q.13
Sol. Volume of tetrahedron OAPB =
6
1
| ] OP OB OA [ |
=
6
1
|
1 0 1
0 sin cos
0 0 1
u u
| =
6
sinu
B(cos , sin , 0) u u
P(1,0,1) y
z
O
A
(1,0,0)
x
u
Also,
OB OP n =

=
0 sin cos
1 0 1
k

u u
= sinu
i

j

( cos u) +
k
(sin u)
MATHEMATICS
Code-A Page # 4
As,
n . r

= 0 x sin u + y cos u + z sin u = 0
d =
) sin cos (sin
| sin |
2 2 2
u + u + u
u
=
) sin 1 (
sin
2
u +
u
. Ans. ]
PART-C
Q.1
[Sol. Let Q (o, 0). Also S (1, 0).
As ZSPQ = 90, so SQ is a diameter of the circle.
Hence,
equation of circle is (x o) (x 1) + y
2
= 0 .......(1)
Since (1) touches y
2
= 4x,
x
y
90
P
S
(1, 0)
Q
( , 0) o
O
(0, 0)
3 2 , 3
so the equation (x o) (x 1) + 4x = 0 has equal roots.
i.e., x
2
x (o 3) + o = 0
(o 3)
2
4o = 0 (o 1) (o 9) = 0
But o = 1, otherwise S and Q will coincide o = 9
So, equation of circle is (x 9) (x 1) + y
2
= 0
x
2
+ y
2
10x + 9 = 0
whose centre is (5, 0) and radius = 9 25 = 4 Ans.]
Q.2
Sol. AC
1
C
2
C
3
is an equilateral triangle and its inradius is r
1
and circumradius is R
1
.
Then R
1
= 2r
1
r
1
=
3
r
r 3
) r 2 (
4
3
s
2
= =
A
R
1
=
3
r 2
From figure CC
3
+ r = R
C
1
C
2
C
3
C
r r
r
r r
r
R
1
+ r = R
3
r 2
+ r = R

1
3
2
1
R
r
+
= a = 2 , b = 3, c = 1
So, (a + b + c)
least
= 6 Ans.]
MATHEMATICS
Code-A Page # 5
Q.3
[Sol. Given c b a

= 1
( ) 2
2
1
|
.
|

\
|
= 1
Also, | | c b a

= 1 | | c b a

= c b a

c , b , a

are mutually perpendicular vectors.

Also, ( ) ( ) ( ) b c a c a


+ = ( ) ( ) b c c a a c a


+
= ( ) ( ) ( ) ( ) ( ) b a c c c c a 0 c a a


+
= b a c c a
2 2


+ + = b a 2 c


+ + .

( ) ( ) ( ) ( ) b c a c a c b a 2

+ + +
=
( ) ( ) c b a 2 c b a 2

+ + + +
=
2
2
2
c b a 4

+ +
= 4 (1) +
2
1
+ 2 = 6 +
2
1
=
2
13
Alternatively: For objective,
Put i

a =

,
2
j

b =

, k

2 c =

.]
Q.4
[Sol. 7 letters 'TEACHER'
Total ways of selection of 7 squares
= (
2
C
1
) (
3
C
1
) (
4
C
4
) + (
2
C
1
) (
3
C
2
) (
4
C
3
) + (
2
C
2
) (
3
C
2
) (
4
C
2
) + (
2
C
1
) (
3
C
3
) (
4
C
2
) + (
2
C
2
) (
3
C
3
) (
4
C
1
)
+ (
2
C
2
)(
3
C
1
)(
4
C
3
) = 6 + 24 + 18 + 12 + 4 = 76
3 1 2 1
1 3 2 1
2 3 1 1
2 2 2 1
3 2 1 1
4 1 1 1
R R R R
4 3 2 1
Total number of ways of putting 7 letters = (76)
! 2
! 7
= (38) (7!) Ans.]
Q.5
[Sol. Here, we have
cos 2x + c sin x = 2c 7
(1 2sin
2
x) + c sin x = 2c 7 2 sin
2
x c sin x + 2c 8 = 0
sin x =
4
) 8 c 2 ( 8 c c
2

sin x =
2
4 c
or 2
But sin x = 2 (Reject)
So,
1
2
4 c
1 s

s
2 s c 4 s 2 2 s c s 6
c = 2, 3, 4, 5, 6. Ans.]
MATHEMATICS
Code-A Page # 6
Q.6
[Sol. For trace = 1, only possibilities of diagonal elements are 1, 1, 1 or 0, 0, 1
Number of possible symmetric matrices of order 3 3
= 2 3
3
C
1

3
C
1

3
C
1
= 6 27 = 162. Ans.]
Q.7
Sol. I =
( )
}

2
1
2
1
dx 1 x cot
; Put, x 1 = t
2
dx = 2t dt
= 2

dt ) t (cot t
1
0
.) P . B . I (
II
2 1
I
}


= 2
( )
(
(

|
|
.
|

\
|
+
+
|
|
.
|

\
|
}

1
0
2
2
1
1
0
2
2
1
dt
2
t
t 1
t cot 2
2
t
t cot
= 2
( )
(
(

+
+ +
|
|
.
|

\
|

t

}
dt
t 1
t cot
1 ) t 1 ( 0
32
2
1
1
0
2
2
= 2

(
(
(

+
+
t
} }

1
0
2
1
1
0
) I ( ) II (
1
2
dt
t 1
t cot
dt t cot . 1
32
.) P . B . I (
= 2
( )
(
(

+
+
+ +
t
}

1
0
1
0
2 1
2
1
0
1
2
) t (cot
2
1
dt
t 1
t
t cot t
32
= 2
(
(

|
|
.
|

\
|
t

t
+ +
t
+
t
4 16 2
1
2 n
2
1
4 32
2 2 2
l
= 2
(

+
t
+
t
2 n
2
1
4 16
2
l
= 2 n
2 8
2
l +
t
+
t
.
Hence,
t
+ t 2 n 8 I 8
2
l
= 4. Ans.]
Q.8
[Sol.
( )
4
a x
y
2

= and y = e
x
x
e
dx
dy
and
2
a x
dx
dy
=

2
a x
= e
x
(x a) = 2e
x
.......(1)
Also
( )
4
a x
2

= e
x
.......(2)

x
x 2
e
4
e 4
= [Using (1)]
e
x
(e
x
1) = 0. Hence e
x
= 1 x = 0
if x = 0 then y = 1
1 =
4
a
2
a
2
= 4 a = 2 or a = 2 (rejected)
As, for a = 2 curves do not intersect.
Hence, sum of the squares of all possible values of a is 4. Ans.]
PHYSICS
Code-A Page # 1
PART-A
Q.1
[Sol.
M
S
P
u
2.5
3.5
2.5
u
]
Q.2
[Sol.
4
M
M
3
a
4
M
0 M

=
4
M 3
12
M
a
=
9
a
a/2
a
]
Q.3
[Sol.
2
k
0

+
0
B

=
1
B

2
B B
B
B
2
k
B
2 1
0
2
0
0

+
=
=
]
Q.4
[Sol.
a
a
V
P
=
b
b
V
P
P
V
a
c
b
a
a a
T
V P
=
b
b b
T
V P
=
c
b a
T
V P
b a
2
a a
V T
V P
=
b
b b
T
V P
T
b
=
2
a
2
b
V
V
T
a
T
c
= T
a

a
b
V
V
= TT
a

a
b
T
T
=
b a
T T
a
b
V
V
=
a
b
T
T
]
Q.5
[Sol.
u F
centre in 2nd quadrant ]
PHYSICS
Code-A Page # 2
Q.6
[Sol.
24 0
60V
60 60 60
10O 12O
8O
0 0
6A
3A
]
Q.11
[Sol. pV = nRT
n =
RT
pv
= same
pV =
M
pRT
M
humid air
< M
dry air
P =
RT
pVM

humid air
<
dry air
]
Q.12
[Sol. Pd =
dt
Ldi
dt
di
= ve ]
Q.13
[Sol. m
2
= 9
m = 3 =
u
v
=
40
v

v = 120 cm
f
1
=
v
1

u
1
=
120
1
+
40
1
f = 30 cm ]
PART-C
Q.1
[Sol. mv = Mv
1
+ M v/2
v
1
=
M 2
mv
= g 5
v =
m
M 2
g 5
v =
m
M 2
g 5 =
01 . 0
1 2
100
= 2000 m/s ]
PHYSICS
Code-A Page # 3
Q.2
[Sol.
u
B v 2R = c ]
Q.3
[Sol.
2
1

9 4
9 4
+

= 26
2
=
2
1
(4 + 9) v
2
v = 26
13
6
= 12 ]
Q.4
[Sol. Fl =
3
m
2
l
o
A
o
A
=
l m
F 3
F
2
l
=
12
m
2
l
o
B
o
B
=
l m
F 6
u =
2
1
o
A
32 =
l m 2
F 27
l m 2
F 27
= u =
2
1
a
B
t
2
=
2
1

l m
F 6
t
2
t =
2
3
sec.
~
2sec. ]
Q.5
[Sol. e
2
R = 2 Ro
e
2
= 2o = 2ou
u = 1 rad. ]
Q.6
[Sol. 140 1(80 T) = 10 80 2 + 20 1 (T 0)
140 80 1600 = 160 T
T = 60C ]
Q.7
[Sol. v =
R
GM
=
2
2 . 11
~ 8km/sec. ]
Q.8
[Sol. qvB sin u = F
1.6 10
19
4 10
6
0.2 sin u = 8 10
13
R =
qB
sin mv u
=
2 . 0 10 6 . 1
10 6 . 1
19
27

|
|
.
|

\
|

19
13
10 6 . 1 2 . 0
10 8
= 1.25 m = 125 cm ]
CHEMISTRY
Code-A Page # 1
PART-A
Q.1
RT / E
a
e A K

=
K =
2
3 1
K
K K
E
a
=
2 3 1
a a a
E E E +
= (40 + 20 30) kJ = 30 kJ
Q.2 [Fe(NH
3
)
4
Cl
2
]Cl [Fe(NH
3
)
4
Cl
2
]
+
+ Cl


3
AgNO

AgCl(white ppt)
[Only V-Group Batch]
Q.3
[Sol.

O
Et
D
CH
3
CH I
3
S 2
N

H C
3
OCH
3
Et
D
]
[Only XY Batch]
Q.3
[Sol. It is Clemmension reduction since DCl is being is used therefore
C=O
R
R
group will be converted into
C
R
R
D
D
group ]
Q.4
[Sol.
X + NO XO + NH
3

2
2

3
0 +5 +2
+2
3
8
n
f
of X = 2
n
f
of NH
3
= 8
milli moles of NH
3
= 2 100 0.11 48 0.25
= 10
m. equivalents of NH
3
= 8 10 = m. equivalents of X
m. moles of X =
2
80
= 40
2.6 = 40 10
3
Atomic weight of X
Atomic weight of X = 65 gm/mole ]
CHEMISTRY
Code-A Page # 2
[Only V-Group Batch]
Q.5
[Sol.
H C
3
CH
3
C CH C
2
O O

2 2
I / ) OH ( Ca
CHI
3
(Yellow ppt.) +
H C
3
CH
3
C
O

3
CaCO
A

CO
CO
H C
3
H C
3
O
O
Ca
]
[Only XY Batch]
Q.5
[Sol.
CH
3
CH
3
CH
3 CH
3
CH
3

H
+
H
+
O O
COH COH
O OH
COH COH
MeOH
18
C OH
C OH
2
OH
OH
OH
O Me
18
O Me
18
O Me
18
H
H C
3
O
C OMe
18
]
Q.6
[Sol. Species having more ve AG value reduce species having less ve AG]
Paragraph for question nos. 7 to 9
Q.7
Sol. 24.63 litre at 1 atm and 300 K 1 mole of SO
2
[H
2
SO
3
] = 1 M
H
2
SO
3
HSO
3
+ H
+
1x x x
x 1
x
2

= 0.5 x = 0.5 M
Q.8
Sol. H
2
O OH + H
+
Co 0.5
0.5 55.5 o = 10
14
o = 3.6 10
16
CHEMISTRY
Code-A Page # 3
Q.9
Sol. H
2
SO
3
+ NaOH NaHSO
3
+ H
2
O
100 mole 150 mole 0 0
50 mole 100
NaHSO
3
+ NaOH Na
2
SO
3
+ H
2
O
100 50
50 50
pH = pKa
2
+ log
| |
| |

3
2
3
HSO
SO
= 7 ]
Q.10
[Sol. AH = nC
P
AT
= 1 (5 + 2) 100 = 700 Cal
AU = nC
V
AT
= 1 5 100 = 500 Cal
AS = n
R
ln
1
2
V
V
+ nC
V
ln
1
2
T
T
= 2 ln 10 + 5 ln
3
4
]
[Only V-Group Batch]
Q.11
[Sol. Na
2
C
2
O
4
+ H
2
SO
4
H
2
C
2
O
4
+ Na
2
SO
4
H
2
C
2
O
4


A
H
2
O + X = CO + Y = CO
2
FeC
2
O
4


A
FeO + CO + CO
2
2HCOONa

A
Na
2
C
2
O
4
+ H
2
2HCOOAg

A
Ag + HCOOH + CO
2
]
[Only XY Batch]
Q.11
[Sol. Mg
2
C
3
+ 8H
2
O C
3
H
4
+ 2Mg(OH)
2
H C C C
H
H
H
6o bond
Be
2
C + 4H
2
O CH
4
+ 2Be(OH)
2
C
H
H
H
H
4o bond ]
CHEMISTRY
Code-A Page # 4
[Only V-Group Batch]
Q.12
[Sol. 3Alcohol give white turbidity immediately on reaction with Lucas reagent due to the faster formation of
3 carbocation as an intermediate in this test.]
[Only XY Batch]
Q.12
[Sol. Only primary amine give isocyanide test with CHCl
3
/ OH ]
[Only V-Group Batch]
Q.13
[Sol. (A) B
3
N
3
H
6
= 5 3 + 7 3 + 1 6 = 42
ZnC
2
= 30 1 + 2 6 = 42
(B)
C = C = C
H
H
H
H
xy plane
xz plane
p
z
p
z
p
y y
p
sp
(sp p )
2
x y
sp
(sp )
x
sp
(sp )
2
x
p
z
(Non planar)
But
C = C = C
H
H
H
H
resultant
=0
Non polar
resultant
(C) BN
2
H
6
2NH
3
[BH
2
(NH
3
)
2
]
+
[BH
4
]

(complete octet
All bonds are 2C2e

)
(D) PCl
5
+ H
2
O (Parital hydrolysis) POCl
3
+ 2HCl
PCl
5
+ 4H
2
O (complete) H
3
PO
4
+ 5HCl ]
[Only XY Batch]
Q.13
[Sol. CO
2
neutralise NaOH it means decreases OH

concentration, increases H
+
concentration So
pH = log[H
+
] increases
Al(OH)
4

(Soluble) + CO
2
Al(OH)
3
+
+ HCO
3
Al
2
O
3
+ NaOH NaAlO
2
+ H
2
O ]
PART-C
Q.1
[Sol. 3 F E
1
= F 0.55 2 2.26 F
E
1
= 1.69 V
2 F E
2
= F 0.96 F 1.66
E
2
= 1.3 V
E
1
+ E
2
= 3 V ]
CHEMISTRY
Code-A Page # 5
Q.2
[Sol. (i) 3XeF
4
+ 6H
2
O Xe + 2XeO
3
+ 12HF
(ii) XeF
2
+ H
2
O Xe + 2HF + 1/2O
2
(iii) 4Na
2
S
2
O
3
. 5H
2
O 2Na
2
SO
4
+ 2Na
2
S
5
+ 5H
2
O
|
(iv) P
4
+ 3NaOH + 3H
2
O PH
3
+ 3NaH
2
PO
2
(v) F
2
+ 2NaOH 2NaF + OF
2
+ H
2
O
(vi) Cl
2
+ cold/dil 2NaOH NaCl + NaClO + H
2
O
(vii) 3HOCl
A
2HCl + HClO
3
(viii) 2NO
2
+ 2NaOH NaNO
2
+ NaNO
3
+ H
2
O
(ix) Zn + 2NaOH Na
2
ZnO
2
+ H
2
]
Q.4
[Sol. 1001 + 3001 = 4002
(4) pOH = pK
b
pH = 14 pK
b
(5) E = 0
2
0591 . 0
ln
0
2 4
1 1
2
2
>

spontaneous
(6) K =
) K K ( 1
K
K
b f
b
f
> >
]
Q.5
[Sol. Pb, Hg, Cu so Ans. is 3]
Q.6
[Sol.
CH
3
CH
2
Cl
CH
3
CH
3
CH
3
Cl
Cl
Cl
(Four)
(Two)
Only structural = 4
Total possible = 8 ]
CHEMISTRY
Code-A Page # 6
Q.7
[Sol. [Cu(CN)
2
(SCN)
2
]
2
[Cu(CN)
2
(SCN)(NCS)]
2
[Cu(CN)
2
(NCS)
2
]
2
[Cu(CN)(NC)(SCN)
2
]
2
[Cu(CN)(NC)(SCN)(NCS)]
2
[Cu(CN)(NC)(NCS)
2
]
2
[Cu(NC)
2
(SCN)
2
]
2
[Cu(NC)
2
(SCN)(NCS)]
2
[Cu(NC)
2
(NCS)
2
]
2
Linkage + Co-ordination
[Cu(NH
3
)
4
][Pt(CN)
4
] 5 Linkage isomers [Cu(NH
3
)(NC)][Pt(CN)
3
NH
3
] 8 Linkage isomers
[Pt(NH
3
)
4
][Cu(CN)
4
] 5 Linkage isomers [Pt(NH
3
)(NC)][Cu(CN)
3
NH
3
] 8 Linkage isomers
B = 26
2 2 2
c b Ma a = H
2
O , b = NH
3
, C = Cl
a
a
b c
c b

a
a
b c
c b
a
a
b
c
c
b

a
a
b
c
c
b a
a b
c
c
b
c = 5
Z = 9 + 26 5 =
10
30
= 3 ]
Q.8
[Sol. (i) n = 1
Molecule = unsymmetrical
S.I. = 2
n
= 2
1
= 2
(ii) Same
(iii) n = 2, unsymmetrical molecule
S.I. = 2
2
= 4
(iv) n =3 , unsymmetrical
S.I. = 2
3
= 8 ]